Lithium iron disulfide battery

• US 9,917,288 B2
• Filed: 10/12/2012
• Issued: 03/13/2018
• Est. Priority Date: 10/13/2011
• Status: Active Grant

• Current Assignee: Energizer Brands, LLC (Energizer Holdings, Inc.)
• Original Assignee: Energizer Brands, LLC (Energizer Holdings, Inc.)
• Inventors: Schubert, Mark A., Wendling, Matthew T., Huang, Weiwei
• Primary Examiner(s): Crepeau, Jonathan
• Assistant Examiner(s): Buchanan, Jacob
• Application Number:
  US13/650,417
• Publication Number:
  US 20130095358A1
• Time in Patent Office: 1,978 Days
• CPC Class Codes: H01M 50/44 Fibrous material
• CPC Class Codes: H01M 6/16 with organic electrolyte H01M6/18 takes precedence

Abstract

A lithium-iron disulfide battery with improved high temperature performance is disclosed. The separator characteristics are deliberately selected to be compatible with the electrolyte at the intended temperature. Additional or alternative modifications can be made in the form of a scaffold or laminated structure. A preferred polymer for such separators is polyimide.

Claims

1. An electrochemical cell comprising:

an anode consisting essentially of lithium or a lithium alloy;

a cathode coated onto a solid current collector, said cathode coating comprising iron disulfide as an active material;

a high temperature polymeric separator having a scaffold structure comprising a first polymer and filling polymer comprising a second polymer, wherein;

the first polymer is selected from;

polyimide, polyester, polyamide, poly(phthalamide), or poly(vinyl chloride); and

the second polymer is selected from;

poly(vinylidene fluoride), polyacrylate, or a polyethylene copolymer;

an electrolyte consisting of one or more solutes dissolved in one or more liquid solvents, said electrolyte being physically distinct from the separator;

wherein the anode, the cathode and the separator are spirally wound;

wherein the second polymer fills interstices of the scaffold structure and the electrolyte is at least partially absorbed by the second polymer; and

wherein the first polymer does not soften at an expected discharge temperature for the cell.

2. The cell according to claim 1, wherein the first polymer comprises polyimide and the expected discharge temperature is at least 90°

C.

3. The cell according to claim 1, wherein the high temperature polymeric separator is configured to impede separator penetration by a portion of the cathode.

4. The cell according to claim 1, wherein the separator has a thickness less than about 50 μ

m.

5. The cell according to claim 1, wherein the separator has a tensile strength of at least about 800 kgf/cm².

6. The cell according to claim 1, wherein the separator has an average dielectric breakdown voltage of at least about 1000 volts.

7. The cell according to claim 1, wherein the first polymer has a melting point greater than about 140°

C.

8. An electrochemical cell comprising:

an anode consisting essentially of lithium or a lithium alloy;

a cathode coated onto a solid current collector, said cathode coating comprising iron disulfide as an active material;

a high temperature polymeric separator having a scaffold structure comprising a first polymer and filling polymer comprising a second polymer;

an electrolyte consisting of one or more solutes dissolved in one or more liquid solvents, said electrolyte being physically distinct from the separator;

wherein the anode, the cathode and the separator are spirally wound;

wherein the scaffold structure is insoluble in the electrolyte and the filling polymer is soluble in the electrolyte and the filling polymer fills interstices of the scaffold structure and the electrolyte is at least partially absorbed by the filling polymer; and

wherein the scaffold structure does not soften at an expected discharge temperature for the cell.

9. The cell according to claim 8, wherein the first polymer comprises polyimide and the expected discharge temperature is at least 90°

C.

10. The cell according to claim 8, wherein the high temperature polymeric separator is configured to impede separator penetration by a portion of the cathode.

11. The cell according to claim 8, wherein the separator has a thickness less than about 50 nm.

12. The cell according to claim 8, wherein the separator has a tensile strength of at least about 800 kgf/cm².

13. The cell according to claim 8, wherein the separator has an average dielectric breakdown voltage of at least about 1000 volts.

14. The cell according to claim 8, wherein the first polymer has a melting point greater than about 140°

C.