Structurally controlled deposition of silicon onto nanowires

• US 9,923,201 B2
• Filed: 05/12/2015
• Issued: 03/20/2018
• Est. Priority Date: 05/12/2014
• Status: Active Grant

• Current Assignee: Amprius Technologies Incorporated (Amprius, Inc.)
• Original Assignee: Amprius, Inc.
• Inventors: Wang, Weijie, Liu, Zuqin, Han, Song, Bornstein, Jonathan, Stefan, Constantin Ionel
• Primary Examiner(s): Eoff, Anca
• Application Number:
  US14/710,103
• Publication Number:
  US 20150325852A1
• Time in Patent Office: 1,043 Days
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 2004/027 Negative electrodes
• CPC Class Codes: H01M 4/0428 Chemical vapour deposition
• CPC Class Codes: H01M 4/134 Electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/1395 of electrodes based on metals, Si or alloys
• CPC Class Codes: H01M 4/366 as layered products
• CPC Class Codes: H01M 4/386 Silicon or alloys based on silicon
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Provided herein are nanostructures for lithium ion battery electrodes and methods of fabrication. In some embodiments, a nanostructure template coated with a silicon coating is provided. The silicon coating may include a non-conformal, more porous layer and a conformal, denser layer on the non-conformal, more porous layer. In some embodiments, two different deposition processes, e.g., a PECVD layer to deposit the non-conformal layer and a thermal CVD process to deposit the conformal layer, are used. Anodes including the nanostructures have longer cycle lifetimes than anodes made using either a PECVD or thermal CVD method alone.

Claims

1. An anode for a lithium battery, comprising:

a substrate;

a nanowire template rooted to the substrate;

a first silicon layer substantially coating the nanowire template, the first silicon layer having a first density; and

a second silicon layer over the first silicon layer and any exposed nanowire template, the second silicon layer having a density higher than the density of the first silicon layer, wherein the first silicon layer is non-conformal to the nanowire template.

2. The anode of claim 1, wherein the first density is less than 2.2 g/cm³.

3. The anode of claim 1, wherein the first density is less than 2.1 g/cm³.

4. The anode of claim 1, wherein the second silicon layer has a density greater than 2.25 g/cm³.

5. The anode of claim 1, wherein the second silicon layer has a density at least 0.05 g/cm³ greater than that of the first silicon layer.

6. The anode of claim 1, wherein the second silicon layer has a density at least 0.15 g/cm³ greater than that of the first silicon layer.

7. The anode of claim 1, wherein the second silicon layer is conformal to the underlying surface.

8. The anode of claim 1, wherein the nanowire template comprises silicide nanowires.

9. The anode of claim 1, wherein the first silicon layer is between about 5 and 20 microns thick at its maximum diameter.

10. The anode of claim 1, wherein the second silicon layer is between about 5 and 500 nanometers thick.

11. The anode of claim 1, wherein the second silicon layer is about 5 and 100 nanometers thick.

12. A lithium battery, comprising:

an anode as in claim 1;

a lithium-containing cathode; and

an electrolyte in ionic communication with both the anode and the cathode.

13. The anode of claim 1, wherein the nanowire template has tips off the substrate and rooted ends at the substrate, and wherein first silicon layer is thicker at the tips than at the rooted ends.

14. The anode of claim 1, wherein there is essentially no silicon on the substrate.

15. An anode for a lithium battery, comprising:

a substrate;

a nanowire template rooted to the substrate;

a first silicon layer substantially coating the nanowire template, the first silicon layer having a first density; and

a second silicon layer over the first silicon layer and any exposed nanowire template, the second silicon layer having a density higher than the density of the first silicon layer, wherein the second silicon layer has a density at least 0.15 g/cm³ greater than the density of the first silicon layer.

16. The anode of claim 15, wherein the first density is less than 2.2 g/cm3.

17. The anode of claim 15, wherein the second silicon layer is conformal to the first silicon layer.

18. The anode of claim 15, wherein the nanowire template comprises silicide nanowires.

19. The anode of claim 15, wherein the first silicon layer is between about 5 and 20 microns thick at its maximum diameter.

20. The anode of claim 19, wherein the second silicon layer is between about 5 and 500 nanometers thick.

21. An anode for a lithium battery, comprising:

a substrate;

a nanowire template rooted to the substrate;

a first silicon layer substantially coating the nanowire template, the first silicon layer having a first density; and

a second silicon layer over the first silicon layer and any exposed nanowire template, the second silicon layer having a density higher than the density of the first silicon layer, wherein the first density is less than 2.1 g/cm³.

22. The anode of claim 21, wherein the second silicon layer is conformal to the first silicon layer.

23. The anode of claim 21, wherein the nanowire template comprises silicide nanowires.

24. The anode of claim 21, wherein the first silicon layer is between about 5 and 20 microns thick at its maximum diameter.

25. The anode of claim 24, wherein the second silicon layer is between about 5 and 500 nanometers thick.