Methods for preparing highly porous microfibrous media with functional particles immobilized inside

• US 9,964,355 B2
• Filed: 03/13/2013
• Issued: 05/08/2018
• Est. Priority Date: 07/10/2012
• Status: Active Grant

• Current Assignee: IntraMicron, Inc.
• Original Assignee: IntraMicron, Inc.
• Inventors: Yang, Hongyun, Dimick, Paul S., Barron, Troy J., Tatarchuk, Bruce J.
• Primary Examiner(s): Yoo, Jun
• Application Number:
  US14/413,882
• Publication Number:
  US 20150176894A1
• Time in Patent Office: 1,882 Days
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28023 Fibres or filaments fibres or filaments in the form of membranes B01J20/28038; B01J20/28007 takes precedence
• CPC Class Codes: B01J 20/28028 Particles immobilised within fibres or filaments
• CPC Class Codes: B01J 20/28078 Pore diameter
• CPC Class Codes: B01J 20/30 Processes for preparing, regenerating, or reactivating
• CPC Class Codes: B01J 20/3042 Use of binding agents; addition of materials ameliorating the mechanical properties of the produced sorbent
• CPC Class Codes: B01J 20/3064 Addition of pore forming agents, e.g. pore inducing or porogenic agents
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: B01J 20/3085 Chemical treatments not covered by groups B01J20/3007 - B01J20/3078
• CPC Class Codes: B01J 2220/42 Materials comprising a mixture of inorganic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: B01J 23/72 Copper
• CPC Class Codes: B01J 35/58 Fabrics or filaments
• CPC Class Codes: F26B 1/00 Preliminary treatment of solid materials or objects to facilitate drying , e.g. mixing or backmixing the materials to be dried with predominantly dry solids F26B5/005 takes precedence

Abstract

Improved methods for preparing highly porous mesh media and loading functional particles into the media are described herein. The highly porous media can be used as supports for catalyst materials for a variety of applications, such as desulfurization. Pre-manufactured catalyst can be loaded into the sintered open media. Thus, the contamination issues associated wetlay paper making and pre-oxidation, the deactivation issues associated with the sintering and pre-oxidation steps, and the corrosion issues associated with the catalyst formation step can be avoided. The methods described herein result in the formation of highly porous media with functional particles immobilized inside.

Claims

1. A method for preparing porous mesh media comprising fibers and functional particles, the method comprising:

(a) dispersing the fibers in a liquid suspension, wherein the fibers are kinked, bent, or curved prior, during, or after dispersing the fibers in the suspension;

(b) applying the dispersion in step (a) on a sheet former to minimize the compression of the media;

(c) removing the solvent in step (b) to form green media without compressing the green media;

(d) drying and pre-oxidizing the green media in step (c);

(e) sintering the dried media in step (d) in a reducing environment to form fiber-fiber junctions, wherein the void space is from about 85 to about 99.5% in the porous mesh media; and

(f) loading the functional particles into the porous mesh media.

2. The method of claim 1, wherein after step (e) the fibers are present in an amount of 0.5-15 vol. %.

3. The method of claim 1, wherein the fibers have a diameter of 0.5-200 μ

m.

4. The method of claim 1, wherein the resulting pore sizes of the porous mesh media are from about 40 to about 100 mesh.

5. The method of claim 1, wherein the length of the fibers is about 0.1-10 mm.

6. The method of claim 1, wherein the fibers are formed from a material selected from the group consisting of metals, polymers, glasses and ceramics, and combinations thereof.

7. The method of claim 1, wherein step (a) further comprises bending the fibers using high speed blades, inclined peddle plates, shear stress of the suspension, or jet pumps.

8. The method of claim 1, wherein the functional particles are selected from the group consisting of catalyst particles, sorbent/adsorbent particles, reactive particles, catalyst support materials, and combinations thereof.

9. The method of claim 8, wherein the functional particles have a particle size in the range of 5-30 times the fiber diameter.

10. The method of claim 1, wherein in step (f) the functional particles are loaded into the porous mesh media by migrating through fluid flow generated by positive or negative pressures on one side of the sintered media.

11. The method of claim 10, wherein the fluid is air or other gas or gas mixtures, liquid or liquid mixtures.

12. The method of claim 10, wherein the functional particles are loaded into the porous mesh media by migrating into the mesh structure from one side or multiple sides of the mesh structure.

13. The method of claim 1, wherein the porous mesh media comprises multiple layers with at least one side of the mesh structure made of a layer that the functional particles cannot pass through.

14. The method of claim 1, further comprising after step (f):

(g) compressing the porous mesh media.

15. The method of claim 2, wherein the fibers are present in an amount of 0.5-10 vol. %.

16. The method of claim 2, wherein the fibers are present in an amount of 0.5-5 vol. %.

17. The method of claim 3, wherein the fibers have a diameter of 4-100 μ

m.

18. The method of claim 9, wherein the functional particles have a particle size in the range of 10-20 times the fiber diameter.

19. The method of claim 13, wherein at least two layers have different porosities.

20. The method of claim 13, wherein at least one layer comprises fibers with diameters that are different from the diameters of the fibers in another layer.