Optical device

• US 9,991,403 B2
• Filed: 02/16/2010
• Issued: 06/05/2018
• Est. Priority Date: 02/16/2009
• Status: Active Grant

• Current Assignee: University of Southampton
• Original Assignee: Marvin Charlton, Pavlos Lagoudakis
• Inventors: Charlton, Martin David Brian, Lagoudakis, Pavlos, Chanyawadee, Soontorn
• Primary Examiner(s): Lee, Eugene
• Application Number:
  US13/201,718
• Publication Number:
  US 20120112165A1
• Time in Patent Office: 3,031 Days
• CPC Class Codes: H01L 27/14603 Special geometry or disposition of pixel-elements, address-lines or gate-electrodes
• CPC Class Codes: H01L 31/02322 comprising luminescent members, e.g. fluorescent sheets upon the device
• CPC Class Codes: H01L 31/0352 characterised by their shape or by the shapes, relative sizes or disposition of the semiconductor regions
• CPC Class Codes: H01L 31/035281 Shape of the body
• CPC Class Codes: H01L 31/055 where light is absorbed and re-emitted at a different wavelength by the optical element directly associated or integrated with the PV cell, e.g. by using luminescent material, fluorescent concentrators or up-conversion arrangements
• CPC Class Codes: H01L 33/0004 Devices characterised by their operation
• CPC Class Codes: H01L 33/08 with a plurality of light emitting regions, e.g. laterally discontinuous light emitting layer or photoluminescent region integrated within the semiconductor body H01L27/15 takes precedence
• CPC Class Codes: H01L 33/20 with a particular shape, e.g. curved or truncated substrate
• CPC Class Codes: H01L 33/505 characterised by the shape, e.g. plate or foil
• CPC Class Codes: Y02E 10/52 PV systems with concentrators

Abstract

An improved optoelectronic device is described, which employs optically responsive nanoparticles and utilises a non-radiative energy transfer mechanism. The nanoparticles are disposed on the sidewalls of one or more cavities, which extend from the surface of the device through the electronic structure and penetrate the energy transfer region. The nanoparticles are located in close spatial proximity to an energy transfer region, whereby energy is transferred non-radiatively to or from the electronic structure through non-contact dipole-dipole interaction. According to the mode of operation, the device can absorb light energy received from the device surface via the cavity and then transfer this non-radiatively or can transfer energy non-radiatively and then emit light energy towards the surface of the device via the cavity. As such, the deice finds application in light emitting devices, photovoltaic (solar) cells, displays, photodetectors, lasers and single photon devices.

Claims

1. An optical device having a surface for receiving light energy or for transmitting light energy, the device comprising:

an electronic structure having an energy transfer region, wherein the electronic structure exhibits an electronic band gap with an associated energy;

a plurality of cavities extending from the surface of the device through the electronic structure and penetrating the energy transfer region, each cavity having a predetermined cross-sectional shape with one or more corresponding sidewalls extending from the surface of the device through the electronic structure, wherein surfaces of the sidewalls are passivated to chemically terminate dangling bonds at the surfaces of the sidewalls; and

a plurality of optically responsive particles disposed on at least one of the cavity sidewalls of each cavity in close spatial proximity to the energy transfer region, the plurality of optically responsive particles being adapted for;

emitting light energy towards the surface of the device via the respective cavity; and

energy transfer with the energy transfer region using a non-radiative energy transfer mechanism,

wherein the electronic band gap energy of the electronic structure is greater than an electronic band gap energy of each optically responsive particle whereby, when an electric potential is applied to the electronic structure, energy is transferred non-radiatively to at least some of the optically responsive particles from the electronic structure via the energy transfer region through non-contact dipole-dipole interaction and is emitted as light energy by the at least some optically responsive particles;

wherein the plurality of cavities is arranged in a two-dimensional periodic or quasi-periodic array across the surface of the device with nearest-neighbour separation distance less than twice a wavelength of emission of the optically responsive particles whereby to permit cross-coupling of electromagnetic optical fields generated by optically responsive particles between cavities and the width of adjoining material between nearest-neighbour cavities is a function of the electronic recombination distance of the electronic structure.

2. An optical device according to claim 1, wherein the electronic structure comprises an epitaxial structure.

3. An optical device according to claim 1, wherein the electronic structure comprises at least one p-n junction having a depletion region in the vicinity of the energy transfer region.

4. An optical device according to claim 1, wherein the electronic structure comprises a semiconductor heterostructure including at least one quantum well which provides for high mobility charge transfer in the vicinity of the energy transfer region, wherein at least some of the optically responsive particles are disposed in close spatial proximity to the at least one quantum well.

5. An optical device according to claim 1, wherein the electronic structure comprises a direct band gap semiconductor material.

6. An optical device according to claim 1, wherein the electronic structure comprises an indirect band gap semiconductor material.

7. An optical device according to claim 1, wherein each optically responsive particle comprises at least one of a direct band gap semiconductor material having a well defined shape, a quantum dot, and a quantum rod.

8. An optical device according to claim 1, wherein each optically responsive particle comprises a phosphor.

9. An optical device according to claim 1, wherein each optically responsive particle comprises a colloidal nanoparticle.

10. An optical device according to claim 1, wherein the one or more sidewalls of each cavity extend through the electronic structure perpendicular to the device surface.

11. An optical device according to claim 1, wherein the one or more sidewalls of each cavity are tapered.

12. An optical device according to claim 1, wherein the one or more sidewalls of each cavity are curved.

13. An optical device according to claim 1, wherein the predetermined cross-sectional shape of each cavity is one of a regular shape, a spiral shape, and a star shape.

14. An optical device according to claim 13, wherein the predetermined cross-sectional shape is fractal along its perimeter.

15. An optical device according to claim 1, wherein the plurality of cavities comprise a photonic crystal.

16. An optical device according to claim 1, wherein the plurality of cavities comprises a photonic quasi-crystal.

17. An optical device according to claim 1, wherein the plurality of cavities is arranged to optimise their packing density across the surface of the device.

18. An optical device according to claim 1, wherein the plurality of cavities is arranged across the surface of the device such that the spacing of nearest neighbour cavities is less than or equal to approximately twice the non-radiative carrier diffusion length of the electronic structure.

19. An optical device according to claim 1, wherein the device comprises a non-transparent electrical contact layer disposed over the surface of the device other than the or each cavity.

20. An optical device according to claim 1, wherein the device is a single photon device.

21. An optical device according to claim 1, wherein the cavity is configured to act as a reflector for reflecting light emitted by each optically responsive particle towards the surface of the device.

22. An optical device according to claim 1, wherein a depth of the cavity in the electronic structure is selected to optimise transmission of light from each optically responsive particle towards the surface of the device.

23. An optical device according to claim 1, wherein the plurality of cavities is configured to permit cross-coupling effects therebetween, whereby the device emits light having a predetermined far-field optical profile.

24. An optical device according to claim 1, wherein the plurality of cavities is configured to enhance emission rate via cross coupling between surface Plasmon modes on the surface of the device and the side walls of the cavities.

25. An optical device according to claim 1 wherein the plurality of cavities each comprise a passivation layer.

26. An optical device according to claim 25 wherein the passivation layers are deposited inside each cavity of the plurality of cavities.

27. An optical device according to claim 25 wherein the passivation layer provides a minimum separation distance between the energy transfer region and at least one of the optically responsive particles.