Aqueous coating composition and production of multicoat paint systems using said coating composition

• US 9,976,052 B2
• Filed: 12/11/2014
• Issued: 05/22/2018
• Est. Priority Date: 12/18/2013
• Status: Expired due to Fees

• Current Assignee: BASF Coatings GmbH (BASF SE)
• Original Assignee: BASF Coatings GmbH (BASF SE)
• Inventors: Steinmetz, Bernhard, Luhmann, Nadia, Jankowski, Peggy, Matura, Michael, Reuter, Hardy, Hoffmann, Peter
• Primary Examiner(s): Tran, Thao T
• Application Number:
  US15/106,069
• Publication Number:
  US 20160319151A1
• Time in Patent Office: 1,258 Days
• Field of Search: 4284231, 528 45, 528 65, 528 66, 528 745
• CPC Class Codes: B05D 7/572 all layers being cured or baked together
• CPC Class Codes: C08F 220/14 Methyl esters , e.g. methyl (meth)acrylate
• CPC Class Codes: C08F 220/18 with acrylic or methacrylic acids
• CPC Class Codes: C08F 220/1804 C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
• CPC Class Codes: C08F 220/40 Esters of unsaturated alcohols , e.g. allyl (meth)acrylate
• CPC Class Codes: C08F 226/10 N-Vinyl-pyrrolidone
• CPC Class Codes: C08F 290/147 Polyurethanes; Polyureas
• CPC Class Codes: C08G 18/0823 containing carboxylate salt groups or groups forming them
• CPC Class Codes: C08G 18/4233 derived from polymerised higher fatty acids or alcohols
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C09D 151/08 grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09D 175/14 Polyurethanes having carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09D 175/16 having terminal carbon-to-carbon unsaturated bonds

Abstract

The present invention relates to an aqueous coating composition comprising at least one aqueous dispersion comprising at least one copolymer (CP), said copolymer (CP) being preparable by (i) initially charging an aqueous dispersion of at least one polyurethane, and then (ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane from (i), in which (a) a water-soluble initiator is used, (b) the olefinically unsaturated monomers are metered in such that a concentration of 6.0% by weight, based on the total amount of olefinically unsaturated monomers used for polymerization, in the reaction solution is not exceeded over the entire reaction time, and (c) the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer, at least one linear hydroxy-functional reaction product (R) having an acid number less than 20 mg KOH/g, the preparation of which involves using at least one compound (v) containing two functional groups (v.a) and an aliphatic or araliphatic hydrocarbyl radical (v.b) which is arranged between the functional groups and has 12 to 70 carbon atoms, and at least one polyurethane resin (X), the preparation of which involves using at least one compound (x.1) containing at least one carboxylic acid group and at least one group reactive toward isocyanate groups. The present invention also relates to a method for producing a multicoat paint system using the coating composition, and to the multicoat coating thus produced.

Claims

1. An aqueous coating composition, comprising:

at least one aqueous dispersion comprising at least one copolymer (CP) obtained by

(i) charging an aqueous dispersion comprising at least one polyurethane (A), and then

(ii) polymerizing a mixture of olefinically unsaturated monomers in the presence of the polyurethane (A) from (i),

wherein

(a) a water soluble initiator initiates the polymerizing,

(b) the olefinically unsaturated monomers are added to the aqueous dispersion such that a concentration of 6.0% by weight based on the total amount of olefinically unsaturated monomers polymerizing, in the aqueous dispersion is not exceeded over the entire reaction time, and

(c) the mixture of the olefinically unsaturated monomers comprises at least one polyolefinically unsaturated monomer;

at least one linear hydroxyl-functional reaction product (R) having an acid number less than 20 mg KOH/g, obtained by reacting at least one compound (v) comprising two functional groups (v.a) and an aliphatic or araliphatic hydrocarbyl radical (v.b) which is arranged between the functional groups and has 12 to 70 carbon atoms; and

at least one polyurethane resin (X), obtained by reacting at least one compound (x.1) comprising at least one carboxylic acid group and at least one group reactive toward isocyanate groups.

