Annealed garnet electrolyte separators
First Claim
1. An electrolyte separator,having top and bottom surfaces and a bulk therebetween, wherein the bulk has a thickness,wherein the top or bottom surface length or width is greater than the thickness of the bulk by a factor of ten (10) or more, and thethickness of the bulk is from about 10 nm to about 100 μ
- m;
wherein the bulk is characterized by the chemical formula LixLa3Zr2Ozy(Al2O3), wherein 5≤
x≤
7.5, 11≤
z≤
12.25, and 0≤
y≤
1;
wherein both the top and bottom surfaces are characterized as having substantially no layer thereupon comprising a lithium carbonate, lithium hydroxide, lithium oxide, lithium peroxide, a hydrate thereof, an oxide thereof, or a combination thereof.
3 Assignments
0 Petitions
Accused Products
Abstract
Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.
-
Citations
40 Claims
-
1. An electrolyte separator,
having top and bottom surfaces and a bulk therebetween, wherein the bulk has a thickness, wherein the top or bottom surface length or width is greater than the thickness of the bulk by a factor of ten (10) or more, and the thickness of the bulk is from about 10 nm to about 100 μ - m;
wherein the bulk is characterized by the chemical formula LixLa3Zr2Ozy(Al2O3), wherein 5≤
x≤
7.5, 11≤
z≤
12.25, and 0≤
y≤
1;wherein both the top and bottom surfaces are characterized as having substantially no layer thereupon comprising a lithium carbonate, lithium hydroxide, lithium oxide, lithium peroxide, a hydrate thereof, an oxide thereof, or a combination thereof. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31, 32, 33, 34, 35, 36, 37, 38, 39)
- m;
-
40. An electrolyte separator, characterized by the chemical formula LixLa3Zr2O12+yAl2O3, wherein 3≤
- x≤
8 and 0≤
y≤
1 and having a top or bottom surface that has less than 5 atomic % of an amorphous material comprising carbon and oxygen.
- x≤
Specification