Detection of volatile chemicals using an RFID sensing system

• US 9,945,793 B2
• Filed: 10/10/2016
• Issued: 04/17/2018
• Est. Priority Date: 03/11/2013
• Status: Active Grant

• Current Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Original Assignee: Empire Technology Development LLC (Allied Inventors Management, LLC)
• Inventors: Roundhill, David Max
• Primary Examiner(s): Siefke, Samuel P
• Application Number:
  US15/289,714
• Publication Number:
  US 20170030843A1
• Time in Patent Office: 554 Days
• CPC Class Codes: G01N 22/00 Investigating or analysing materials by the use of microwaves or radio waves, i.e. electromagnetic waves with a wavelength of one millimetre or more G01N3/00 - G01N17/00, G01N24/00 take precedence
• CPC Class Codes: G01N 27/025 a current being generated within the material by induction
• CPC Class Codes: G01N 27/122 Circuits particularly adapted therefor, e.g. linearising circuits
• CPC Class Codes: G01N 27/416 Systems G01N27/27 takes precedence
• CPC Class Codes: G01N 33/0042 for SO2, SO3
• CPC Class Codes: G01N 33/0044 for H2S, sulfides
• CPC Class Codes: G01N 33/0075 for multiple spatially distributed sensors, e.g. for environmental monitoring transmission systems for measured values G08C

Abstract

Methods, systems, and apparatuses, including computer programs encoded on computer-readable media, for monitoring volatile chemicals. A system includes an radio-frequency identification (RFID) tag composed of a patterned metal. The patterned metal is configured to absorb a volatile chemical. The RFID tag includes a non-volatile memory configured to store identification data. The RFID tag also includes a receiver that receives a signal at a frequency in a frequency range. The frequency is based upon an amount of the volatile chemical absorbed in the patterned metal. A transmitter of the RFID tag transmits the identification data in response to receiving the signal. The strength of the transmitted identification data is based upon an amount of the absorbed volatile chemical.

Claims

1. A non-transitory computer-readable medium having stored thereon computer-executable instructions that, in response to execution by one or more processors, cause the one or more processors to perform or control performance of operations to:

broadcast a request signal over a request frequency range;

obtain a first response from a radio-frequency identification (RFID) tag, in response to the broadcast of the request signal at a first request frequency within the request frequency range, wherein the RFID tag is composed of a patterned metal, and wherein the patterned metal absorbs a first volatile chemical;

send a first command to the RFID tag at the first request frequency to open a first valve, wherein the first valve allows a fluid to flow over the RFID tag;

send a second command to the RFID tag at the first request frequency to close the first valve; and

determine a level of the first volatile chemical absorbed in the patterned metal based upon the first request frequency.

2. The non-transitory computer-readable medium of claim 1, wherein the computer-executable instructions that, in response to execution, further cause the one or more processors to perform at least one operation to:

obtain a second response from the RFID tag, in response to the broadcast of the request signal at a second request frequency within the request frequency range, wherein the patterned metal absorbs a second volatile chemical; and

determine a level of the second volatile chemical absorbed in the patterned metal based upon the second request frequency.

3. The non-transitory computer-readable medium of claim 1, wherein the patterned metal absorbs the first volatile chemical from the fluid.

4. The non-transitory computer-readable medium of claim 1, wherein the patterned metal comprises gold or silver.

5. The non-transitory computer-readable medium of claim 4, wherein the first volatile chemical absorbed by the patterned metal comprises one of a sulfide and a thiol.

6. The non-transitory computer-readable medium of claim 1, wherein the patterned metal comprises platinum or tungsten.

7. The non-transitory computer-readable medium of claim 6, wherein the first volatile chemical absorbed by the patterned metal comprises sulphur dioxide.

8. A sensor to detect a volatile chemical, the sensor comprising:

a chamber that comprises a polymer section, wherein the chamber is configured to allow a flow of a fluid, and wherein the chamber is connected to the polymer section through one or more valves;

a substrate attached onto an inner wall of the polymer section of the chamber; and

a radio-frequency identification (RFID) tag formed on a surface of the substrate, wherein the RFID tag is communicatively coupled to an RFID reader, and wherein the RFID tag is composed of a patterned metal configured to absorb the volatile chemical, the RFID tag comprising;

a non-volatile memory having stored thereon computer executable instructions that, in response to execution by one or more processors, cause the one or more processors to perform or control performance of operations to;

obtain a request signal at a frequency in a frequency range, wherein the frequency is based upon an amount of the volatile chemical absorbed in the patterned metal, wherein a first signal is obtained from the RFID reader to open the one or more valves, and wherein a second signal is obtained from the RFID reader to close the one or more valves; and

transmit identification data in response to the obtained request signal, wherein a strength of the transmitted identification data is based upon the amount of the volatile chemical absorbed in the patterned metal.

9. The sensor of claim 8, wherein the patterned metal is configured to absorb the volatile chemical from the fluid.

10. The sensor of claim 8, wherein a strength of the request signal is based upon the amount of the volatile chemical absorbed in the patterned metal.

11. The sensor of claim 8, wherein the RFID reader is configured to:

broadcast the request signal over a plurality of frequencies in a request frequency range;

receive a response from the RFID tag at a particular request frequency; and

determine a level of the volatile chemical absorbed in the patterned metal based upon a strength of the received response from the RFID tag and the particular request frequency.

12. The sensor of claim 8, wherein the polymer section comprises polytetraflouroethylene.

13. The sensor of claim 8, wherein the substrate comprises one of a polyimide film and a biaxially-oriented polyethylene terephthalate.

14. The sensor of claim 8, wherein the patterned metal comprises gold or silver.

15. The sensor of claim 14, wherein the volatile chemical absorbed by the patterned metal comprises one of a sulfide or a thiol.

16. The sensor of claim 8, wherein the patterned metal comprises platinum or tungsten.

17. The sensor of claim 16, wherein the volatile chemical absorbed by the patterned metal comprises sulphur dioxide.