Electrolyte supported cell designed for longer life and higher power

• US 9,991,540 B2
• Filed: 12/15/2015
• Issued: 06/05/2018
• Est. Priority Date: 11/13/2007
• Status: Active Grant

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: El Batawi, Emad, Petersen, Eric, Stephenson, Richard
• Primary Examiner(s): Ruddock, Ula C
• Assistant Examiner(s): Anthony, Julian
• Application Number:
  US14/969,441
• Publication Number:
  US 20160172702A1
• Time in Patent Office: 903 Days
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 8/006 Flat
• CPC Class Codes: H01M 8/1213 characterised by the electrode/electrolyte combination or the supporting material
• CPC Class Codes: H01M 8/1226 characterised by the supporting layer
• CPC Class Codes: H01M 8/1246 the electrolyte consisting of oxides
• CPC Class Codes: H01M 8/1253 the electrolyte containing zirconium oxide
• CPC Class Codes: H01M 8/126 the electrolyte containing cerium oxide
• CPC Class Codes: H01M 8/1286 Fuel cells applied on a support, e.g. miniature fuel cells deposited on silica supports
• CPC Class Codes: H01M 8/2425 High-temperature cells with solid electrolytes
• CPC Class Codes: H01M 8/2483 characterised by internal manifolds
• CPC Class Codes: H01M 8/2484 characterised by external manifolds
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 156/1051 by folding

Abstract

A solid oxide fuel cell (SOFC) that includes an anode electrode, a cathode electrode and a solid oxide electrolyte having a fuel inlet riser opening and a fuel outlet riser opening. The electrolyte is located between the anode electrode and the cathode electrode. The SOFC also includes a ceramic support layer on the electrolyte. The ceramic support is layer located around the at least one of a periphery of the electrolyte or at least partially around perimeters of the fuel inlet and fuel outlet riser openings. The ceramic support layer comprises a multi-component material comprising yttria stabilized zirconia (YSZ) and alpha alumina.

Claims

1. A method of making a solid oxide fuel cell (SOFC) comprising:

providing a solid oxide electrolyte having a thickness of 25-175 μ

m and comprising an active region and an inactive region surrounding the active region, the inactive region comprising a fuel inlet riser opening and a fuel outlet riser opening;

forming an anode electrode on a first side of the electrolyte in the active region, and forming a cathode electrode on a second side of the electrolyte in the active region; and

depositing a ceramic support layer on the electrolyte, the-ceramic support layer located around at least one of a periphery of the electrolyte or at least partially around perimeters of the fuel inlet and fuel outlet riser openings,

wherein the ceramic support layer comprises a multi-component material comprising a stabilized zirconia and alumina.

2. The method claim 1, wherein the stabilized zirconia comprises yttria stabilized zirconia (YSZ) and the alumina comprises alpha alumina.

3. The method of claim 2, wherein a weight ratio of the YSZ to the alpha alumina is 2-5:

1.

4. The method of claim 3, wherein the YSZ has less than 5 atomic % yttria.

5. The method of claim 4, wherein,

the YSZ has less than 3% yttria,

a weight ratio of the YSZ to the alpha alumina is 3:

1, and

the ceramic support layer is located at least partially around perimeters of the fuel inlet and fuel outlet riser openings in the electrolyte to form electrolyte reinforcing regions.

6. The method of claim 1, wherein depositing a ceramic support layer comprises depositing an ink comprising stabilized zirconia and alumina ceramic particles with an average particle size less than 1 micron and an organic binder followed by sintering the stabilized zirconia and alumina ceramic particles.

7. The method of claim 6, further comprising sintering the ceramic support layer at temperatures above 1150 C to burn out the binder and sinter ceramic particles into a polycrystalline support layer.

8. The method of claim 7, further comprising hot isostatically or uniaxially pressing the ceramic support layer before, after or during the step of sintering.

9. The method of claim 1, wherein the ceramic support layer surrounds the active region of the electrolyte.

10. The method of claim 1, wherein substantially all of the ceramic support layer is disposed outside of the active region.

11. The method of claim 10, further comprising firing the anode and cathode electrodes together with the ceramic support layer or separately from the ceramic support layer.

12. The method of claim 1, wherein:

the ceramic support layer is located on the inactive region of the electrolyte; and

a combined thickness of the electrolyte and the ceramic support layer is thicker than a thickness of the active region and thicker than a thickness of the inactive region that does not contain ceramic support layer.

13. The method of claim 12, wherein the combined thickness of the electrolyte and the ceramic support layer is about 5 μ

m to about 20 μ

m thicker than the thickness of the active region and about 5 μ

m to about 20 μ

m thicker than the thickness of the inactive region that does not contain the ceramic reinforcing region.

14. A method of making a solid oxide fuel cell (SOFC) comprising:

providing a solid oxide electrolyte having a thinckness of 25-175 μ

m and comprising an active region and an inactive region surrounding the active region, the inactive region comprising a fuel inlet riser opening and a fuel outlet riser opening;

forming an anode electrode on a first side of the electrolyte and a cathode electrode on a second side of the electrolyte; and

depositing a stabilized zirconia and alumina ceramic support layer on the inactive region such that the ceramic support layer at least partially surrounds the fuel inlet and fuel outlet riser openings,

wherein substantially all of the ceramic support layer is disposed outside of the active region.

15. The method of claim 14, wherein the ceramic support layer is disposed on the first side of the electrolyte and comprises channels leading to the anode electrode.

16. The method of claim 14, wherein the ceramic support layer completely surrounds the anode electrode.

17. The method of claim 14, wherein the ceramic support layer is disposed on the second side of the electrolyte and completely surrounds the fuel inlet and fuel outlet riser openings.

18. The method of claim 17, wherein the ceramic support layer completely surrounds the cathode electrode.

19. The method of claim 14, wherein depositing a stabilized zirconia and alumina ceramic support layer comprises depositing an ink comprising stabilized zirconia powder particles and alumina powders particles and an organic binder, followed by sintering the stabilized zirconia and alumina powder particles.

20. The method of claim 14, wherein depositing a stabilized zirconia and alumina ceramic support layer comprises depositing an ink comprising powder particles made of combination of stabilized zirconia and alumina, and an organic binder, followed by sintering the combination stabilized zirconia and alumina powder particles.