Method of flash-cooling produced water and heating steam generator feedwater

• US 9,909,401 B2
• Filed: 08/07/2015
• Issued: 03/06/2018
• Est. Priority Date: 08/13/2014
• Status: Active Grant

• Current Assignee: Veolia Water Technologies, Inc. (Veolia Environnement SA)
• Original Assignee: Veolia Water Technologies, Inc. (Veolia Environnement SA)
• Inventors: Patterson, Mark D.
• Primary Examiner(s): Buck, Matthew R
• Application Number:
  US14/821,073
• Publication Number:
  US 20160047218A1
• Time in Patent Office: 942 Days
• CPC Class Codes: C02F 1/041 by means of vapour compression
• CPC Class Codes: C02F 1/048 Purification of waste water by evaporation
• CPC Class Codes: C02F 1/06 Flash evaporation
• CPC Class Codes: C02F 1/40 Devices for separating or removing fatty or oily substances or similar floating material cleaning or keeping clear the surface of open water from oil or like materials E02B15/04; devices in sewers for separating liquid or solid substances from sewage E03F5/14, e.g. for use in drains leading to the sewer E03F5/16
• CPC Class Codes: C02F 2101/32 Hydrocarbons, e.g. oil
• CPC Class Codes: C02F 2103/10 from quarries or from mining activities
• CPC Class Codes: C02F 2103/365 from petrochemical industry (e.g. refineries)
• CPC Class Codes: C02F 2209/005 Processes using a programmable logic controller [PLC]
• CPC Class Codes: C02F 2209/02 Temperature
• CPC Class Codes: C02F 2209/03 Pressure
• CPC Class Codes: C02F 2301/063 Underpressure, vacuum
• CPC Class Codes: E21B 43/24 using heat, e.g. steam injection

Abstract

An oil recovery process where produced water is cooled through a flash evaporization process and the resulting vapor is utilized to heat steam generator feedwater.

Claims

1. A method of recovering oil and cooling produced water comprising:

recovering an oil-water mixture from an oil-bearing formation;

separating the oil from the oil-water mixture to yield the produced water;

directing the produced water through a plurality of flash evaporators connected in series;

cooling the produced water as the produced water flows through the series of flash evaporators by varying the pressure in the flash evaporators such that the produced water experiences successive pressure drops in the flash evaporators as the produced water flows through the plurality of flash evaporators, causing a portion of the produced water in each flash evaporator to be converted to vapor;

preheating a steam generator feedwater by transferring heat from the vapor to the steam generator feedwater;

after preheating the steam generator feedwater, directing the steam generator feedwater to a steam generator and generating steam; and

injecting the steam into the oil-bearing formation or injection well.

2. The method of claim 1 including directing the steam generator feedwater through a series of heat exchangers and wherein each flash evaporator produces a vapor stream, the method including directing the vapor streams from the flash evaporators to the series of heat exchangers and transferring heat from the vapor streams to the steam generator feedwater passing through the series of heat exchangers.

3. The method of claim 1 including controlling the pressure in the flash evaporators such that one or more of the flash evaporators are operated at a lower pressure than a preceding flash evaporator relative to the flow of produced water through the flash evaporators.

4. The method of claim 3 including controlling the pressure in each flash evaporator by a pressure controller that is operative to control a control valve that is communicatively connected to a respective flash evaporator.

5. The method of claim 1 wherein each flash evaporator produces a vapor stream that is directed to and through a heat exchanger and from the heat exchanger to a pressure control device that controls the pressure within the flash evaporator that produced the vapor stream.

6. The method of claim 1 wherein the series of flash evaporators form a produced water cooling unit and wherein, in addition to the series of flash evaporators, the cooling unit includes a series of heat exchangers and a series of pressure control devices wherein one flash evaporator, one heat exchanger, and one pressure control device forms a single stage in the cooling unit;

and the method includes directing the produced water from one flash evaporator to another flash evaporator and in the process cooling the produced water and concentrating the produced water;

producing a vapor stream in each flash evaporator and directing the vapor stream to and through one heat exchanger and to the pressure control device of a single stage;

directing the steam generator feedwater through a series of the heat exchangers and transferring heat from the vapor streams to the steam generator feedwater;

employing the vapor streams directed from the heat exchangers to control the pressure in the flash evaporators such that the pressure in the flash evaporators decrease from one flash evaporator to another flash evaporator in the direction of the flow of the produced water therethrough.