2. The coating composition according to claim 1, wherein the mixture of olefinically unsaturated monomers comprises 0.1 to 6.0 mol % of polyolefinically unsaturated monomers.

3. The coating composition according to claim 1, wherein:

the mixture of olefinically unsaturated monomers comprises allyl methacrylate; and

no further polyolefinically unsaturated monomers are present.

4. The coating composition according to claim 1, wherein the functional groups (v.a) in the at least one compound (v) are selected from the group consisting of hydroxyl groups, carboxyl groups, and mixtures thereof.

5. The coating composition according to claim 1, wherein dimeric fatty acids, dimer diols, or both are reacted as the compound (v) in the preparation of the reaction product (R).

6. The coating composition according to claim 1, wherein:

the reaction product (R) is obtained by reacting at least one dimer fatty acid with at least one aliphatic, araliphatic, and/or aromatic dihydroxy-functional compound having a number-average molecular weight of 120 to 6000 g/mol; and

the dihydroxy-functional compounds are selected from the group consisting of polyether diols, polyester diols, dimer diols, and mixtures thereof.

7. The coating composition according to claim 1, wherein the at least one reaction product (R) is selected from the group consisting of:

reaction products obtained by reacting dimer fatty acids with at least one aliphatic dihydroxy-functional compound of the general structural formula (I);

8. The coating composition according to claim 1, wherein the at least one compound (x.1) reacted for the preparation of the polyurethane resin (X) is selected from the group consisting of a carboxy-functional polyether polyol, a carboxy-functional polyester polyol, a monomeric monocarboxylic acid containing two hydroxyl groups, and mixtures thereof.

9. The coating composition according to claim 1, wherein the polyurethane resin (X) is obtained by reacting at least one alpha,alpha-dimethylolalkanoic acid as the compound (x.1).

10. The coating composition according to claim 9, wherein the at least one alpha,alpha-dimethylolalkanoic acid is selected from the group consisting of 2,2-dimethylolacetic acid, 2,2-dimethylolpropionic acid, 2,2-dimethylolbutyric acid, 2,2-dimethylolpentanoic acid, and mixtures thereof.

11. The coating composition according to claim 1, further comprising:

at least one hydroxyl-functional polymer other than (CP), (R) and (X) as a binder, selected from the group consisting of a polyurethane, a polyester, a polyacrylate, copolymers thereof, and mixtures thereof,

a melamine resin as a crosslinking agent, and

at least one color pigment, effect pigment, or both.

12. The coating composition according to claim 11, wherein the melamine resin as a crosslinking agent is present in the range of 0.5% to 20% by weight relative to the total weight of the coating composition.

13. The coating composition according to claim 11, wherein the at least one color pigment, effect pigment, or both are present in the range of 1% to 30% by weight relative to the total weight of the coating composition.

14. The coating composition according to claim 1, further comprising:

a thickener present in the range of 0.01% to 5.0% by weight relative to the total weight of the coating composition.

15. A method for producing a multicoat paint system, the method comprising:

(1) applying an aqueous basecoat material to a substrate;

(2) forming a polymer film from the aqueous basecoat material applied in stage (1);

(3) applying a clearcoat material to the polymer film formed from the aqueous basecoat material; and

(4) curing the polymer film together with a film formed from the clearcoat material,

wherein the aqueous basecoat material applied in stage (1) is the coating composition according to claim 1.

16. The method according to claim 15, wherein:

the substrate is a metallic substrate or a plastic substrate; and

the substrate is untreated or has been pretreated or precoated.

17. A multicoat paint system obtained by the method according to claim 15.

18. The multicoat paint system of claim 17, which has a film thickness of a pinhole limit of greater than or equal to 25 μ

m.

19. A method, comprising:

applying the coating composition according to claim 1 to a substrate to obtain a multicoat paint system product,

wherein the multicoat paint system product has improved stability to visual defects compared to a product not coated with the coating composition.

20. The method according to claim 19, wherein the method increases a film thickness of a pinhole limit of the multicoat paint system product by at least 4 μ

m.