System and process for reclaiming single and mixed amine solvents

• US 9,994,512 B2
• Filed: 03/28/2013
• Issued: 06/12/2018
• Est. Priority Date: 03/29/2012
• Status: Active Grant

• Current Assignee: Delta Cleantech, Inc.
• Original Assignee: HTC Purenergy Inc.
• Inventors: Aboudheir, Ahmed A., Elmoudir, Walid H.
• Primary Examiner(s): Ramdhanie, Bobby
• Assistant Examiner(s): Obenhuber, Briana M
• Application Number:
  US14/386,703
• Publication Number:
  US 20150083576A1
• Time in Patent Office: 1,902 Days
• CPC Class Codes: B01D 1/0064 Feeding of liquid into an evaporator
• CPC Class Codes: B01D 1/0082 Regulation; Control
• CPC Class Codes: B01D 1/06 Evaporators with vertical tubes
• CPC Class Codes: B01D 2252/204 Amines
• CPC Class Codes: B01D 2257/302 Sulfur oxides
• CPC Class Codes: B01D 2257/304 Hydrogen sulfide
• CPC Class Codes: B01D 2257/404 Nitrogen oxides other than dinitrogen oxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/96 Regeneration, reactivation or recycling of reactants
• CPC Class Codes: C07C 209/84 Purification
• CPC Class Codes: C07C 213/10 Separation; Purification; Stabilisation; Use of additives

Abstract

A processes is for purifying an amine compound from a feed solvent which includes an amine salt of the amine compound. The process includes heating the feed solvent in a single stage evaporator of a reclaimer at a reduced operating pressure by feeding the evaporator with a constant amount of thermal energy; and evaporating the amine compound to purity the amine compound from the feed solvent.

Claims

1. A reclaiming system for purifying an amine compound from a feed solvent, the system comprising:

a single stage vertical solvent evaporator unit for separating the amine compound from the feed solvent by evaporation, the vertical evaporator unit comprising;

an inlet for the feed solvent;

a vertical evaporator vessel in fluid communication with the inlet and comprising a first waste collector for collecting reclaiming waste from the vertical evaporator vessel;

a vertical sidearm heater providing thermal energy to the solvent evaporator unit at a constant rate, the vertical sidearm heater in fluid communication with the evaporator vessel and configured to receive liquid from the vertical evaporator vessel and to provide vapor comprising a separated amine compound and non-condensable gases to the vertical evaporator vessel, and comprising a second waste collector for collecting unevaporated reclaiming waste from the vertical sidearm heater; and

at least one liquid outlet in fluid communication with the first and second waste collectors to remove the collected reclaiming waste from the reclaiming system;

a vacuum pump reducing the operating pressure of the reclaiming system;

a condenser unit in fluid communication with the vertical evaporator unit and accepting the separated amine compound vapor from the solvent evaporator unit to form a condensed amine compound; and

a liquid/gas separator unit in fluid communication with the condenser unit to separate the condensed amine compound from the non-condensable gases, providing a purified amine compound.

2. The reclaiming system according to claim 1, wherein the single stage vertical solvent evaporator unit further comprises an inlet for sparging steam into the feed solvent in the single stage vertical solvent evaporator unit.

3. The reclaiming system according to claim 1, wherein the single stage vertical solvent evaporator unit further comprises an inlet for adding water into the feed solvent in the single stage vertical solvent evaporator unit.

4. The reclaiming system according to claim 1, wherein the reclaiming system further comprises a mixer configured to mix a base with the feed solvent.

5. A process for purifying an amine compound from a feed solvent that includes heat stable salts and suspended solid impurities, the process comprising:

heating the feed solvent in a single stage vertical evaporator of the reclaiming system of claim 1 under vacuum by feeding the single stage vertical evaporator with a constant amount of thermal energy;

evaporating the amine compound to purify the amine compound from the feed solvent;

replacing the evaporated amine compound with additional feed solvent;

operating the single stage vertical evaporator under vacuum to maintain the temperature of the amine compound at its boiling point temperature;

collecting reclaiming waste in a waste collector of the single stage vertical evaporator;

withdrawing at least a portion of the collected reclaiming waste from the single stage vertical evaporator while the single stage vertical evaporator is under vacuum when;

a) a content of the amine compound in a vapor output from the single stage vertical evaporator falls below a threshold level;

b) the temperature of the single stage vertical evaporator reaches or exceeds a threshold temperature;

c) a recovery rate for the amine compound falls below a threshold recovery rate for the amine compound;

or

d) any combination thereof, and replacing the withdrawn reclaiming waste with additional feed solvent.

6. The process according to claim 5, wherein water, steam, or both is added to the feed solvent.

7. The process according to claim 5, wherein low pressure saturated steam is sparged into the feed solvent in the single stage vertical evaporator.

8. The process according to claim 5, wherein the feed solvent includes an amine salt of the amine compound, and the process further includes neutralizing, with a base, at least a portion of the amine salt to liberate the amine compound.

9. The process according to claim 8, wherein the base is added in a basic solution which is:

at least a 50 wt % solution of sodium hydroxide or potassium hydroxide in water.

10. The process according to claim 8, wherein the base is added in a basic solution which is:

at least a 40 wt % solution of sodium hydroxide or potassium hydroxide in water.

11. The process according to claim 8, wherein the base is added in a basic solution which is:

at least a 30 wt % solution of sodium hydroxide or potassium hydroxide in water.

12. The process according to claim 8, wherein the base is added in a basic solution which is:

at least a 20 wt % solution of sodium hydroxide or potassium hydroxide in water.

13. The process according to claim 5, wherein the vacuum pressure is between 100 kPa and 3 kPa.

14. The process according to claim 5, wherein heating the feed solvent is done using low pressure steam at a constant rate and at constant conditions.

15. The process according to claim 14, wherein the low pressure steam is obtained from an oil refinery, natural gas processing plant, CO₂ capture plant, utilities, waste energy recovery boilers, or steam produced as by-product from a chemical process.