Cast detergent-containing article and method of making and using

• US RE32,763 E
• Filed: 08/27/1986
• Issued: 10/11/1988
• Est. Priority Date: 02/07/1978
• Status: Expired due to Term

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Fernholtz, Peter J., Copeland, James L., Penttila, Richard C.
• Primary Examiner(s): Albrecht, Dennis
• Application Number:
  US06/901,249
• Time in Patent Office: 776 Days
• Field of Search: 134/36, 134/25.1, 134/29, 134/57 D, 252/90, 252/92, 252/93, 252/99, 252/103, 252/134, 252/135, 252/156, 252/174, 252/DIG.16, 137/268, 206/524.5, 239/310, 422/261, 422/263, 422/264, 422/278
• US Class Current: 510/225
• CPC Class Codes: A47L 15/4436 in the form of a detergent solution made by gradually dissolving a powder detergent cake or a solid detergent block
• CPC Class Codes: B01F 1/0027 using additional holders in conduits, containers or pools for keeping the solid material in place, e.g. supports, receptacles
• CPC Class Codes: C11D 17/0052 Cast detergent compositions
• CPC Class Codes: Y10T 137/4891 With holder for solid, flaky or pulverized material to be dissolved or entrained

Abstract

Solid cast detergent-containing articles are produced for use in automatic washing machines. A liquid detergent composition is cast into a mold where it is allowed to solidify. The solid cast detergent, surrounded on all but its upper surface by the mold, is used in automatic washing machines having a dispensing device designed to dispense a liquid aqueous detergent formed from the solid cast detergent using an impinging liquid spray. The liquid aqueous detergent flows out of the dispensing device generally simultaneously with its formation in the dispenser. The cast detergent composition includes an alkaline hydratable chemical and optionally further includes one or more preformed cores or plugs comprising an available chlorine source, a defoamer, or the like.

Claims

1. A process for forming a three-dimensional, uniform solidi , casti, detergent .Iadd.for ware and hard surface washing .Iaddend.within a receptacle-shaped mold which comprises:

(a) heating .[.about 20-75 parts by weight of a 40-75 weight percent.]. .Iadd.an .Iaddend.aqueous solution of an alkali metal hydroxide .[.to about 55°

to 95°

C..].;

(b) distributing an effective amount of a hardness sequestering agent and .[.about 15-40 parts by weight of an.]. .Iadd.additional solid .Iaddend.alkaline hydratable chemical in said aqueous solution;

(c) thickening said solution, and mixing said solution during said thickening to form a castable uniform dispersion;

(d) pouring said uniform dispersion into said receptacle-shaped mold and at least partly filling said mold; and

(e) allowing said thickened dispersion to solidify in said mold to a uniform, solid cast detergent wherein at least one surface of the cast detergent is exposed by the receptacle-shaped mold .Iadd.and wherein the alkali metal hydroxide and the hardness sequestering agent are present in amounts sufficient to render the cast detergent solid at room temperature by virtue of water of hydration. .Iaddend.

2. The process of claim 1 wherein said alkali metal hydroxide is sodium hydroxide.

3. The process of claim 2 wherein said hardness sequestering agent is added to the aqueous solution maintained at a temperature of 55°

-.[.70.]..Iadd.85.Iaddend.°

C. and the hardness sequestering agent is sodium tripolyphosphate.

4. The process of claim 1 further comprising, following step (d) and prior to step (e), the step of inserting in said thickened solution in said mold at least one preformed plug composition.

5. The process of claim 4 wherein at least one preformed plug composition comprises a source of available chlorine.

6. The process of claim 1 wherein the .Iadd.additional solid .Iaddend.alkaline hydratable chemical is selected from the group consisting of anhydrous sodium hydroxide, and combinations of sodium hydroxide and a sodium condensed phosphate.

7. The process of claim 6 wherein the said alkaline hydratable chemical is a combination of anhydrous sodium hydroxide and anhydrous sodium tripolyphosphate.

