Solid electrolytic capacitor with interlayer crosslinking

• US 9,941,055 B2
• Filed: 06/18/2015
• Issued: 04/10/2018
• Est. Priority Date: 02/27/2012
• Status: Active Grant

• Current Assignee: Kemet Electronics Corporation (Yageo Corporation)
• Original Assignee: Kemet Electronics Corporation (Yageo Corporation)
• Inventors: Chacko, Antony P, Hui, Danny Yiu Kai
• Primary Examiner(s): HA, NGUYEN T
• Application Number:
  US14/743,195
• Publication Number:
  US 20150287538A1
• Time in Patent Office: 1,027 Days
• CPC Class Codes: H01G 9/0036 Formation of the solid electrolyte layer
• CPC Class Codes: H01G 9/012 specially adapted for solid capacitors
• CPC Class Codes: H01G 9/028 Organic semiconducting electrolytes, e.g. TCNQ
• CPC Class Codes: H01G 9/0425 specially adapted for cathode
• CPC Class Codes: H01G 9/08 Housing; Encapsulation
• CPC Class Codes: H01G 9/15 Solid electrolytic capacitors H01G11/00 takes precedence

Abstract

A method for preparing a solid electrolytic capacitor and an improved solid electrolytic capacitor is provided. The method includes providing an anode, forming a dielectric on the anode, forming a cathode on the dielectric and forming subsequent layers on the cathode wherein the cathode and subsequent layers preferably comprise interlayers. At least one interlayer comprises a monomer, oligomer or polymer with multifunctional or multiple reactive groups and an adjacent layer comprises a molecule with crosslinkable functionality. The oligomer or polymer with multifunctional or multiple reactive groups on one layer react with the crosslinkable functionality in the adjacent layer.

Claims

1. A method for preparing a solid electrolytic capacitor comprising:

providing an anode;

forming a dielectric on said anode;

forming a cathode on said dielectric wherein said cathode comprises a metal containing layer;

forming a protective coating on said metal containing layer with said metal layer between said cathode and said protective coating wherein said protective layer comprises a monomer, oligomer or polymer with multifunctional or multiple reactive groups and an adjacent layer wherein said adjacent layer is adjacent to said protective layer comprises a molecule with crosslinkable functionality; and

wherein said oligomer or polymer with multifunctional or multiple reactive groups on one layer react with said crosslinkable functionality in said adjacent layer.

2. The method for preparing a solid electrolytic capacitor of claim 1 wherein said adjacent layer is a second metal containing layer.

3. The method for preparing a solid electrolytic capacitor of claim 1 further comprising attaching a cathode lead to a first protective coating of said protective coating.

4. The method for preparing a solid electrolytic capacitor of claim 3 further comprising forming a second protective coating of said protective coating on said cathode lead.

5. The method for preparing a solid electrolytic capacitor of claim 1 wherein said forming a protective coating comprises forming a second protective coating as an adjacent layer to a first protective coating.

6. The method for preparing a solid electrolytic capacitor of claim 5 further comprising crosslinking said second protective coating to said first protective coating.

7. The method for preparing a solid electrolytic capacitor of claim 1 further comprising forming an encapsulating layer as said adjacent layer on said protective coating.

8. The method for preparing a solid electrolytic capacitor of claim 7 further comprising crosslinking said encapsulating layer to said protective coating.

9. The method for preparing a solid electrolytic capacitor of claim 1 wherein said cathode comprises at least one intrinsically conductive polymer layer.

10. The method for preparing a solid electrolytic capacitor of claim 9 wherein said intrinsically conducting polymer is polyethylene dioxythiophene.

11. The method for preparing a solid electrolytic capacitor of claim 1 wherein said cathode comprises at least one carbon containing layer.

12. The method for preparing a solid electrolytic capacitor of claim 1 wherein said metal of said metal containing layer is selected from silver, copper, and nickel.

13. The method for preparing a solid electrolytic capacitor of claim 1 wherein said reactive groups are selected from hydroxyl, carboxylic acid, epoxy, amine, anhydride functional group, polyester, urethane, amide, imide, and epoxy functional molecules.

14. The method for preparing a solid electrolytic capacitor of claim 13 wherein said hydroxy number is from about 50 to 100 (mg KOH/g resin solids).

15. The method for preparing a solid electrolytic capacitor of claim 1 wherein said crosslinkable functionality is selected from the group consisting of carboxylic, hydroxyl, amine, epoxy, anhydride, isocyanate, imide and amide.

16. The method for preparing a solid electrolytic capacitor of claim 1 wherein said crosslinkable functionality includes compounds and polymers comprising melamines, isocyanates, epoxies, hexamethoxymelamines, crosslinkable polyesters, glyoxals, furfural aldehydes and melamine formaldehyde condensates.

17. The method for preparing a solid electrolytic capacitor of claim 16 wherein said molecule with crosslinkable functionality is hexakis (methoyxymethyl) melamine.

