Manufacturing of nitrogen-containing materials

• US 9,950,966 B2
• Filed: 07/03/2013
• Issued: 04/24/2018
• Est. Priority Date: 07/05/2012
• Status: Active Grant

• Current Assignee: Gestalt Chemical Products Incorporated
• Original Assignee: Gestalt Chemical Products Incorporated
• Inventors: Oliferenko, Alexander
• Primary Examiner(s): Smith, Jennifer A
• Application Number:
  US14/412,662
• Publication Number:
  US 20150321967A1
• Time in Patent Office: 1,756 Days
• CPC Class Codes: C04B 18/20 from macromolecular compounds
• CPC Class Codes: C04B 18/22 Rubber , e.g. ground waste tires
• CPC Class Codes: C04B 18/24 Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper , cork
• CPC Class Codes: C04B 20/023 Chemical treatment
• CPC Class Codes: C05C 11/00 Other nitrogenous fertilisers
• CPC Class Codes: C05C 3/00 Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
• CPC Class Codes: C09K 17/14 containing organic compounds only
• CPC Class Codes: C09K 17/48 Organic compounds mixed with inorganic active ingredients, e.g. polymerisation catalysts
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete

Abstract

It has been discovered that waste cross-linked polymer materials both synthetic (scrap tire rubber, used polyurethane, and epoxy and phenol resins in discarded printed circuit boards) and natural (wood biomass, keratin, and chitin) can be conveniently depolymerized at slightly elevated temperatures and moderate pressures by the action of a liquid chemical reagent. The proposed inexpensive process results in a substantial to total depolymerization of synthetic polymers and thereby recovers valuable liquid and solid materials. When applied to lignocellulosic biomass, the proposed process, depending on the reaction conditions, either unlocks the lignin-hemicellulose matrix making cellulose more available for fermenting microorganisms or results in carbonization, or coalification of the biomass that may be desirable in terms of sequestering excessive carbon from the Earth'"'"'s biosphere.

Claims

1. A process for producing a nitrogen-containing product, the process comprising:

(a) combining rubber and a chemical reagent in a hermetically sealed reaction vessel, wherein the chemical reagent is made by combining a fist agent of ammonia, anhydrous ammonia or a combination thereof, and a second agent of chloroalkane, dichloromethane or combination thereof;

(b) heating the contents of the said reaction vessel to a temperature of between about 20-250°

C.

2. The process of claim 1, wherein the reaction vessel is under external pressure while heating the contents of the said reaction vessel.

3. The process of claim 1, wherein the heating is at a maximum temperature of between about 50-250°

C.

4. The process of claim 1, wherein the heating is at a maximum temperature of between about 80-120°

C.

5. The process of claim 1, wherein the heating is at a maximum temperature of between about 50-250°

C. for between about 1 minute and 24 hours.

6. The process of claim 1, wherein the heating is conducted with the pressure in the reaction vessel ranging from between about 1 bar to 275 bar (from 14.5 to 4,000 psi).

7. The process of claim 1, further comprising allowing the heated reaction vessel to cool to room temperature.

8. The process of claim 1, further comprising allowing the rubber and chemical reagent mixture to remain in the reaction vessel at room temperature for between about 1 to 600 minutes prior to heating.

9. The process of claim 1, wherein said first agent and said second agent are in a mole-to-mole ratio which ranges from about 1:

10 to 10;

1, respectively.

10. The process of claim 1, wherein step (a) further includes at least one of, switchgrass, corn stover, sugarcane bagasse, straw, algae, seaweed, peat, lignite, coal, leather, tanning waste, wool, other keratin-containing animal products, fabric cuttings, or chitin.

11. The process of claim 1 further comprising making the chemical reagent by combining at least one of ammonia, anhydrous ammonia or a combination thereof, and at least one of a chloroalkane, dichloromethane or combination thereof prior to combining the rubber with the chemical reagent.

12. A process comprising:

(a) combining rubber and a chemical reagent in a hermetically sealed reaction vessel, wherein the chemical reagent is made by combining a first agent of ammonia, anhydrous ammonia or a combination thereof, and a second agent of chloroalkane, dichloromethane or combination thereof;

(b) heating the contents of the said reaction vessel to a temperature of between about 20-250°

C.

13. The process of claim 12 further comprising producing the chemical reagent by combining said first agent and said second agent prior to combining the rubber with the chemical reagent.

14. A process for producing a nitrogen-containing product produced by the process of:

(a) making a chemical reagent by combining a first agent of ammonia, anhydrous ammonia or a combination thereof, with a second agent of a chloroalkane, dichloromethane or combination thereof;

(b) combining artificial and/or natural cross-linked polymeric material and the chemical reagent in a hermetically sealed reaction vessel;

(c) allowing the polymeric material and chemical reagent mixture to remain in the reaction vessel at room temperature for between about 1 to 600 minutes prior to heating; and

(d) heating the contents of the said reaction vessel to a temperature of between about 20-250°

C.

15. The process of claim 14, wherein the polymeric material is scrap tires, discarded polyurethane items, used PET bottles, scrap PVC items, or printed circuit boards.

16. The process of claim 14, wherein step (a) further includes at least one of, switchgrass, corn stover, sugarcane bagasse, straw, algae, seaweed, peat, lignite, coal, leather, tanning waste, wool, other keratin-containing animal products, fabric cuttings, or chitin.