System and method for carbon dioxide capture and sequestration from relatively high concentration CO2 mixtures

• US 9,975,087 B2
• Filed: 04/10/2017
• Issued: 05/22/2018
• Est. Priority Date: 04/30/2010
• Status: Active Grant

• Current Assignee: Global Thermostat Operations LLC
• Original Assignee: Graciela Chichilnisky
• Inventors: Eisenberger, Peter
• Primary Examiner(s): Jones, Christopher P
• Application Number:
  US15/483,536
• Publication Number:
  US 20170209832A1
• Time in Patent Office: 407 Days
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2252/20421 Primary amines
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2258/0283 Flue gases
• CPC Class Codes: B01D 2258/06 Polluted air
• CPC Class Codes: B01D 2259/4005 Nature of purge gas
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 53/0407 Constructional details of adsorbing systems
• CPC Class Codes: B01D 53/047 Pressure swing adsorption
• CPC Class Codes: B01D 53/06 with moving adsorbents, e.g. rotating beds B01D53/025 takes precedence
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: B01D 53/1412 Controlling the absorption process
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1475 Removing carbon dioxide
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/18 Absorbing units; Liquid distributors therefor B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32
• CPC Class Codes: B01D 53/346 Controlling the process
• CPC Class Codes: B01D 53/62 : Carbon oxides
• CPC Class Codes: B01J 20/08 : comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/103 : comprising silica
• CPC Class Codes: B01J 20/22 : comprising organic material
• CPC Class Codes: B01J 20/28042 : Shaped bodies; Monolithic structures
• CPC Class Codes: B01J 20/3425 : of sorbents or filter aids comprising organic materials
• CPC Class Codes: B01J 20/3466 : with steam
• CPC Class Codes: Y02A 50/20 : Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
• CPC Class Codes: Y02C 20/40 : of CO2

Abstract

A system and method of reducing the net carbon dioxide footprint of an industrial process that generates power from the combustion of hydrocarbon fuels in which ambient air is admixed with up to 50% by volume of an effluent gas from the power generator of the industrial process, in order to substantially increase the CO₂ concentration in the air prior to treatment. The treatment comprises adsorbing CO₂ from the admixed ambient air utilizing a cooled, porous substrate-supported amine adsorbent, wherein the porous substrate initially contacts the mixed ambient air containing condensed water in its pores, which act as an intrinsic coolant with respect to the exothermic heat generated by the adsorption process. In addition, prior to regenerating the supported adsorbent, air pressure is substantially reduced in the sealed regeneration chamber and the low pressure chamber is placed in fluid connection with a higher pressure regeneration chamber containing steam and carbon dioxide, to preheat the sorbent to be regenerated and to quickly cool the regenerated sorbent prior to use for further CO₂ adsorption.

Claims

1. A system for removing carbon dioxide from carbon dioxide-laden air, the system comprising

a pair of carbon dioxide removal structures, each structure comprising an amine-containing sorbent that is capable of absorbing or binding to carbon dioxide, to remove carbon dioxide from the air, and a porous solid mass substrate upon the surfaces of which the sorbent is supported, and a movable structural support for the substrate;

the structural support supporting the solid mass substrate in a position such that the sorbent is exposed to a flow of carbon dioxide laden air so as to allow for the removal of CO₂ from the air;

a pair of sealable CO₂-capture chambers, one for each carbon dioxide removal structure for capturing carbon dioxide from the CO₂ loaded removal structure;

the capture chambers comprising;

openable fluid connection means between the carbon dioxide capture chamber and an exhaust pump for reducing the atmospheric pressure within the sealed carbon dioxide capture chamber after the entry of a removal structure into the capture chamber;

openable fluid connection means between each of the carbon dioxide capture chamber and a source of process heat steam;

an openable fluid connection means between the two carbon dioxide capture chambers; and

an openable fluid connection means between each carbon dioxide capture chamber and a CO₂ collection chamber; and

apparatus for moving each of the carbon dioxide removal structures into and out of a carbon dioxide capture chamber.

2. The system of claim 1, wherein the carbon dioxide removal structure comprises an array of porous substrate monoliths formed of a material selected from the group consisting of silica, alumina, and alumina coated silica, and wherein the substrate is supporting an amine sorbent.

3. The system of claim 1, wherein the sorbent is a primary amine.

4. The system as defined in claim 1, wherein the porous solid mass comprises a highly porous monolithic ceramic structure which supports the carbon dioxide sorbent to absorb or bind carbon dioxide from the air.

5. The system of claim 1, comprising a pair of vertically oriented carbon capture structures, each of which is selectively operable in a manner wherein one of the pair of vertically oriented carbon capture structures is alternatively and successively in the path of carbon dioxide laden air while the other of the pair of vertically oriented carbon capture structures is being heated with process heat to separate the previously adsorbed carbon dioxide from the sorbent and regenerate the sorbent on the porous support.

6. The system of claim 5, wherein each of the vertically oriented carbon capture structures is configured and operable so that it is alternatively and successively placed in the path of carbon dioxide laden air, to remove the carbon dioxide from the air, and exposed so as to be heated with process heat, to separate the carbon dioxide from the sorbent and regenerate the sorbent.

7. The system of claim 1, comprising an automatically operating valve system designed and adapted to alternatively and successively pass carbon dioxide laden air to the carbon capture structure and to pass process heat to the carbon capture structure to separate the carbon dioxide from the amine sorbent and regenerate the sorbent.