Composite sampling of fluids

• US 9,945,821 B2
• Filed: 07/21/2015
• Issued: 04/17/2018
• Est. Priority Date: 01/27/2012
• Status: Active Grant

• Current Assignee: SGS North America Incorporated (SGS SA)
• Original Assignee: SGS North America Incorporated (SGS SA)
• Inventors: Kriel, Wayne A., Lataire, Sven
• Primary Examiner(s): Williams, Hezron E
• Assistant Examiner(s): Devito, Alex
• Application Number:
  US14/804,846
• Publication Number:
  US 20150323508A1
• Time in Patent Office: 1,001 Days
• CPC Class Codes: G01N 1/22 in the gaseous state specially adapted for biological material G01N33/497; measuring breath flow A61B5/087
• CPC Class Codes: G01N 1/2247 Sampling from a flowing stream of gas
• CPC Class Codes: G01N 1/24 Suction devices G01N1/22 - G01N1/2294 take precedence
• CPC Class Codes: G01N 2001/105 from high-pressure reactors or lines
• CPC Class Codes: G01N 2001/1093 Composite sampling; Cumulative sampling
• CPC Class Codes: G01N 2030/025 Gas chromatography
• CPC Class Codes: G01N 30/06 Preparation
• CPC Class Codes: G01N 30/28 Control of physical parameters of the fluid carrier
• CPC Class Codes: G01N 33/225 Gaseous fuels, e.g. natural gas

Abstract

Composite sampling of a fluid flowing through a conduit includes collecting, in a vessel coupled to the conduit through which the fluid is flowing, a first discrete sample of fluid from the conduit, the first discrete sample having a first selected volume, and collecting, in the vessel and at a first interval from the first sample, a second discrete sample of the fluid from the conduit, the second discrete sample having a second selected volume, thereby forming a composite sample in the vessel while the vessel is coupled to conduit. The composite sample includes the first discrete sample and the second discrete sample, and may include one or more additional discrete samples. An apparatus for collecting the composite sample includes a gas chromatograph, and is arranged such that the composite sample is provided to the gas chromatograph without removing the composite sample from the apparatus or transporting the composite sample.

Claims

1. A method comprising:

collecting, in a vessel coupled to a gas chromatograph and to a conduit through which a fluid is flowing, a first discrete sample of fluid from the conduit, the first discrete sample having a first selected volume;

collecting, in the vessel and at a first interval from the first discrete sample, a second discrete sample of the fluid from the conduit, the second discrete sample having a second selected volume, thereby forming a composite sample in the vessel while the vessel is coupled to conduit, the composite sample comprising the first discrete sample and the second discrete sample; and

transferring the composite sample from the vessel to the gas chromatograph.

2. The method of claim 1, further comprising assessing the composition of the composite sample with the gas chromatograph.

3. The method of claim 1, further comprising controlling the collection of the first discrete sample, the collection of the second discrete sample, the transfer of the composite sample, or any combination thereof with a controller.

4. The method of claim 3, further comprising controlling the first selected volume of the first discrete sample and the second selected volume of the second discrete sample with the controller.

5. The method of claim 3, further comprising controlling the first interval with the controller.

6. The method of claim 3, further comprising controlling the controller via a computer operatively coupled to the controller.

7. The method of claim 1, wherein the first selected volume and the second selected volume are user-selectable.

8. The method of claim 1, wherein the gas chromatograph is coupled to the conduit and further comprising transferring a non-composite sample of the fluid flowing through the conduit to the gas chromatograph.

9. The method of claim 8, further comprising assessing the composition of the non-composite sample with the gas chromatograph.

10. The method of claim 1, wherein the first interval is based on elapsed time between the first discrete sample and the second discrete sample or on a volume of fluid flow in the conduit.

11. The method of claim 1, wherein the gas chromatograph is coupled to an additional conduit and receives a sample of additional fluid via the additional conduit.

12. The method of claim 11, further comprising assessing the composition of the sample of the additional fluid with the gas chromatograph.

13. The method of claim 1, further comprising regulating the pressure of the fluid between the conduit and the vessel.

14. The method of claim 1, further comprising collecting, in the vessel and at a second interval from the second discrete sample, a third discrete sample of the fluid from the conduit, the third discrete sample having a third selected volume, thereby forming a composite sample in the vessel while the vessel is coupled to conduit, the composite sample comprising the first discrete sample, the second discrete sample, and the third discrete sample.

15. The method of claim 1, further comprising vaporizing the first discrete sample before collecting the first discrete sample in the vessel.

16. The method of claim 1, further comprising vaporizing the second discrete sample before collecting the second discrete sample in the vessel.

17. The method of claim 1, further comprising vaporizing the composite sample before the fluid is vaporized before transferring the composite sample to the gas chromatograph.