Zinc-air battery

• US 9,997,814 B2
• Filed: 02/01/2016
• Issued: 06/12/2018
• Est. Priority Date: 12/14/2009
• Status: Active Grant

• Current Assignee: Phinergy Ltd.
• Original Assignee: Phinergy Ltd.
• Inventors: Goldstein, Jonathan R.
• Primary Examiner(s): Doan, Nghia
• Application Number:
  US15/011,777
• Publication Number:
  US 20160261012A1
• Time in Patent Office: 862 Days
• Field of Search: 320101, 320107, 429402-407
• CPC Class Codes: H01M 10/425 Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing printed circuits H05K1/00
• CPC Class Codes: H01M 10/44 Methods for charging or discharging circuits for charging H02J7/00
• CPC Class Codes: H01M 10/46 Accumulators structurally combined with charging apparatus circuits for charging H02J7/00
• CPC Class Codes: H01M 12/08 composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
• CPC Class Codes: H01M 50/70 Arrangements for stirring or circulating the electrolyte
• CPC Class Codes: H01M 50/77 with external circulating path
• CPC Class Codes: H02J 7/00 Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
• CPC Class Codes: H02J 7/0042 characterised by the mechanical construction
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A zinc-air cell, a battery which is a low weight, low volume, or higher energy system, or a combination thereof and an apparatus for recharging the same are disclosed.

Claims

1. A zinc-air cell comprising

a zinc-containing anode;

a cathode comprising at least one porous structure capable of absorbing oxygen from the air;

a casing in which said anode and cathode are positioned, said casing further comprising an alkaline electrolyte fluid;

an inlet and outlet in said casing, whereby said inlet and outlet are constructed so as to permit exchange of said electrolyte fluid in said cell with an electrolyte fluid located in an external reservoir; and

wherein said anode and cathode are electrically connectible across a load,

a) wherein said zinc-air cell further comprises at least one electro-conducting porous support for zinc incorporation there-within wherein said porous support comprises a metal or a metal alloy or graphite/carbon sponge;

or

b) wherein said zinc-air cell further comprises a porous polymer-based mat positioned proximally to said porous support wherein said porous polymer-based mat is comprised of polytetrafluoroethylene, nylon, polypropylene or polyethylene, and has a thickness of between 30-1000 μ

m;

or

c) wherein said zinc-air cell further comprises an agitator;

or

d) wherein said zinc-air cell further comprises at least one porous tube which is placed in said casing, in contact with said slurry, and spans said casing such that a portion of said porous tube protrudes from said casing;

wherein said porous tube is so constructed so as to facilitate alkaline electrolyte passage there-through;

or

e) a combination of two or more of a) through d).

2. The air cell of claim 1, further comprising at least a first separator positioned within said cell between said anode and said cathode.

3. The air cell of claim 1, wherein said cell further comprises an outer coating, mesh or wire assembly positioned proximally to said porous polymer-based mat and distal to said porous support and comprising an electrocatalyst for hydrogen evolution in the presence of zinc.

4. The zinc-air cell of claim 1, further comprising:

a slurry consisting of zinc and alkaline electrolyte placed within said casing;

a separator positioned between said porous structure and said slurry;

elongated conductors placed in said casing and in contact with said slurry;

at least one porous tube which is placed in said casing, in contact with said slurry, and spans said casing such that a portion of said porous tube protrudes from said casing;

wherein said porous tube is so constructed so as to facilitate alkaline electrolyte passage there-through; and

whereby said inlet and outlet permit introduction and exchange of said slurry, introduction and exchange of said electrolyte fluid or a combination thereof in said cell with a slurry, an electrolyte fluid, or a combination thereof located in an external reservoir.

5. The zinc-air cell of claim 4, wherein said porous tube is comprised of polytetrafluoroethylene, nylon, polyethylene or polypropylene.

6. The zinc-air cell of claim 1, wherein said zinc-air cell is located on-board a vehicle and wherein said external reservoir is located off-board said vehicle.