Microwave produced pyrolysis oil from beneficiated organic-carbon-containing feedstock

• US 9,909,078 B2
• Filed: 07/20/2016
• Issued: 03/06/2018
• Est. Priority Date: 08/20/2013
• Status: Active Grant

• Current Assignee: CTP Biotechnology, LLC
• Original Assignee: Biomass Energy Enhancements LLC.
• Inventors: Van Thorre, Douglas M, Tait, Carleton Drew, Catto, Michael L, Scalzo, Philip James
• Primary Examiner(s): McAvoy, Ellen M
• Application Number:
  US15/215,281
• Publication Number:
  US 20160326444A1
• Time in Patent Office: 594 Days
• Field of Search: 585240, 585242
• CPC Class Codes: B01D 3/34 with one or more auxiliary substances
• CPC Class Codes: C10G 1/02 by distillation
• CPC Class Codes: C10J 2300/0916 Biomass
• CPC Class Codes: C10J 2300/092 Wood, cellulose
• CPC Class Codes: C10J 3/72 Other features
• CPC Class Codes: C10L 1/04 essentially based on blends of hydrocarbons
• CPC Class Codes: C10L 2200/0469 Renewables or materials of biological origin
• CPC Class Codes: C10L 2290/02 Combustion or pyrolysis
• CPC Class Codes: C10L 2290/04 Gasification
• CPC Class Codes: C10L 2290/30 Pressing, compressing or compacting
• CPC Class Codes: C10L 2290/36 Applying radiation such as microwave, IR, UV
• CPC Class Codes: C10L 3/00 Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
• CPC Class Codes: C10L 5/447 Carbonized vegetable substances, e.g. charcoal, or produced by hydrothermal carbonization of biomass
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel
• CPC Class Codes: Y02P 20/145 the feedstock being materials of biological origin

Abstract

A processed pyrolysis oil composition, a renewable liquid fuel, having a high energy density, low water content and a more neutral pH, and made with an oxygen-starved microwave sub-system from a processed organic-carbon-containing feedstock made with a beneficiation sub-system is described. Renewable biomass feedstock passed through a beneficiation sub-system to reduce water content to below at least 20 wt % and water-soluble salt reduction of at least 60% from that of unprocessed organic-carbon-containing feedstock on a dry basis. The processed feedstock is introduced into a substantially microwave-transparent reaction chamber. A microwave source emits microwaves which are directed through the microwave-transparent wall of the reaction chamber to impinge on the feedstock within the reaction chamber. The microwave source may be rotated relative to the reaction chamber. The feedstock is subjected to microwaves until the desired reaction occurs to produce a liquid processed pyrolysis oil fuel.

Claims

1. A composition, comprising:

a processed pyrolysis oil composition that comprises a liquid renewable carbon fuel with characteristics that include an energy density of at least 33.0 MMBTU/ton (38.4 GJ/MT), a water content of less than 15 wt %, and a pH of at least as high as 4.0, and

the processed pyrolysis oil is made from unprocessed organic-carbon-containing feedstock that is converted into the processed organic-carbon-containing feedstock with a beneficiation sub-system, and to the processed pyrolysis oil with a microwave sub-system.

2. The composition of claim 1, wherein the beneficiation sub-system comprises:

a transmission device configured to convey into a reaction chamber unprocessed organic-carbon-containing feedstock comprising free water, intercellular water, intracellular water, intracellular water-soluble salts, and at least some plant cells comprising cell walls that include lignin, hemicellulose, and microfibrils within fibrils;

at least one reaction chamber comprising at least one entrance passageway, at least one exit passageway for fluid, at least one exit passageway for processed organic-carbon-containing feedstock, and at least three sections, the sections comprising;

a wet fibril disruption section configured to interact with at least some of the lignin and hemicellulose between the fibrils to make at least some regions of the cell wall more susceptible to outflow by water-soluble salts,