18. The method for preparing a solid electrolytic capacitor of claim 1 wherein said oligomer or polymer is a polyester comprising carboxylic acid with an acid number of from about 3 to 100 (mg KOH/g resin solids).

19. The method for preparing a solid electrolytic capacitor of claim 18 wherein said acid number is 20-50 (mg KOH/g resin solids).

20. The method for preparing a solid electrolytic capacitor of claim 18 wherein said acid number is or 50-100 (mg KOH/g resin solids).

21. The method for preparing a solid electrolytic capacitor of claim 18 wherein said oligomer or polymer is a polyester comprising carboxylic acid with an hydroxy number of from about 3 to 200 (mg KOH/g resin solids).

22. The method for preparing a solid electrolytic capacitor of claim 1 wherein said anode comprises a valve metal preferably selected from the group consisting of Al, Ta, Nb and NbO.

23. The method for preparing a solid electrolytic capacitor of claim 1 wherein said cathode layer further comprises organic or inorganic particles of fibers with reactive functional groups.

24. The method for preparing a solid electrolytic capacitor of claim 23 wherein said inorganic particles are selected from nanoparticles, microparticles, functionalized particles, fibers or one interlayer is crosslinked with either functionalized polymer or functionalized particles of an adjacent interlayer.

25. A capacitor made by the method of claim 1.

26. A capacitor comprising:

an anode;

a dielectric on said anode;

a cathode on said dielectric;

a metal containing layer on said cathode;

a protective coating on said metal containing layer; and

wherein said protective coating comprises a monomer, oligomer or polymer with multifunctional or multiple groups and an adjacent layer comprises a molecule with cross-linked to said multifunctional or multiple groups.

27. The capacitor of claim 26 wherein said cathode comprises at least one selected from chemically polymerized intrinsically conducting polymer, electrochemically polymerized intrinsically conducting polymer, and a layer formed from a prepolymerized intrinsically conducting polymer dispersion.

28. The capacitor of claim 26 wherein at least one said cathode or said protective layer further comprises at least one of organic or inorganic particles or fibers with reactive functional groups, carbon particle filled polymer, a metal particle filled polymer, a conductive particle filled polymer, particles of fibers with reactive functional groups or crosslinkable groups.

29. The capacitor of claim 26 where said molecule is selected from the group consisting of polyurethane, polyester, polyamide, polyimide, epoxy, butyral and phenolic.

30. The capacitor of claim 29 wherein said polyester has an acid number of from about 3 to 200 and a hydroxy number of from about 3 to 200.

31. The capacitor of claim 26 wherein the polymer with multifunctional or multiple groups is selected from polyester, polyurethane, polyamide, polyamine, polyamide, polyimide, silicone polyester, hydroxyl functional silicone, hydroxyethyl cellulose, polyvinyl alcohol, phenolic, epoxy, butyral, copolymers.

32. The capacitor of claim 26 wherein said cathode comprises a metal containing layer as said adjacent layer.

33. The capacitor of claim 32 wherein said metal of said metal containing layer is selected from silver, copper, and nickel.

34. The capacitor of claim 26 further comprising a cathode lead attached to a first protective coating of said protective coating.

35. The capacitor of claim 34 further comprising forming a second protective coating of said protective coating on said cathode lead.

36. The capacitor of claim 26 wherein said protective coating comprises a second protective coating as an adjacent layer to a first protective coating.

37. The capacitor of claim 36 wherein said second protective coating is crosslinked to said first protective coating.

38. The capacitor of claim 26 further comprising an encapsulating layer as said adjacent layer.

39. The capacitor of claim 38 further wherein said encapsulating layer is crosslinked to said protective coating.

40. The capacitor of claim 26 wherein said cathode comprises at least one intrinsically conductive polymer layer.

41. The capacitor of claim 40 wherein said intrinsically conducting polymer is polyethylene dioxythiophene.

42. The capacitor of claim 26 wherein said cathode comprises at least one carbon containing layer.

43. The capacitor of claim 26 wherein said reactive groups are selected from hydroxyl, carboxylic acid, epoxy, amine, anhydride functional group, polyester, urethane, amide, imide, and epoxy functional molecules.

44. The capacitor of claim 26 wherein said crosslinkable functionality is selected from the group consisting of carboxylic, hydroxyl, amine, epoxy, anhydride, isocyanate, imide and amide.

45. The capacitor of claim 26 wherein said crosslinkable functionality includes compounds and polymers comprising melamines, isocyanates, epoxies, hexamethoxymelamines, crosslinkable polyesters, glyoxals, furfural aldehydes and melamine formaldehyde condensates.

46. The capacitor of claim 45 wherein said molecule with crosslinkable functionality is hexakis (methoyxymethyl) melamine.

47. The capacitor of claim 26 wherein said anode comprises a valve metal preferably selected from the group consisting of Al, Ta, Nb and NbO.