Measurement of sugar in a solution

• US 9,903,850 B2
• Filed: 12/15/2015
• Issued: 02/27/2018
• Est. Priority Date: 12/19/2014
• Status: Expired due to Fees

• Current Assignee: Salunda Limited
• Original Assignee: Salunda Limited
• Inventors: Harrison, Martin Roy
• Primary Examiner(s): Nguyen, Hoai-An D
• Application Number:
  US14/970,140
• Publication Number:
  US 20160178601A1
• Time in Patent Office: 805 Days
• Field of Search: 324600, 324629, 324633, 324636, 324637, 324639, 324640, 324649, 324652, 600300, 600309, 600310, 600316, 600318, 600319, 600345, 600347, 600365
• CPC Class Codes: G01N 22/00 Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more G01N3/00 - G01N17/00, G01N24/00 take precedence
• CPC Class Codes: G01N 27/026 Dielectric impedance spectroscopy electrochemical impedance spectroscopy for measuring corrosion G01N17/02
• CPC Class Codes: G01N 33/2835 specific substances contained in the oil or fuel

Abstract

A system and method for measuring the amount of sugar in a sample including measuring a solution of the sugar using oscillating electromagnetic fields generated in the sample at least two radio frequencies at which the electromagnetic properties of the solution differ. There are detected characteristics of the oscillating electromagnetic fields generated in the sample at each radio frequency that are dependent on the electromagnetic properties of the solution. A measure of the amount of sugar is derived from those characteristics. By combining measurements at different radio frequencies, the effects of changes in the ion concentration can then be removed to give an unambiguous measure for the sugar.

Claims

1. A method of measuring the amount of sugar in a sample comprising a solution of the sugar, the method comprising:

generating a resonant oscillating electromagnetic field having a first frequency of 100 MHz or more in a cavity resonator containing the sample;

generating a further oscillating electromagnetic field having a second frequency of 100 MHz or less in the sample by driving oscillations in a tank circuit comprising reactive elements that include a reactive probe arranged to generate the further oscillating electromagnetic field in the sample, the first and second frequencies being different frequencies at which the electromagnetic properties of the solution differ;

detecting a characteristic of the resonant oscillating electromagnetic field that is dependent on the electromagnetic properties of the solution;

detecting an electrical parameter of the oscillations of the tank circuit that is a characteristic of the further oscillating electromagnetic field that is dependent on the electromagnetic properties of the solution; and

deriving a measure of the amount of sugar from said detected characteristics.

2. A method according to claim 1, wherein said characteristic of the resonant oscillating electromagnetic field is the resonance frequency of the resonant oscillating electromagnetic field.

3. A method according to claim 1, wherein said oscillations in said tank circuit are driven by a marginal oscillator.

4. A method according to claim 3, wherein said electrical parameter of the oscillations of the tank circuit is the frequency of the oscillations.

5. A method according to claim 1, wherein said measure of the amount of sugar from said detected characteristics is derived by combining said detected characteristics to cancel the effect of conductive ions and/or gasses and/or solids in the solution.

6. A method according to claim 1, wherein the two frequencies differ by at least one order of magnitude.

7. A method according to claim 1, wherein the two frequencies differ by at least two orders of magnitude.

8. A method according to claim 1, wherein the sample is a flowing fluid sample.

9. A method according to claim 1, wherein the sample is a sample taken from a process of manufacture of a biofuel.

10. A method according to claim 1, wherein the solution is an aqueous solution.

11. A method according to claim 1, wherein said first and second frequencies are radio frequencies.

12. A sensor system for measuring the amount of sugar in a sample comprising a solution of the sugar, the sensor system comprising:

a measurement apparatus comprising;

a cavity resonator arranged to contain the sample,

a transmission antenna disposed in the cavity resonator,

a drive circuit arranged to drive the transmission antenna to generate a resonant oscillating electromagnetic field having a first frequency of 100 MHz or more in the cavity resonator,

a tank circuit comprising reactive elements that include a reactive probe arranged to generate a further oscillating electromagnetic field in the sample, and

an oscillator circuit arranged to drive oscillations in the tank circuit that cause the probe to generate the further oscillating electromagnetic field having a second frequency of 100 MHz or less, the first and second frequencies being different frequencies at which the electromagnetic properties of the solution differ;

a detection system comprising;

a reception antenna disposed in the cavity resonator,

a resonant cavity detection circuit connected to the reception antenna and arranged to detect a characteristic of the resonant oscillating electromagnetic field that is dependent on the electromagnetic properties of the sample,

a tank circuit detection circuit arranged to detect an electrical parameter of the oscillations of the tank circuit that is a characteristic of the further oscillating electromagnetic field that is dependent on the electromagnetic properties of the solution; and

an analysis system arranged to derive a measure of the amount of sugar from said detected characteristics.

13. A sensor system according to claim 12, wherein said characteristic of the resonant oscillating electromagnetic field is the resonance frequency of the resonant oscillating electromagnetic field.

14. A sensor system according to claim 12, wherein said oscillator circuit is a marginal oscillator.

15. A sensor system according to claim 14, wherein said electrical parameter of the oscillations of the tank circuit is the frequency of the oscillations.

16. A sensor system according to claim 12, wherein the analysis system is arranged to derive said measure of the amount of sugar from said detected characteristics by combining said detected characteristics to cancel the effect of conductive ions and/or gasses and/or solids in the solution.

17. A sensor system according to claim 12, wherein the two frequencies differ by at least one order of magnitude.

18. A sensor system according to claim 12, frequencies differ by at least two orders of magnitude.

19. A sensor system according to claim 12, wherein the sample is a flowing fluid sample.

20. A sensor system according to claim 12, wherein the sample is a sample taken from a process of manufacture of a biofuel.

21. A sensor system according to claim 12, wherein the solution is an aqueous solution.

22. A sensor system according to claim 12, wherein the first and second frequencies are radio frequencies.

23. A sensor system according to claim 12 in combination with said sample.