7. A method of recovering oil from an oil-bearing formation comprising:

recovering an oil-water mixture from the oil-bearing formation;

separating the oil from the oil-water mixture to produce the oil and produced water;

directing a feedwater to a steam generator and producing steam;

injecting the steam into the oil-bearing formation or an injection well;

evaporating a portion of the produced water to produce a vapor by directing the produced water through a plurality of flash evaporators and causing a portion of the produced water in each flash evaporator to be converted to the vapor;

transferring heat from the vapor to the feedwater so as to heat the feedwater prior to the feedwater reaching the steam generator; and

wherein transferring heat from the vapor to the feedwater includes directing the vapor and the feedwater to a heat exchanger and transferring heat from the vapor to the feedwater in the heat exchanger.

8. The method of claim 7 including isolating the vapor from the feedwater by directing the vapor to one side of the heat exchanger and directing the feedwater to another side of the heat exchanger and transferring heat from the vapor on one side of the heat exchanger to the feedwater on the other side of the heat exchanger.

9. The method of claim 7 wherein evaporating a portion of the feedwater to produce the vapor includes directing the produced water through a series of flash evaporators and flash evaporating a portion of the produced water in each flash evaporator to produce a series of vapor streams;

and transferring heat from the vapor streams to the feedwater.

10. The method of claim 9 including directing each vapor stream to a separate heat exchanger and directing the feedwater through each of the heat exchangers where heat is transferred from the vapor streams to the feedwater.

11. The method of claim 7 wherein evaporating a portion of the produced water includes:

directing the produced water through a series of flash evaporators and producing a series of vapor streams;

directing each vapor stream to a separate heat exchanger; and

flowing the feedwater through the heat exchangers in a direction that is counter to the direction of flow of the produced water through the series of flash evaporators.

12. The method of claim 7 wherein evaporating a portion of the produced water to produce a vapor includes:

directing the produced water into a first flash evaporator and producing a first vapor stream and a first cooled produced water stream;

directing the first cool produced water stream to a second flash evaporator and producing a second vapor stream and a second cooled produced water stream; and

controlling the pressure in the first and second flash evaporators such that the pressure in the second flash evaporator is less than the pressure in the first evaporator.

13. The method of claim 12 wherein there is provided three or more flash evaporators including the first and second flash evaporators and a last flash evaporator;

and wherein the method includes sequentially decreasing the pressure in each flash evaporator from the first flash evaporator to the last flash evaporator.

14. The method of claim 13 wherein the last flash evaporator produces a last cooled produced water stream and the method includes directing the last cooled produced water stream to a produced water treatment unit.

15. The method of claim 7 wherein evaporating a portion of the produced water to produce the vapor includes directing the produced water to the plurality of flash evaporators and controlling the pressure in the flash evaporators with a vacuum system.

16. The method of claim 15 including controlling the pressure in the flash evaporators such that the pressure in the flash evaporators is less than the saturation pressure of the produced water in the flash evaporators.

17. The method of claim 15 wherein there is provided a pressure control valve operatively connected between the vacuum system and the flash evaporators and the method includes controlling the pressure in the flash evaporators via the pressure control valve.

18. A system for cooling produced water separated from a recovered oil-water mixture and pre-heating a steam generator feedwater used for generating steam for injection into an oil-bearing formation, the system comprising:

an oil-water separation unit for receiving the recovered oil-water mixture and separating the oil from the oil-water mixture to produce oil and the produced water;

a cooling unit comprising a series of operatively interconnected stages with each stage comprising;

i. a flash evaporator having an inlet, outlet and a flash chamber;

ii. a heat exchanger operatively connected to the flash evaporator for receiving vapor produced by the flash evaporator;

iii. a pressure control circuit operatively connected to the heat exchanger and operative to control the pressure in the flash chamber;

a steam generator for generating steam for injection into the oil-bearing formation;

a produced water cooling line operatively connected to the flash evaporators of the stages for directing the produced water to the flash evaporators and cooling the produced water and producing the vapor;

a first vapor line for directing the vapor from each flash evaporator to one of the heat exchangers;

a second vapor line for directing the vapor from each heat exchanger to one of the pressure control circuits;

a steam generator feedwater line for directing the feedwater to the heat exchangers where heat is transferred from the vapor in the heat exchangers to the feedwater; and

wherein the pressure control circuit decreases the pressure from one flash evaporator to another flash evaporator and wherein succeeding pressure drops occur in the flash evaporators in the direction of flow of the produced water through the flash evaporators.

