Wide band semi-specular mirror film incorporating nanovoided polymeric layer

• US 9,995,861 B2
• Filed: 10/14/2011
• Issued: 06/12/2018
• Est. Priority Date: 10/20/2010
• Status: Active Grant

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Coggio, William D., Black, William B., Weber, Michael F., Tai, Huiwen
• Primary Examiner(s): Kakalec, Kimberly N
• Application Number:
  US13/878,625
• Publication Number:
  US 20130215512A1
• Time in Patent Office: 2,433 Days
• Field of Search: 359599, 4283044, 42831111, 4283179, 4283191, 362355
• CPC Class Codes: G02B 5/0242 by means of dispersed particles
• CPC Class Codes: G02B 5/0247 by means of voids or pores
• CPC Class Codes: G02B 5/0841 comprising organic materials, e.g. polymers
• CPC Class Codes: G02B 5/285 comprising deposited thin solid films G02B5/281 - G02B5/289 take precedence; multilayered film filters for fibre optic multiplexing G02B6/29361

Abstract

Low loss, high reflectivity wide band mirror films provide a desired mix of specular reflection and diffuse reflection or scattering to provide semi-specular reflectivity. The mirror films generally include both a specularly reflective multilayer optical film (MOF) having a wide reflection band, and a scattering layer. In some cases a low refractive index TIR layer is sandwiched between the MOF and the scattering layer. In other cases the scattering layer contacts the MOF directly. In embodiments that include the TIR layer, the TIR layer preferably has a nanovoided morphology and includes a plurality of particles and a polymer binder. In embodiments wherein the scattering layer contacts the MOF directly, the scattering layer preferably also has a nanovoided morphology and includes a plurality of particles and a polymer binder.

Claims

1. A reflective film, comprising:

a multilayer optical film having a first major surface and a second major surface, wherein the multilayer optical film includes a plurality of microlayers configured to provide a broad reflection band that shifts as a function of incidence angle, the multilayer optical film having a long wavelength band edge disposed at a wavelength no greater than 1600 nm for normally incident light; and

a diffusing layer in contact with the first major surface, the diffusing layer adapted to scatter visible light into the multilayer optical film over a range of angles such that the scattered light can be substantially reflected by the broad reflection band;

wherein the diffusing layer comprises a polymer binder having a nanovoided morphology comprising a plurality of interconnected voids or a network of voids dispersed in the polymer binder; and

wherein the reflective film has a total hemispheric reflectivity for visible light of at least 97% when the second major surface of the multilayer optical film is in contact with an absorbing material.

2. The reflective film of claim 1, wherein the broad reflection band has, for normally incident light, a long wavelength band edge disposed at a wavelength no greater than 1000 nm, wherein the reflective film provides visible light scattering corresponding to a transport ratio of less than 80%.

3. The reflective film of claim 2, wherein the transport ratio is less than 80%.

4. The reflective film of claim 2, wherein the transport ratio is less than 40%.

5. The reflective film of claim 1, wherein the diffusing layer has a void volume fraction of at least 30%.

6. The reflective film of claim 1, wherein the diffusing layer also comprises a plurality of particles.

7. The reflective film of claim 6, wherein the particles comprise silicon dioxide or alumina oxide.

8. The reflective film of claim 6, wherein the plurality of particles has a size distribution that includes particles with a size not greater than 1 micrometer, and aggregates of the particles.

9. The reflective film of claim 6, wherein a weight percent of particles in the diffusing layer is at least 50%.

10. The reflective film of claim 6, wherein the weight percent of particles in the diffusing layer is at least 66%.

11. The reflective film of claim 6, wherein the weight percent of particles in the diffusing layer is at least 75%.

12. The reflective film of claim 6, wherein the weight percent of particles in the diffusing layer is at least 80%.

13. The reflective film of claim 1, wherein the diffusing layer has a scattering distribution into a substrate of refractive index ns when illuminated by a normally incident beam of visible light, wherein ns is a minimum refractive index of the plurality of microlayers, and wherein the scattering distribution is substantially reduced at grazing angles in the substrate.

14. The reflective film of claim 1, wherein the diffusing layer has a scattering distribution into a substrate of refractive index ns when illuminated by a normally incident beam of visible light, wherein ns is a minimum refractive index of the plurality of microlayers, and wherein the scattering distribution has a value S0 at a scattering angle of 0 degrees and a value S60 at a scattering angle of 60 degrees, and wherein S60 is less than 10% of S0, and wherein the scattering angle is the deviation angle within the substrate relative to the normally incident beam.

15. The reflective film of claim 14, wherein the scattering distribution has a value S70 at a scattering angle of 70 degrees, and wherein S70 is also less than 10% of S0.

16. The reflective film of claim 14, wherein the scattering distribution has a value S50 at a scattering angle of 50 degrees, and wherein S50 is also less than 10% of S0.