Use of polyurethane powder as inner additive of redispersible polymer powder

• US 9,932,268 B2
• Filed: 10/24/2012
• Issued: 04/03/2018
• Est. Priority Date: 10/28/2011
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.), The Dow Chemical Company (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Dombrowski, Juergen, Kuehn, Hartmut, Perello, Margarita, Scharlemann, Sonja
• Primary Examiner(s): RIETH, STEPHEN EDWARD
• Application Number:
  US14/353,825
• Publication Number:
  US 20140288202A1
• Time in Patent Office: 1,987 Days
• Field of Search: None
• CPC Class Codes: C04B 16/082 other than polystyrene based, e.g. polyurethane foam
• CPC Class Codes: C04B 2103/0057 added as redispersable powders
• CPC Class Codes: C04B 24/2676 Polystyrenes
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 40/0039 Premixtures of ingredients
• CPC Class Codes: C08J 2300/12 Polymers characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
• CPC Class Codes: C08J 2309/06 Copolymers with styrene
• CPC Class Codes: C08J 2331/04 Homopolymers or copolymers of vinyl acetate
• CPC Class Codes: C08J 2375/04 Polyurethanes
• CPC Class Codes: C08J 3/005 Processes for mixing polymers
• CPC Class Codes: C08J 3/05 from solid polymers
• CPC Class Codes: C08J 3/12 Powdering or granulating

Abstract

A powdered polyurethane, preferably a powdered recycled polyurethane rigid foam is co-dried with a water insoluble film-forming polymer to obtain a redispersible polymer powder composite for use in hydraulic binders or cementitious compositions to improve performance of cementitious compositions or mortar, in applications such as cement based the adhesives (CBTA), or external thermal insulating composite systems (ETICS).

Claims

1. A water-redispersible polymer powder composite comprising a co-dried admixture of a water insoluble film-forming polymer, a colloidal stabilizer, and a powdered polyurethane foam, the amount of the powdered polyurethane foam being from 1% by weight to 99% by weight, based upon the total weight of the water-redispersible polymer powder composite, wherein the powdered polyurethane foam is a ground recycled rigid polyurethane foam having an average particle size of from 5 microns to 500 microns and the water-redispersible polymer powder composite has an average particle size of from 20 to 150 microns.

2. The water-redispersible polymer powder composite as claimed in claim 1 wherein the water insoluble film-forming polymer comprises a polymer prepared from a styrene and butadiene, a copolymer of styrene, butadiene and another comonomer, a vinylacetate ethylene (VAE) copolymer, a VAE/VA-VeoVA copolymer mixture, a polyurethane, a polyolefin, cellulose, a cellulose ether or a modified cellulose.

3. The water-redispersible polymer powder composite as claimed in claim 1 wherein the water insoluble film-forming polymer comprises a polymer prepared from styrene and butadiene, or a copolymer of styrene, butadiene and another monomer, or a vinylacetate-ethylene copolymer.

4. The water-redispersible polymer powder composite claimed in claim 1 wherein the amount of the powdered polyurethane foam is from 20% by weight to 70% by weight, based upon the total weight of the water-redispersible polymer powder composite.

7. A dry mix composition comprising cement ingredients and the water redispersible polymer powder composite as claimed in claim 1 in an amount of at least 0.1% by weight, based upon the weight of the dry mix composition.

5. A method for producing a water redispersible polymer powder composite comprising drying an aqueous mixture of a water insoluble film-forming polymer, a colloidal stabilizer, and a powdered polyurethane foam to obtain a water redispersible polymer powder composite, the amount of the powdered polyurethane foam being from 1% by weight to 99% by weight, based upon the total weight of the water-redispersible polymer powder composite, the powdered polyurethane foam being a ground recycled rigid polyurethane foam having an average particle size of from 5 microns to 500 microns, and the water-redispersible polymer powder composite having an average particle size from 20 to 150 microns.

6. The method for producing a water redispersible polymer powder composite as claimed in claim 5 wherein the water insoluble film-forming polymer comprises a polymer prepared from a styrene and butadiene, a copolymer of styrene, butadiene and another comonomer, a vinylacetate ethylene (VAE) copolymer, a VAE/VA-VeoVA copolymer mixture, a polyurethane, a polyolefin, a cellulose, or a cellulose derivative, the amount of the powdered polyurethane foam is from 20% by weight to 70% by weight, based upon the total weight of the water-redispersible polymer powder composite, and the powdered polyurethane foam has an average particle size of from 20 microns to 150 microns.