a vapor explosion section in communication with the wet fibril disruption section and at least configured to volatilize plant fibril permeable fluid through rapid decompression to penetrate the more susceptible regions of the cell wall so as to create a porous organic-carbon-containing feedstock with plant cell wall passageways for intracellular water and intracellular water-soluble salts to pass from the plant cell, and

a compaction section in communication with the vapor explosion section and configured to compress the porous organic-carbon-containing feedstock between pressure plates so as to permit the escape of intracellular water and intracellular water-soluble salt from the reaction chamber fluid exit passageway and to create processed organic-carbon-containing feedstock that passes out through its reaction chamber exit passageway; and

a collection device in communication with the reaction chamber and configured to gather the processed organic-carbon-containing feedstock having a water content of less than 20% by weight and a water-soluble salt content that is decreased by at least 60% on a dry basis from that of the unprocessed organic-carbon-containing feedstock.

3. The composition of claim 1 wherein the microwave sub-system, comprises:

at least one reaction chamber within a microwave reflecting enclosure, the reaction chamber comprising at least one microwave-transparent chamber wall and at least one reaction cavity within the reaction chamber that is configured to hold the organic-carbon-containing feedstock in an externally supplied oxygen free atmosphere;

a microwave subsystem comprising at least one device configured to emit microwaves when energized, the microwave device positioned relative to the reaction chamber so that the microwaves are directed through the microwave-transparent chamber wall and into the reaction cavity; and

a mechanism configured to provide relative motion between the microwave device and the reaction chamber.

4. The pyrolysis oil composition of claim 1, further comprising:

a water content of less than 10 wt %.

5. The pyrolysis oil composition of claim 1, further comprising:

less than 5 weight percent volatiles.

6. The pyrolysis oil composition of claim 1, further comprising:

a pH of at least as high as 5.0.

7. The pyrolysis oil composition of claim 1, further comprising:

a pH of at least as high as 6.0.

8. The pyrolysis oil composition of claim 6 wherein the pH is at least one pH number greater than would have been in a pyrolysis oil made with the unprocessed organic-carbon-containing feedstock passed through the microwave sub-system.

9. The pyrolysis oil composition of claim 1, further comprising:

a specific gravity of less than 1.05.

10. The pyrolysis oil composition of claim 1 wherein specific gravity is at least 0.1 less than would have been in a pyrolysis oil composition made with the unprocessed organic-carbon-containing feedstock passed through the microwave sub-system.

11. The pyrolysis oil composition of claim 1, further comprising:

having a specific gravity that is at least 20 percent less than would have been in a pyrolysis oil composition made with the unprocessed organic-carbon-containing feedstock passed through the microwave sub-system.

12. The pyrolysis oil composition of claim 1, further comprising:

at least 50 percent less tar by weight than the tar in a pyrolysis oil composition made with the same feedstock but using a thermal process that creates a liquid phase during the process.

13. The composition of claim 2 wherein the processed organic-carbon-containing feedstock is from at least two unprocessed organic-carbon-containing feedstock from a group consisting of a herbaceous plant material, a soft woody plant material, and a hard woody plant material, wherein each type passes in series through the at least one reaction chamber, and wherein the energy density of each processed plant material in the processed organic-carbon-containing feedstock is at least 20 MMBTU/ton (23.3 GJ/MT).

14. The composition of claim 2 wherein the unprocessed organic-carbon-containing has a water-soluble salt content of at least 4000 mg/kg on a dry basis.

15. The composition of claim 2 wherein the beneficiation sub-system, further comprises:

a pretreatment chamber that is configured to use for each organic-carbon-containing feedstock a particular set of conditions including time duration, temperature profile, and the chemical content of pretreatment solution to at least initiate the dissolution of contaminates that would hinder creation of the plant cell wall passageways that allow intracellular water and intracellular water-soluble salts to pass outward from the plant cells.

16. The composition of claim 2 wherein the vapor explosion section, further comprises:

at least one rinsing subsection configured to flush at least some of the water-soluble salt from the porous organic-carbon-containing feedstock before it is passed to the compaction section.