Fuel cell system with partial recycling of anode exhaust

• US 9,911,989 B2
• Filed: 07/24/2006
• Issued: 03/06/2018
• Est. Priority Date: 07/25/2005
• Status: Active Grant

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: McElroy, James, Venkataraman, Swaminathan, Finn, John, LeVan, M. Douglas, Mitlitsky, Fred
• Primary Examiner(s): Stagg, Miriam
• Assistant Examiner(s): Thomas, Brent C
• Application Number:
  US11/491,487
• Publication Number:
  US 20100239924A1
• Time in Patent Office: 4,243 Days
• Field of Search: 429423
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/04007 related to heat exchange
• CPC Class Codes: H01M 8/04097 with recycling of the reactants H01M8/04119, H01M8/04104 take precedence
• CPC Class Codes: H01M 8/04231 Purging of the reactants
• CPC Class Codes: H01M 8/0612 from carbon-containing material
• CPC Class Codes: H01M 8/0668 Removal of carbon monoxide or carbon dioxide
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A method of operating a fuel cell system includes providing a fuel inlet stream into a fuel cell stack, operating the fuel cell stack to generate electricity and a hydrogen containing fuel exhaust stream having a temperature above 200 C, lowering a temperature of the fuel exhaust stream to 200 C or less, separating the fuel exhaust stream into a first separated fuel exhaust stream and a second separated fuel exhaust stream, and recycling the first separated fuel exhaust stream into the fuel inlet stream.

Claims

1. A method of operating a fuel cell system, comprising:

providing a fuel inlet stream into a fuel cell stack;

operating the fuel cell stack to generate electricity, an air exhaust stream and a fuel exhaust stream, the fuel exhaust stream having a temperature above 200 C and a first composition immediately after leaving the fuel cell stack;

heating the fuel inlet stream with the entire fuel exhaust stream in a fuel heat exchanger;

heating a fuel cell stack air inlet stream with an output of the fuel heat exchanger in an air preheater heat exchanger;

splitting the fuel exhaust stream into a first split fuel exhaust stream and a second split fuel exhaust stream such that the first and second split fuel exhaust streams have the same first composition;

lowering a temperature of at least the entire of the first or second split fuel exhaust streams to 200 C or less;

recycling the first split fuel exhaust stream into the fuel inlet stream; and

burning the second fuel exhaust stream with the air exhaust stream, wherein heating the fuel inlet stream is performed prior to burning the second fuel exhaust stream;

wherein neither the fuel exhaust stream, the first split fuel exhaust stream nor the second split fuel exhaust stream is passed through a water gas shift reactor.

2. The method of claim 1, further comprising using a low temperature blower to controllably recycle the first split fuel exhaust stream having a temperature of 200 C or less into the fuel inlet stream.

3. The method of claim 2, wherein:

the first split fuel exhaust stream contains steam;

the fuel inlet stream comprises a hydrocarbon fuel inlet stream; and

the step of recycling comprises controllably recycling the first split fuel exhaust stream into the fuel inlet stream to achieve a steam to carbon ratio of between 2;

1 and 2.3;

1 in the fuel inlet stream.

4. The method of claim 3, further comprising varying an amount of fuel exhaust being recycled into the fuel inlet stream to continuously maintain the steam to carbon ratio of between 2:

1 and 2.3;

1 in the fuel inlet stream during operation of the fuel cell stack.

5. The method of claim 4, wherein the fuel cell stack comprises a solid oxide fuel cell stack and the fuel inlet stream comprises a methane or a natural gas fuel inlet stream.

6. The method of claim 5, further comprising:

providing the fuel inlet stream into a reformer;

reforming the fuel inlet stream in the reformer;

providing the reformed fuel inlet stream into the fuel cell stack; and

using at least one of radiative, convective or conductive heat generated in the fuel cell stack or an air exhaust stream from the fuel cell stack to heat the reformer.

7. The method of claim 1, wherein the first split fuel exhaust stream is lowered to a temperature of 200 C or less.

8. The method of claim 1, further comprising providing the second split fuel exhaust stream into a catalytic burner.

9. The method of claim 1, wherein the entire fuel exhaust stream is provided from the fuel cell stack directly into the fuel heat exchanger.

10. The method of claim 9, wherein only the fuel inlet stream and the entire fuel exhaust stream are provided into the fuel heat exchanger.

11. The method of claim 10, wherein the fuel heat exchanger is located upstream of the air preheater heat exchanger.

12. The method of claim 1, further comprising providing an air inlet stream into the fuel cell stack and heating the air inlet stream using the air exhaust stream in an air heat exchanger.