Herbicide formulations

• US 9,961,900 B2
• Filed: 06/11/2013
• Issued: 05/08/2018
• Est. Priority Date: 06/11/2012
• Status: Active Grant

• Current Assignee: Vive Crop Protection Inc.
• Original Assignee: Vive Crop Protection Inc.
• Inventors: Anderson, Darren J., Das, Anjan Kumar, Dinglasan, Jose Amado, Li, Fugang, Norton, Danielle
• Primary Examiner(s): Pryor, Alton N
• Application Number:
  US14/406,855
• Publication Number:
  US 20150141249A1
• Time in Patent Office: 1,792 Days
• Field of Search: None
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: A01N 25/10 Macromolecular compounds
• CPC Class Codes: A01N 25/14 wettable
• CPC Class Codes: A01N 25/22 containing ingredients stabilising the active ingredients
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 25/32 Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
• CPC Class Codes: A01N 43/653 1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
• CPC Class Codes: A01N 43/76 1,3-Oxazoles; Hydrogenated 1,3-oxazoles
• CPC Class Codes: A01N 43/90 having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
• CPC Class Codes: A01N 47/36 containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

Abstract

The present disclosure describes a formulation comprising a nanoparticle including a polymer-associated herbicide, such as fenoxaprop or pyroxsulam with an average diameter of between about 1 nm and about 500 nm; wherein the polymer is a polyelectrolyte and a dispersant or a wetting agent. The disclosure describes various formulations and formulating agents that can be included in the formulations.

Claims

1. A formulation comprising:

nanoparticles comprising polymer-associated herbicide compound comprising a polymer and a herbicide compound with an average diameter of between about 1 nm and about 500 nm,

wherein the polymer is a polyelectrolyte copolymer comprised of between 50 weight percent and 95 weight percent methacrylic acid monomers and between 50 weight percent and 5 weight percent ethyl acrylate or styrene monomers, and the polymer-associated herbicide compound makes up between about 20 weight percent and about 50 weight percent of the formulation;

between about 0.5 weight percent and about 5 weight percent of a dispersant;

between about 0.5 weight percent and about 5 weight percent of a wetting agent;

between about 0.01 weight percent and about 0.2 weight percent of a preservative;

between about 0.05 weight percent and about 5 weight percent of an anti-foaming agent; and

water.

2. The formulation of claim 1, wherein the herbicide compound is selected from the group consisting of aryloxyphenoxypopionates, cyclohexanediones, triazolinone inhibitors of PPO, and ALS inhibitors.

3. The formulation of claim 1, further comprising a herbicide safener associated with the polymer.

4. The formulation of claim 3, wherein the herbicide safener is selected from the group consisting of mefenpyr-diethyl, isoxadifen-ethyl, cloquintocet-mexyl and combinations thereof.

5. The formulation of claim 4, wherein a ratio of a weight percent of the herbicide safener to a weight percent of the herbicide compound is between about 100:

1 and about 1;

100.

6. The formulation of claim 3, wherein the herbicide safener is between about 1 weight percent and about 20 weight percent of the formulation.

7. The formulation of claim 1, wherein the nanoparticles have an average diameter of between about 1 nm and about 100 nm.

8. The formulation of claim 1, wherein the nanoparticles have an average diameter of between about 1 nm and about 20 nm.

9. The formulation of claim 1, wherein the nanoparticles are in an aggregate and the aggregate has a diameter of between about 10 nm and about 5000 nm.

10. The formulation of claim 1, wherein a ratio of a weight percent of the herbicide compound to a weight percent of the polymer within the nanoparticles is between about 10:

1 and about 1;

10.

11. The formulation of claim 1, wherein the herbicide compound is fenoxaprop-P-ethyl or pyroxsulam.

12. The formulation of claim 1, wherein the polymer is a random copolymer.

13. The formulation of claim 1, wherein the dispersant or the wetting agent is selected from the group consisting of lignosulfonates, organosilicones, methylated seed oils, ethoxylates, sulfonates, sulfates and combinations thereof.

14. The formulation of claim 1, further comprising between about 0.05 weight percent and about 5 weight percent of a thickener.

15. The formulation of claim 14, wherein the thickener is selected from the group consisting of guar gum, locust bean gum, xanthan gum, carrageenan, alginates, methyl cellulose, sodium carboxymethyl cellulose, hydroxyethyl cellulose, modified starches, polysaccharides, other modified polysaccharides, polyvinyl alcohol, glycerol alkyd and combinations thereof.

16. The formulation of claim 1, wherein the preservative is selected from the group consisting of tocopherol, ascorbyl palmitate, propyl gallate, butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), propionic acid and its sodium salt;

sorbic acid and its sodium or potassium salts;

benzoic acid and its sodium salt;

p-hydroxy benzoic acid sodium salt;

methyl p-hydroxy benzoate;

1,2-benzisothiazalin-3-one, and combinations thereof.

17. The formulation of claim 1, further comprising between about 0.05 weight percent and about 10 weight percent of an anti-freezing agent.

18. The formulation of claim 17, wherein the anti-freezing agent is selected from the group consisting of ethylene glycol, propylene glycol, urea and combinations thereof.

19. The formulation of claim 1, further comprising between about 1 weight percent and about 20 weight percent of a non-ionic surfactant.