Non-dichroic omnidirectional structural color

• US 10,048,415 B2
• Filed: 03/13/2017
• Issued: 08/14/2018
• Est. Priority Date: 08/12/2007
• Status: Active Grant

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Motor Engineering & Manufacturing North America Incorporated (Toyota Motor Corporation), Vivai Solutions Incorporated
• Inventors: Banerjee, Debasish, Zhang, Minjuan, Kohlmann, Paul, Ishii, Masahiko
• Primary Examiner(s): Chang, Audrey Y
• Application Number:
  US15/457,136
• Publication Number:
  US 20170248746A1
• Time in Patent Office: 519 Days
• Field of Search: 359584, 359585, 359586, 359588
• CPC Class Codes: B05D 5/061 Special surface effect
• CPC Class Codes: G02B 5/003 Light absorbing elements
• CPC Class Codes: G02B 5/085 at least one of the reflecting layers comprising metal
• CPC Class Codes: G02B 5/22 Absorbing filters G02B5/201 - G02B5/208 take precedence
• CPC Class Codes: G02B 5/26 Reflecting filters G02B5/28 takes precedence
• CPC Class Codes: G02B 5/285 comprising deposited thin solid films G02B5/281 - G02B5/289 take precedence; multilayered film filters for fibre optic multiplexing G02B6/29361

Abstract

A non-dichroic omnidirectional structural color multilayer structure. The non-dichroic omnidirectional structural color multilayer structure has an absorbing layer, a first layer extending across the absorbing layer, and a second layer extending across the first layer. The multilayer structure can reflect a narrow band of electromagnetic radiation that has a width of less than 500 nanometers and a center wavelength shift of less than 200 nanometers when the multilayer structure is viewed from angles between 0 and 45 degrees. In addition, the absorbing layer can block electromagnetic radiation reflected off of a surface that is proximate to the multilayer structure and thereby afford for a “pure” color that is not contaminated by reflected light from surrounding surfaces.

Claims

1. A non-dichroic omnidirectional structural color comprising:

a multilayer stack having an absorbing layer, a first layer made from a first material having a first index of refraction and a first predefined thickness extending across said absorbing layer, and a second layer made from a second material having a second index of refraction and a second predefined thickness extending across said first layer;

said absorbing layer is selected from the group consisting of chromium, nickel, carbon, graphite, graphene, titanium, vanadium, aluminum, cobalt, silver, molybdenum, niobium, iron, steel, tungsten and alloys thereof;

said multilayer stack reflecting a single narrow band of visible electromagnetic radiation having a reflectance between 65-80% of incident light waves, a width of less than 200 nanometers and a center wavelength shift of less than 50 nanometers when viewed from angles between 0 and 45 degrees and exposed to a source of broadband electromagnetic radiation.

2. The non-dichroic omnidirectional structural color of claim 1, wherein said multilayer stack has a third layer and a fourth layer on an opposite side of said absorbing layer.

3. The non-dichroic omnidirectional structural color of claim 2, wherein said third layer and said fourth layer are made from said first material and said second material, respectively.

4. The non-dichroic omnidirectional structural color of claim 3, wherein said third layer and said fourth layer have a thickness equal to said first predefined thickness and said second predefined thickness, respectively.

5. The non-dichroic omnidirectional structural color of claim 1, wherein said absorbing layer is selected from the group consisting semi-opaque materials and opaque materials.

6. The non-dichroic omnidirectional structural color of claim 1, wherein said absorbing layer is a visually dark oxide.

7. The non-dichroic omnidirectional structural color of claim 6, wherein said visually dark oxide is selected from the group consisting of biotite, doped mica, aluminum oxide, doped aluminum oxide, neodymium oxide, tungsten oxide, iron oxide and combinations thereof.

8. The non-dichroic omnidirectional structural color of claim 1, wherein said multilayer structure is a paint pigment.

9. The non-dichroic omnidirectional structural color of claim 8, further comprising a binder mixed with said paint pigment to form a paint, said paint blocking electromagnetic radiation reflected off of a primer layer when said paint is applied thereto.

10. The non-dichroic omnidirectional structural color of claim 9, further comprising a paint additive mixed within said paint, said paint pigment blocking electromagnetic radiation reflected off of said paint additive when said paint is exposed to said source of broadband electromagnetic radiation.

11. The non-dichroic omnidirectional structural color of claim 1, further comprising a substrate, said multilayer stack being a coating on said substrate.

12. The non-dichroic omnidirectional structural color of claim 11, wherein said substrate is a particle.

13. A process for producing a non-dichroic omnidirectional structural color paint pigment, the process comprising;

providing an absorbing layer, the absorbing layer being selected from the group consisting of chromium, nickel, carbon, graphite, graphene, titanium, vanadium, aluminum, cobalt, silver, molybdenum, niobium, iron, steel, tungsten and alloys thereof;

providing a first layer extending over the absorbing layer, the first layer having a first thickness and a first index of refraction;

providing a second layer extending over the first layer, the second layer having a second thickness and a second index of refraction, the absorbing layer, first layer and second layer reflecting a single narrow band of visible electromagnetic radiation having a reflectance of between 65-80% of incident light waves, a width of less than 200 nanometers and a center wavelength shift of less than 50 nanometers when viewed from angles between 0 and 45 degrees and exposed to a source of broadband electromagnetic radiation.

14. The process of claim 13, further including a substrate and providing the absorbing layer, first layer and second layer on the substrate.

15. The process of claim 14, wherein the substrate is a particle and the particle is coated with the absorbing layer, first layer and second layer.