System employing ion exchange resin regenerated by acid

• US 9,963,361 B2
• Filed: 12/13/2016
• Issued: 05/08/2018
• Est. Priority Date: 12/13/2011
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Everson, Terrence P., Wen, Li, Tan, Lylien, Voss, Peter, Toetschinger, Mark
• Primary Examiner(s): Barry, Chester T
• Application Number:
  US15/376,850
• Publication Number:
  US 20170088442A1
• Time in Patent Office: 511 Days
• Field of Search: None
• CPC Class Codes: A47L 15/241 the dishes moving in a horizontal plane
• CPC Class Codes: A47L 15/4217 Fittings for water supply, e.g. valves or plumbing means to connect to cold or warm water lines, aquastops
• CPC Class Codes: A47L 15/4229 Water softening arrangements
• CPC Class Codes: B01J 39/05 in the strongly acidic form
• CPC Class Codes: B01J 39/07 in the weakly acidic form
• CPC Class Codes: B01J 39/08 Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
• CPC Class Codes: B01J 39/19 obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
• CPC Class Codes: B01J 39/20 obtained by reactions only involving unsaturated carbon-to-carbon bonds
• CPC Class Codes: B01J 47/15 for obtaining a solution having a fixed pH
• CPC Class Codes: B01J 49/06 containing cationic exchangers
• CPC Class Codes: B01J 49/53 for cationic exchangers
• CPC Class Codes: B01J 49/75 of water softeners
• CPC Class Codes: B08B 3/04 Cleaning involving contact with liquid
• CPC Class Codes: B08B 3/14 Removing waste, e.g. labels, from cleaning liquid; Regenerating cleaning liquidstreatment of water in general C02F
• CPC Class Codes: C02F 1/42 by ion-exchange ion-exchange in general B01J
• CPC Class Codes: C02F 2001/425 using cation exchangers
• CPC Class Codes: C02F 2209/00 Controlling or monitoring parameters in water treatment
• CPC Class Codes: C02F 2209/005 Processes using a programmable logic controller [PLC]
• CPC Class Codes: C02F 2209/06 pH
• CPC Class Codes: C02F 2303/16 Regeneration of sorbents, filters
• CPC Class Codes: D06F 39/007 : Arrangements of water softeners

Abstract

Methods and systems for acid regeneration of ion exchange resins are disclosed. Acid resins designed for use in a variety of cleaning application using a water source use a treated, softened, acidic water source according to the invention. Various methods of using the softened acidic water generated by acid regenerate-able ion exchange resins are disclosed to beneficially reduce spotting, filming and scale buildup on treated surfaces, reduce and/or eliminate the need for polymers, threshold reagents and/or rinse aids, and using protons generated in the acidic water effluent for triggering events useful in various cleaning applications.

Claims

1. A system employing an ion exchange resin regenerated by an acid comprising:

an inlet for providing a water source;

a water treatment reservoir;

a water treatment component housed within the water treatment reservoir, wherein said water treatment component comprises at least one ion exchange resin capable of generating a treated water source by exchanging protons on said resin for dissolved cations including water hardness ions and total dissolved solids in said water source, and wherein said ion exchange resin is an acid form or in an inert metal form;

an outlet;

a water delivery line in fluid communication with a cleaning application and/or storage reservoir to provide the treated water source to the cleaning application and/or storage reservoir; and

a storage reservoir housing an acid salt regenerant and a regenerant delivery line fluidly connected to the water treatment reservoir to deliver the regenerant to the ion exchange resin;

wherein the inlet is in fluid communication with the water treatment reservoir;

wherein a first end of the outlet is in fluid communication with the water treatment reservoir and a second end is in fluid communication with the water delivery line;

wherein the treated water source meets a defined water specification, and wherein the specification is a softened, acidic water having total dissolved solids (TDS) of less than about 300 ppm, a hardness level of less than about 2 grains and a pH less than about 6.

2. The system according to claim 1, wherein said ion exchange resin is a weak acid cation exchange resin and/or a strong acid cation exchange resin.

3. The system according to claim 1, wherein said ion exchange resin is a weak acid exchange resin having a polyacrylic copolymer matrix and carboxylic acid functional group, or wherein said ion exchange resin is a strong acid exchange resin having a polystyrene matrix and sulfonic acid functional group.

4. The system according to claim 1, wherein said ion exchange resin is an acid exchange resin selected from the group consisting of a cross-linked acrylic acid with carboxylic acid functional group, a cross-linked methacrylic acid with carboxylic acid functional group, a polystyrene with sulfonic acid functional group, a polystyrene with sulfonic acid functional group and mixtures of thereof.

5. The system according to claim 1, wherein said regenerant is selected from the group consisting of sodium chloride, urea sulphate, urea, sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid, citric acid, acetic acid, methane sulfonic acid and combinations thereof.

6. The system according to claim 1, further comprising an additional water treatment apparatus and water delivery line in fluid connection with the water treatment reservoir.

7. The system according to claim 1, wherein the regenerant comprises a concentration of about 10 wt-% to about 50 wt-% urea sulfate and about 50 wt-% to about 90 wt-% alkali metal salt, and wherein the system further comprises a measuring device for obtaining pH and/or proton concentration and/or total dissolved solids measurements from the water treatment reservoir, the water source and/or the treated water source, and a controller to receive the measurements and trigger an event.