Preparation method of low-pH controlled-release intelligent corrosion inhibitor

• US 10,131,995 B2
• Filed: 01/15/2016
• Issued: 11/20/2018
• Est. Priority Date: 01/21/2015
• Status: Active Grant

• Current Assignee: Beijing University of Science and Technology
• Original Assignee: Beijing University of Science and Technology
• Inventors: Li, Xiaogang, Dong, Chaofang, Cheng, Xuequn, Du, Cuiwei, Xiao, Kui
• Primary Examiner(s): Buie-Hatcher, Nicole M.
• Assistant Examiner(s): Reza-Asdjodi, Mohammad
• Application Number:
  US14/997,290
• Publication Number:
  US 20160208165A1
• Time in Patent Office: 1,040 Days
• CPC Class Codes: C23F 11/00 Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent adding inhibitors to mineral oil, fuels, or lubricants C10; adding inhibitors to pickling solutions C23G
• CPC Class Codes: C23F 11/10 using organic inhibitors

Abstract

This disclosure relates to a preparation method of a low-pH controlled-release intelligent corrosion inhibitor. The low-pH controlled-release intelligent corrosion inhibitor comprises a hydrogel with low pH responsiveness and a corrosion inhibiting substance having the capacity of corrosion inhibition. That is, a corrosion inhibiting substance is wrapped in a low-pH sensitive hydrogel. The swelling degree of the pH sensitive hydrogel may be changed according to the amounts of monomers and crosslinking agents so as to control the releasing speed of the corrosion inhibiting substance. By the soaking experiment and the measurements of electrochemical polarization curves and alternating impedance spectra, the sensitive and long-lasting features of the low-pH controlled-release intelligent corrosion inhibitor are indicated. Therefore, the advantageous effects of this disclosure lies in that: 1) the system enables the releasing speed of the corrosion inhibiting substance to be controlled by pH; 2) the system enables long-lasting effect and high corrosion inhibition efficiency of the corrosion inhibiting substance; and 3) the system has broad applicability.

Claims

1. A preparation method of a low-pH controlled-release corrosion inhibitor,

comprising the steps of:

(a) dissolving a monomer in an aqueous solution of an acidic medium with a mass fraction of 0.5-1.0% to prepare a monomer-acidic medium aqueous solution wherein said monomer has a mass fraction of 1.2%-1.8%, then adding an aqueous solution of a crosslinking agent with a mass fraction of 1%-2% to said monomer-acidic medium aqueous solution, and stirring and reacting, wherein said monomer is chitosan, said acidic medium is acetic acid, and said crosslinking agent is glutaraldehyde;

(b) cooling, washing, freezing, and drying the product prepared in step (a) to obtain a pH-responsive hydrogel; and

(c) adding said pH-responsive hydrogel into an aqueous solution of a corrosion inhibiting substance having a concentration of 1-5 mg/mL, and then lyophilizing in vacuum to prepare said low-pH controlled-release corrosion inhibitor, wherein said corrosion inhibiting substance is benzotriazole,

wherein said low pH is 2-5.

2. The preparation method of the low-pH controlled-release corrosion inhibitor according to claim 1, wherein said step (a) comprises:

formulating the aqueous solution of said acidic medium with a mass fraction of 0.5-1.0%, then dissolving said monomer in said aqueous solution, uniformly stirring and standing to prepare a monomer-acidic medium aqueous solution wherein said monomer has a mass fraction of 1.2%-1.8%, then adding an aqueous solution of the crosslinking agent with a mass fraction of 1%-2% into said monomer-acidic medium aqueous solution, continuously stirring the obtained mixture at a speed of 1000-1500 rotations/min for 20-30 min, and reacting at 30-35°

C. for 24-28 h.

3. The preparation method of the low-pH controlled-release corrosion inhibitor according to claim 1, wherein said step (b) comprises:

cooling the product prepared in step (a) to room temperature, then washing the product with ethanol and deionized water, freezing the washed product at −

25 to −

20°

C. for 24-28 h, and then lyophilizing in vacuum to constant weight, to obtain the pH-responsive hydrogel.

4. The preparation method of the low-pH controlled-release corrosion inhibitor according to claim 1, wherein said step (c) comprises:

adding said pH-responsive hydrogel into the aqueous solution of said corrosion inhibiting substance having a concentration of 1-5 mg/mL, soaking for 2-3 days, freezing at −

25 to −

20°

C. for 24-28 h, and then lyophilizing in vacuum to a constant weight, to prepare said low-pH controlled-release corrosion inhibitor.