19. The system of claim 18 wherein the pressure control circuits include a vacuum unit and a series of pressure control valves disposed between the vacuum unit and the flash evaporators and wherein the vacuum unit and the pressure control valves cooperate to control the pressure in the flash evaporators.

20. The system of claim 18 wherein each pressure control circuit of each stage is in fluid communication with a vapor compartment of one of the heat exchangers.

21. The system of claim 20 wherein the pressure control circuit includes a controller and a valve and wherein the controller is operative to adjust the valve which is in fluid communication with the vapor compartment of one of the heat exchangers and in fluid communication with the flash chamber of one of the flash evaporators.

22. The system of claim 21 wherein the pressure control circuit includes a vacuum system that operates in concert with the controllers and the valves and wherein the vacuum system, controllers and valves controls the pressure within the flash chambers of the flash evaporators.

23. The system of claim 18 wherein the pressure control circuit provides a pressure in each flash chamber of the flash evaporators that is lower than the saturation pressure at the temperature of the produced water entering the respective flash evaporator.

24. The system of claim 18 wherein each heat exchanger includes a compartment for receiving both the vapor and the steam generator feedwater and wherein the vapor directly heats the feedwater.

25. A system for cooling produced water separated from a recovered oil-water mixture and preheating a steam generator feedwater used for generating steam for injection into an oil-bearing formation, the system comprising:

an oil-water separation unit for receiving the recovered oil-water mixture and separating oil from the oil-water mixture to produce oil and the produced water;

one or more flash evaporators for receiving the produced water and cooling the produced water by flash evaporating the produced water to produce vapor and cooled produced water;

one or more heat exchangers for receiving the vapor produced by the one or more flash evaporators;

a steam generator for generating steam for injection into the oil-bearing formation;

a steam generator feedwater line for feeding the feedwater to the steam generator;

the steam generator feedwater line configured to direct the feedwater through the one or more heat exchangers prior to the feedwater reaching the steam generator wherein heat is transferred from the vapor to the steam generator feedwater; and

wherein the heat exchanger isolates the vapor from the steam generator feedwater and heat is transferred from the vapor to the steam generator feedwater.

26. The system of claim 25 including a pressure controlled subsystem for controlling the pressure in the one or more flash evaporators.

27. The system of claim 26 wherein the pressure controlled subsystem includes a vacuum unit and a pressure control valve disposed between the vacuum unit and the flash evaporator and wherein the vacuum unit and pressure control valve cooperate to control the pressure in the flash evaporator.

28. The system of claim 25 wherein the system includes a series of flash evaporators configured to permit the produced water to flow through each of the flash evaporators;

and wherein each flash evaporator produces a vapor stream and a cooled produced water stream.

29. The system of claim 28 wherein the system includes a series of heat exchangers and wherein each heat exchanger is operatively connected to a flash evaporator such that the vapor stream produced by each flash evaporator is directed to one heat exchanger;

and wherein the steam generator feedwater line is configured to direct the steam generator feedwater through each of the heat exchangers.

30. The system of claim 29 wherein the system is configured such that the produced water flowing through the flash evaporators and the steam generator feedwater flowing through the heat exchangers flow in counter directions.

31. A method of recovering oil and cooling produced water comprising:

recovering an oil-water mixture from an oil-bearing formation;

separating oil from the oil-water mixture to yield the produced water;

directing the produced water through a plurality of flash evaporators connected in series;

cooling the produced water as the produced water flows through the series of flash evaporators by varying the pressure in the flash evaporators such that the produced water experiences successive pressure drops in the flash evaporators as the produced water flows through the plurality of flash evaporators, causing a portion of the produced water in each flash evaporator to be converted to vapor;

preheating a steam generator feedwater by transferring heat from the vapor to a steam generator feedwater;

after preheating the steam generator feedwater, directing the steam generator feedwater to a steam generator and generating steam;

injecting the steam into an oil-bearing formation or injection well; and

wherein each flash evaporator produces a vapor stream that is directed to and through a heat exchanger and from the heat exchanger to a pressure control device that controls the pressure within the flash evaporator that produced the vapor stream.