Strengthened glass articles having etched features and methods of forming the same

• US 9,938,186 B2
• Filed: 03/13/2013
• Issued: 04/10/2018
• Est. Priority Date: 04/13/2012
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Moll, Johannes, Price, James Joseph, Ruffin, Alranzo Boh, Tsuda, Sergio, Wagner, Robert Stephen, Watkins, James Joseph
• Primary Examiner(s): Handville, Brian
• Application Number:
  US13/800,033
• Publication Number:
  US 20130273324A1
• Time in Patent Office: 1,854 Days
• Field of Search: 428156, 428161, 428172
• CPC Class Codes: B41M 5/24 Ablative recording, e.g. by burning marks; Spark recording marking by high energetic means, e.g. by laser otherwise than burning or ablative removal B41M5/26; materials or methods for recording or reproduction by optical means G11B7/00
• CPC Class Codes: B44C 1/227 by etching
• CPC Class Codes: B44C 1/228 by laser radiation
• CPC Class Codes: C03C 21/002 to perform ion-exchange between alkali ions C03C21/005 takes precedence
• CPC Class Codes: C03C 23/0025 by a laser beam
• CPC Class Codes: Y10T 428/24479 including variation in thickness
• CPC Class Codes: Y10T 428/24521 with component conforming to contour of nonplanar surface

Abstract

Strengthened glass articles having laser etched features, electronic devices, and methods of fabricating etched features in strengthened glass articles are disclosed. In one embodiment, a strengthened glass article includes a first strengthened surface layer and a second strengthened surface layer under a compressive stress and extending from a first surface and a second surface, respectively, of the strengthened glass article to a depth of layer, and a central region between the first strengthened surface layer and the second strengthened surface layer that is under tensile stress. The strengthened glass article further includes at least one etched feature formed by laser ablation within the first surface or the second surface having a depth that is less than the depth of layer and a surface roughness that is greater than a surface roughness of the first surface or second surface outside of the at least one etched feature.

Claims

1. An electronic device comprising:

a touchscreen comprising a strengthened glass article, wherein the strengthened glass article of the touchscreen comprises;

a first surface and a second surface, wherein the first surface comprises a top surface for receiving user input;

a first strengthened surface layer and a second strengthened surface layer under a compressive stress and extending from the first surface and the second surface, respectively, of the strengthened glass article to a depth of layer, and a central region between the first strengthened surface layer and the second strengthened surface layer that is under tensile stress; and

at least one etched feature within the first surface, the at least one etched feature comprising a depth that is less than the depth of layer and a surface roughness that is greater than a surface roughness of the first surface outside of the at least one etched feature, and the at least one etched feature comprises a plurality of defect lines separated by a separation distance of between about 1 μ

m and about 3 μ

m such that the plurality of defect lines create a diffractive grating within the boundary of the at least one etched feature, wherein the at least one etched feature is formed by laser ablation; and

one or more layers of material disposed on the first surface of the strengthened glass article and the etched feature, wherein at least one of the one or more layers of material comprise an iridescent material layer disposed on the at least one etched feature and not disposed on at least a portion of the first surface surrounding the at least one etched feature.

2. The electronic device of claim 1, wherein the depth of the at least one etched feature is within a range of about 10 μ

m to about 40 μ

m.

3. The electronic device of claim 1, wherein the depth of layer of the strengthened glass article is greater than 5 μ

m and has a surface compression of greater than about 100 MPa.

4. The electronic device of claim 1, wherein the at least one etched feature is defined by a plurality of intersecting defect lines that form a cross-hatch defect pattern.

5. The electronic device of claim 1, wherein the at least one etched feature is defined by a two-dimensional pattern or a three-dimensional pattern within a boundary of the at least one etched feature.

6. The electronic device of claim 1, wherein the at least one etched feature comprises a wall that separates the at least one etched feature from the portion of the first surface surrounding the at least one etched feature.

7. The electronic device of claim 1, wherein the iridescent material layer comprises a thickness that is less than the depth of the at least one etched feature.