8. The process of claim 1 wherein the said hydratable material added is selected from the group consisting of sodium or potassium .[.trimetaphosphate.]. .Iadd.tripolyphosphate.Iaddend..

9. A solid, cast detergent-containing article produced by the process of claim 1 comprising:

(a) said solid cast detergent.Iadd.;

.Iaddend.and

(b) the mold into which said solid cast detergent was cast, wherein said mold acts as a container for said cast detergent.

10. A process for forming a three-dimensional, uniform.Iadd., .Iaddend.solid.Iadd., .Iaddend.cast detergent .Iadd.for ware and other hard surface washing .Iaddend.within a receptacle-shaped mold which comprises:

(a) heating .[.about 20-75 parts by weight of a 40-75 weight percent.]. .Iadd.an .Iaddend.aqueous solution of an alkali metal hydroxide to about 55°

C. to .Badd..[.95.]..Baddend. .Iadd.85.Iaddend.°

C.;

(b) distributing an effective amount of a hardness sequestering agent and .[.about 15 to 40 parts by weight of an.]. .Iadd.additional solid .Iaddend.alkaline hydratable chemical in said aqueous solution;

(c) thickening said solution with a polyelectrolyte polymer, to form a castable uniform dispersion;

(d) pouring said uniform dispersion into said receptacle-shaped mold and at least partly filling said mold; and

(e) allowing the castable thickened dispersion to solidify in said mold to a uniform cast detergent, wherein at least one surface of the cast detergent is exposed by said mold .Iadd.wherein the alkali metal hydroxide and the hardness sequestering agent are present in amounts sufficient to render the cast detergent solid at room temperature by virtue of water of hydration.Iaddend..

11. The process of claim 10 wherein said alkali metal hydroxide is sodium hydroxide.

12. The process of claim .[.10.]. .Iadd.11 .Iaddend.wherein said hardness sequestering agent is added to the aqueous solution maintained at a temperature of 55°

-.Badd..[.70.]..Baddend..Iadd.85.Iaddend.°

C. and said hardness sequestering agent is sodium tripolyphosphate. .[.

13. The process of claim 10 further comprising, following step (d) and prior to step (e), the step of inserting into the castable thickened solution in said mold at least one preformed plug composition..].

14. The process of claim 13 wherein at least one .[.of.]. preformed plug composition comprises a source of available chlorine.

15. The process of claim 10 wherein the said alkaline hydratable chemical is selected from the group consisting of anhydrous sodium hydroxide, and combinations of sodium hydroxide and a sodium condensed phosphate.

16. The process of claim 15 wherein the said alkaline hydratable chemical is a combination of an anhydrous sodium hydroxide and anhydrous sodium tripolyphosphate.

17. The process of claim 10 wherein the said hydratable material added is selected from the group consisting of sodium or potassium .[.trimetaphosphate.]. .Iadd.tripolyphosphate.Iaddend..

18. A solid, cast detergent-containing article produced by the process of claim 10 comprising:

(a) solid cast detergent; and

(b) the mold wherein the mold acts as a container for said cast detergent.

26. The method of claim .[.18.]. .Iadd.19 .Iaddend.wherein said castable liquid detergent composition comprises:

(a) at least about 30% by weight of an alkaline hydratable chemical consisting essentially of an alkali metal hydroxide;

(b) effective hardness-sequestering amount of an alkali metal condensed phosphate;

(c) .[.more than 5% by weight of.]. water of hydration in both discrete and continuous states of hydration, at least a portion of said water of hydration being associated with said alkali metal hydroxide;

(d) .[.up to 15% by weight of a.]. .Iadd.an effective hardness sequestering amount of an organic .Iaddend.polyelectrolyte; and

(e) up to 5% by weight of an additive selected from the group consisting of a defoamer and a solid, .[.avaliable.]. .Iadd.available .Iaddend.chlorine-containing component.

