Electrochromic films and related methods thereof

• US 10,061,175 B2
• Filed: 07/25/2014
• Issued: 08/28/2018
• Est. Priority Date: 07/25/2013
• Status: Active Grant

• Current Assignee: E-Vision Optics LLC
• Original Assignee: e-Vision, LLC (New Smart Optics, Inc.)
• Inventors: Trajkovska-Broach, Anita, Sun, Ying, Kokonaski, William
• Primary Examiner(s): Gross, Carson
• Application Number:
  US14/341,349
• Publication Number:
  US 20150027613A1
• Time in Patent Office: 1,495 Days
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C23C 14/083 of refractory metals or yttrium
• CPC Class Codes: C23C 14/226 in order to form films with columnar structure
• CPC Class Codes: C23C 14/505 for rotation of the substrates
• CPC Class Codes: C23C 14/58 After-treatment
• CPC Class Codes: C23C 14/5873 Removal of material
• CPC Class Codes: C25D 13/02 with inorganic material
• CPC Class Codes: C25D 13/12 characterised by the article coated
• CPC Class Codes: C25D 7/00 Electroplating characterised by the article coated
• CPC Class Codes: C25D 9/04 with inorganic materials
• CPC Class Codes: G02C 7/101 having an electro-optical light valve electro-optical elements per se G02F
• CPC Class Codes: G02F 1/1514 characterised by the electrochromic material, e.g. by the electrodeposited material
• CPC Class Codes: G02F 1/1524 Transition metal compounds
• CPC Class Codes: G02F 2202/36 Micro- or nanomaterials
• CPC Class Codes: Y10T 156/10 Methods of surface bonding and/or assembly therefor

Abstract

EC film stacks and different layers within the EC film stacks are disclosed. Methods of manufacturing these layers are also disclosed. In one embodiment, an EC layer comprises nanostructured EC layer. These layers may be manufactured by various methods, including, including, but not limited to glancing angle deposition, oblique angle deposition, electrophoresis, electrolyte deposition, and atomic layer deposition. The nanostructured EC layers have a high specific surface area, improved response times, and higher color efficiency.

Claims

1. A method comprising:

depositing an electro-chromic material over a first surface having a first surface normal to form a first nanostructured electro-chromic layer over an ophthalmic substrate by exposing the first surface to a flux of the electro-chromic material traveling in a first direction;

wherein an incident angle between the first direction and the first surface normal is at least 1 degree and at most 89 degrees, and

wherein the ophthalmic substrate is a member of the group consisting of a lens blank or a semi-finished lens blank.

2. The method of claim 1, wherein the incident angle is at least 1 degree and less than 10 degrees.

3. The method of claim 1, wherein the incident angle is at least 10 degrees and less than 80 degrees.

4. The method of claim 1, wherein the incident angle is at least 80 degrees and at most 89 degrees.

5. The method of claim 1, further comprising rotating the first surface relative to the flux while depositing the electro-chromic material.

6. The method of claim 1, further comprising:

depositing a first ion-conducting layer over the first nanostructured electro-chromic layer after depositing the electro-chromic material; and

depositing a second ion-conducting layer over the first ion-conducting layer after depositing the first ion-conducting layer to form an electro-chromic optical device.

7. The method of claim 1,

wherein the electro-chromic material comprises two electro-chromic materials;

and

the step of depositing comprises co-depositing two electro-chromic materials over the surface.

8. The method of claim 1, wherein the first nanostructured electro-chromic layer comprises at least one columnar structure.

9. The method of claim 8, wherein the at least one columnar structure and the first surface normal form an angle that is less than the incident angle.

10. The method of claim 1, wherein the first nanostructured electro-chromic layer has at least one feature size ranging from 1 nanometer to 500 nanometers.

11. The method of claim 1, wherein the electro-chromic material is selected from a group consisting of:

tungsten oxide, nickel oxide, iridium oxide, molybdenum oxide, vanadium oxide, and combinations thereof.

12. The method of claim 1, wherein formation of the first nanostructured electro-chromic layer is accomplished by a combination of:

(1) exposing the first surface to the flux of the electro-chromic material traveling in the first direction, and (2) at least one of sol-gel, dip-coating, spin-coating, knife coating, annealing, or sintering.

13. The method of claim 1, wherein the first nanostructured electro-chromic layer has a specific surface area greater than 50 m²/g.

14. The method of claim 1, wherein the first nanostructured electro-chromic layer has a coloration efficiency of greater than 50 cm²/C.

15. The method of claim 1, wherein the first nanostructured electro-chromic layer comprises a mixture of two different electro-chromic materials.

17. The method of claim 1, wherein the angle deposition is glancing-angle deposition or oblique-angle deposition.

18. The method of claim 1, wherein the electro-chromic material comprises WO_x, where x is in a range of 2.7 to 2.9.

19. The method of claim 5, wherein rotating the first surface relative to the flux while depositing the electro-chromic material comprises discontinuous rotation.

16. A method comprising:

depositing a first electro-chromic material over a first surface having a first surface normal to form a first nanostructured electro-chromic layer over an ophthalmic substrate by exposing the first surface to a first flux of the first electro-chromic material traveling in a first direction;

wherein a first incident angle between the first direction and the first surface normal is at least 1 degree and at most 89 degrees;

depositing a second electro-chromic material, different than the first electro-chromic material, over a second surface having a second surface normal to form a second nanostructured electro-chromic layer over the ophthalmic substrate by exposing the second surface to a second flux of the second electro-chromic material traveling in a second direction;

wherein a second incident angle between the second direction and the second surface normal is at least 1 degree and at most 89 degrees;

depositing a first ion-conducting layer over the first nanostructured electro-chromic layer;

depositing a second ion-conducting layer over the second nanostructured electro-chromic layer; and

assembling the first surface and the second surface such that the first ion-conducting layer and the second ion-conducting layer are in contact with each other to form an electro chromic optical system.

20. The method of claim 16, wherein the ophthalmic substrate is a member of the group consisting of a lens, a lens blank, or a semi-finished lens blank.

21. A method comprising:

depositing non-stoichiometric tungsten oxide over a surface to form a nanostructured electro-chromic layer over a semi-finished lens blank by exposing the surface to a flux of the non-stoichiometric tungsten oxide at an incident angle of at least 1 degree and at most 89 degrees with respect to the surface.

22. The method of claim 21, further comprising:

surfacing the semi-finished lens blank to a lens prescription after depositing the non-stoichiometric tungsten oxide.

23. The method of claim 21, further comprising:

edging the semi-finished lens blank to a lens shape after depositing the non-stoichiometric tungsten oxide.

24. The method of claim 21, further comprising:

actuating the nanostructured electro-chromic layer to produce a dynamic response in less than 30 seconds.

25. The method of claim 24, wherein actuating the nanostructured electro-chromic layer comprises:

applying a voltage of equal or less than 4 volts to the nanostructured electro-chromic layer.