Methods and compositions for stimulating the production of hydrocarbons from subterranean formations

• US 9,994,762 B2
• Filed: 05/26/2015
• Issued: 06/12/2018
• Est. Priority Date: 03/14/2013
• Status: Active Grant

• Current Assignee: Flotek Industries Incorporated
• Original Assignee: Flotek Industries Incorporated
• Inventors: Hill, Randal M., Champagne, Lakia M., Lett, Nathan L., Green, Maria Elizabeth, Saboowala, Hasnain
• Primary Examiner(s): WASHVILLE, JEFFREY D
• Application Number:
  US14/721,155
• Publication Number:
  US 20150252249A1
• Time in Patent Office: 1,113 Days
• Field of Search: None
• CPC Class Codes: C09K 8/602 containing surfactants
• CPC Class Codes: C09K 8/68 containing organic compounds
• CPC Class Codes: C09K 8/86 containing organic compounds

Abstract

Methods and compositions for stimulating of the production of hydrocarbons (e.g., formation crude oil and/or formation gas) from subterranean formations are provided. In some embodiments, the compositions are emulsions or microemulsions, which may include water, a terpene, and a surfactant. In some embodiments, methods of selecting a composition for treating an oil or gas well are provided.

Claims

1. An emulsion or a microemulsion for stimulating an oil or gas well, comprising:

an aqueous phase;

a surfactant;

a freezing point depression agent; and

a non-aqueous phase comprising a first type of terpene solvent and a second type of terpene solvent, wherein the first type of terpene solvent is nopol and the second type of terpene solvent is d-limonene.

3. The emulsion or the microemulsion of claim 1, wherein the ratio of the aqueous phase to the total amount of terpene solvent is between about 3:

1 and about 1;

2.

4. The emulsion or the microemulsion of claim 1, wherein the ratio of the aqueous phase to the total amount of terpene solvent is between about 10:

1 and about 3;

1.

5. The emulsion or the microemulsion of claim 1, wherein the emulsion or the microemulsion comprises a first type of freezing point depression agent and a second type of freezing point depression agent.

6. The emulsion or the microemulsion of claim 1, wherein the freezing point depression agent comprises an alkylene glycol, an alcohol, and/or a salt.

7. The emulsion or the microemulsion of claim 1, wherein the freezing point depression agent is present in an amount between about 5 wt % and about 40 wt % versus the total microemulsion or emulsion.

8. The emulsion or the microemulsion of claim 1, wherein the emulsion or the microemulsion comprises a first type of surfactant and a second type of surfactant.

9. The emulsion or the microemulsion of claim 1, wherein the surfactant is selected from the group consisting of alkyl polyglycol or alkyl polyglucoside nonionic surfactants, or mixtures of said nonionic surfactants with an ionic surfactant comprising anionic, cationic, or zwitterionic surfactants.

10. The emulsion or the microemulsion of claim 1, wherein the surfactant is present in an amount between about 15 wt % and 55 wt % yersus the total microemulsion or emulsion.

11. A composition for injecting into a wellbore, comprising:

an aqueous carrier fluid; and

the emulsion or a microemulsion as in claim 1, wherein the emulsion or the microemulsion is present in an amount between about 0.1 wt % and about 2 wt % versus the total composition.

2. An emulsion or a microemulsion for stimulating an oil or gas well, comprising:

an aqueous phase;

a surfactant;

a freezing point depression agent; and

an oil continuous phase being a first type of terpene solvent and a second type of terpene solvent, wherein the first type of terpene solvent is nopol and the second type of terpene solvent is d-limonene.

12. A composition for injecting into a wellbore, comprising:

an aqueous carrier fluid; and

the emulsion or a microemulsion as in claim 2, wherein the emulsion or the microemulsion is present in an amount between about 0.1 wt % and about 2 wt % versus the total composition.