Water treatment process and water treatment system
First Claim
1. A water treatment process comprising:
- a scale inhibitor supplying step of supplying a calcium scale inhibitor which is a scale inhibitor for inhibiting the deposition of a scale containing calcium to water containing Ca2+ ions, SO42−
ions, carbonate ions and silica;
a pH adjusting step of adjusting the water to a pH of 10 or more at which the silica is soluble in the water;
a demineralizing step of separating the water into concentrated water in which the Ca2+ ions, the SO42−
ions, the carbonate ions and the silica are concentrated and treated water after the scale inhibitor supplying step and the pH adjusting step; and
a crystallizing step of supplying seed crystals of gypsum to the concentrated water so that gypsum is crystallized from the concentrated water; and
an upstream side precipitating step of precipitating at least calcium carbonate from the water so that the concentration of the calcium carbonate in the water is reduced, before the scale inhibitor supplying step and the pH adjusting step.
2 Assignments
0 Petitions
Accused Products
Abstract
In a water treatment system (1) and a water treatment process, a scale inhibitor is supplied to water to be treated containing Ca ions, SO4 ions, carbonate ions, and silica, and the water to be treated is adjusted to a pH at which silica is soluble. The pH-adjusted water to be treated containing the calcium scale inhibitor is separated in a demineralizing section (10) into concentrated water and treated water. In a crystallizing section (20), seed crystals of gypsum are supplied to the concentrated water, whereby gypsum is crystallized and removed. Silica in the water to be treated is removed from the concentrated water on the downstream side of the crystallizing section (20). Calcium carbonate in the water to be treated is removed from the concentrated water on the upstream side of the demineralizing section (10) or the downstream side of the crystallizing section (20).
44 Citations
18 Claims
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1. A water treatment process comprising:
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a scale inhibitor supplying step of supplying a calcium scale inhibitor which is a scale inhibitor for inhibiting the deposition of a scale containing calcium to water containing Ca2+ ions, SO42−
ions, carbonate ions and silica;a pH adjusting step of adjusting the water to a pH of 10 or more at which the silica is soluble in the water; a demineralizing step of separating the water into concentrated water in which the Ca2+ ions, the SO42−
ions, the carbonate ions and the silica are concentrated and treated water after the scale inhibitor supplying step and the pH adjusting step; anda crystallizing step of supplying seed crystals of gypsum to the concentrated water so that gypsum is crystallized from the concentrated water; and an upstream side precipitating step of precipitating at least calcium carbonate from the water so that the concentration of the calcium carbonate in the water is reduced, before the scale inhibitor supplying step and the pH adjusting step. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9)
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10. A water treatment system comprising:
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a scale inhibitor supplying section that supplies a calcium scale inhibitor which is a scale inhibitor for inhibiting the deposition of a scale containing calcium to water containing Ca2+ ions, SO42−
ions, carbonate ions and silica;a pH adjusting section that supplies a pH adjuster to the water to adjust the pH of the water to 10 or more such that the silica is soluble in the water; a demineralizing section that is positioned on a downstream side of the scale inhibitor supplying section and the pH adjusting section and separates the water into concentrated water in which the Ca2+ ions, the SO42−
ions, the carbonate ions and the silica are concentrated and treated water;a crystallizing section including a crystallizing tank that is positioned on a downstream side of the demineralizing section and crystallizes gypsum from the concentrated water and a seed crystal supplying section that supplies seed crystals of gypsum to the crystallizing tank; and an upstream side precipitating section, on an upstream side of the scale inhibitor supplying section and the pH adjusting section, that precipitates at least calcium carbonate from the water so that the concentration of the calcium carbonate in the water is reduced. - View Dependent Claims (11, 12, 13, 14, 15, 16, 17, 18)
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Specification