Infrared reflective optical interference film

• US RE34,605 E
• Filed: 12/11/1992
• Issued: 05/10/1994
• Est. Priority Date: 07/24/1990
• Status: Expired due to Term

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Wheatley, John A., Schrenk, Walter J.
• Primary Examiner(s): Sikes, William L.
• Assistant Examiner(s): PARSONS, DAVID
• Application Number:
  US07/989,303
• Time in Patent Office: 515 Days
• Field of Search: 359/359, 359/577, 359/586, 359/588, 359/589
• US Class Current: 359/359
• CPC Class Codes: G02B 1/04 made of organic materials, e.g. plastics G02B1/08 takes precedence
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
• CPC Class Codes: G02B 5/305 including organic materials, e.g. polymeric layers

Abstract

The present invention provides an optical interference film, made of multiple layers of polymers, which reflects wavelengths of light in the infrared region of the spectrum while being substantially transparent to wavelengths of light in the visible spectrum. The optical interference film includes multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, and C, with the layers being of an optical thickness of between about 0.09 and 0.45 micrometers. Each of the polymeric materials has a different index of refraction, n_i, and the refractive index of the second polymeric material is intermediate the respective refractive indices of the first and third polymeric materials.

Claims

1. An optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum comprising multiple alternating layers of at least first, second, and third "diverse", substantially transparent polymeric materials A, B, and C, each of said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n_i, and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials.

2. The optical interference film of claim 1 in which there is a layer thickness gradient across the thickness of said film.

3. The optical interference film of claim 2 in which said layer thicknesses increase monotonically across the thickness of said film.

4. The optical interference film of claim 1 in which the polymeric materials form a repeating unit ABCB.

5. The optical interference film of claim 1 in which said second polymeric material is a copolymer of said first and third polymeric materials.

6. The optical interference film of claim 1 in which said second polymeric material is a miscible blend of said first and third polymeric materials.

7. The optical interference film of claim 6 in which said first polymeric material is polyvinylidene fluoride, said third polymeric material is polymethyl methacrylate.

8. The optical interference film of claim 6 in which said first polymeric material is a polycarbonate and said third polymeric material is a copolyester based on 1,4-cyclohexanedimethylene terephthalate.

9. The optical interference film of claim 1 in which said first polymeric material is polystyrene, said second polymeric material is a copolymer of styrene and methyl methacrylate, and said third polymeric material is polymethyl methacrylate.

10. The optical interference film of claim 1 in which one of said polymeric materials is a copolymer of thiodiphenol and bisphenol A.

11. The optical interference film of claim 1 in which one of said polymeric materials is polyethylene 2,6 naphthalate.

12. The optical interference film of claim 1 in which one of said polymeric materials is a copolymer of gluterimide and methyl methacrylate.

13. The optical interference film of claim 1 in which the optical thickness ratio of material A, f_A, is 1/3, the optical thickness ratio of material B, f_B, is 1/6, the optical thickness ratio of material C, f_C, is 1/3, and ##EQU11##

14. The optical interference film of claim 1 in which said first polymeric material differs in refractive index from said second polymeric material by at least about 0.03.

15. The optical interference film of claim 14 in which said second polymeric material differs in refractive index from said third polymeric material by at least about 0.03.

16. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, and C, said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n_i, and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a glass substrate.

17. The laminate of claim 16 in which the optical thickness ratio of material A, f_A, is 1/3, the optical thickness ratio of material B, f_B, is .[.1/3.]. .Iadd.1/6, the optical thickness ratio of material C, f_C, is 1/3, and ##EQU12##

18. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, and C, said layers being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n_i, and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a polymeric resin substrate.

19. The laminate of claim 18 in which the optical thickness ratio of material A, f_A, is 1/3, the optical thickness ratio of material B, f_B, is .[.1/3.]. .Iadd.1/6, the optical thickness ratio of material C, f_C, is 1/3, and ##EQU13##

20. The laminate of claim 18 in which said laminate is in the form of a profile. .Iadd.

21. An optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum comprising multiple alternating layers of at least first, second, and third "diverse", substantially transparent polymeric materials A, B, and C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n_i, and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials. .Iaddend. .Iadd.22. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials A, B, C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n_i, and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a glass substrate. .Iaddend. .Iadd.23. A laminate comprising an optical interference film which reflects light in the infrared region of the spectrum while transmitting light in the visible region of the spectrum, including multiple alternating layers of at least first, second, and third diverse, substantially transparent polymeric materials, A, B, C, said layers of first and third polymeric materials being of an optical thickness of between about 0.09 and 0.45 micrometers and each of said polymeric materials having a different index of refraction, n_i, and wherein the refractive index of said second polymeric material is intermediate the respective refractive indices of said first and third polymeric materials, laminated to a polymeric resin substrate. .Iaddend.