27. The method of claim 18 wherein said castable liquid detergent composition further comprises a sodium silicate. .[.28. A method for forming an article of commerce incorporating a uniform, cast detergent composition which comprises:

(a) forming a castable liquid detergent composition at a temperature of up to 95°

C. which comprises;

(1) at least 30% by weight of an alkaline hydratable chemical consisting essentially of alkali metal hydroxide;

(2) an effective amount of a hardness-sequestering agent;

(3) an effective thickening amount of a polyacrylate; and

(4) more than 15 parts by weight, per 100 parts by weight of said alkaline hydratable chemical of water of hydration, at least a portion of said water of hydration being associated with said alkali metal hydroxide;

(b) cooling the liquid composition to afford a thickened uniform dispersion; and

(c) casting the uniform dispersion in a receptacle-shaped mold to yield a solid, uniform detergent composition..]. .[.29. The method of claim 26 wherein the mold in which the composition was cast and solidified is a container for the detergent..]. .[.30. The method of claim 29 wherein the article further comprises a cover attached to the container..]. .[.31. The method of claim 28 wherein the article comprises at least one preformed core surrounded by and in contact with the detergent on at least one side of the core..]. .[.32. The method of claim 31 wherein the preformed core comprises a material selected from the group consisting of a defoamer and a solid, available chlorine-containing component..]. .[.33. The method of claim 32 comprising a plurality of preformed cores, at least one of which comprises a solid, available chlorine-containing component..]. .[.34. The method of claim 33 wherein the preformed core has been coated with an inert barrier film..]. .[.35. The method of claim 28 wherein said castable liquid detergent composition comprises;

(a) at least about 30% by weight of an alkaline hydratable chemical consisting essentially of an alkali metal hydroxide;

(b) an effective hardness-sequestering amount of an alkali metal condensed phosphate;

(c) more than 5% by weight of water of hydration in both discrete and continuous states of hydration, at least a portion of said water of hydration being associated with said alkali metal hydroxide;

(d) up to about 15% by weight of a polyacrylate; and

(e) up to 5% by weight of an additive selected from the group consisting of a defoamer and a solid, available chlorine-containing component..]. .[.36. The method of claim 28 wherein said castable liquid detergent composition further comprises a sodium silicate..].

19. A method of making an article of commerce incorporating a .Iadd.warewashing .Iaddend.detergent composition which comprises:

(a) forming a castable liquid detergent composition at a temperature of up to .Badd..[.95.]..Baddend. .Iadd.85.Iaddend.°

C. which comprises;

(1) at least 30% by weight of an alkaline hydratable chemical consisting essentially of alkali metal hydroxide;

(2) an effective amount of a hardness sequestering agent; and

(3) .[.more than 15 parts by weight, per 100 parts by weight of said alkaline hydratable chemical, of.]. water of hydration, at least a portion of said water of hydration being associated with said alkali metal hydroxide .Iadd.wherein the alkali metal hydroxide and the hardness sequestering agent are present in an amount sufficient to render the cast detergent a solid at room temperature by virtue of water of hydration.Iaddend.;

(b) cooling and agitating the liquid composition at a rate such that the liquid composition thickens without segregation of components forming a thickened liquid dispersion;

(c) pouring the thickened liquid dispersion into a receptacle-shaped mold; and

(d) solidifying said liquid dispersion to form a uniform solid .Iadd.warewashing .Iaddend.detergent composition.

20. The method of claim 19 wherein the mold in which the composition .[.was.]. .Iadd.is .Iaddend.cast and solidified is a container for the detergent.

21. The method of claim 20 wherein the article further comprises a cover attached to the container.

22. The method of claim 19 wherein the article comprises at least one preformed core .[.surrounded by and in contact with the detergent on at least one side of the core.]..

23. The method of claim 22 wherein the preformed core comprises a material selected from the group consisting of a defoamer and a solid, available chlorine-containing component.

24. The method of claim 23 comprising a plurality of preformed cores, at least one of which comprises a solid, available chlorine-containing component.

25. The method of claim 23 wherein the preformed core has been coated with .[.an inert barrier.]. .Iadd.a .Iaddend.film.