Method and system for recycling spent ethylene glycol from recovered aircraft de-icing solutions

• US 10,144,688 B2
• Filed: 03/17/2016
• Issued: 12/04/2018
• Est. Priority Date: 03/17/2016
• Status: Active Grant

• Current Assignee: AÉro Mag 2000 Rrr Inc.
• Original Assignee: AÉro Mag 2000 Rrr Inc.
• Inventors: Lepine, Mario, Bergeron, Ghislain, Guy, Michel
• Primary Examiner(s): Miller, Jonathan
• Application Number:
  US14/999,007
• Publication Number:
  US 20170267617A1
• Time in Patent Office: 992 Days
• Field of Search: 73 61
• CPC Class Codes: B01D 15/08 Selective adsorption, e.g. chromatography
• CPC Class Codes: B01D 2311/246 Concentration control
• CPC Class Codes: B01D 2311/2626 Absorption or adsorption
• CPC Class Codes: B01D 2311/2649 Filtration
• CPC Class Codes: B01D 3/148 in combination with at least one evaporator
• CPC Class Codes: B01D 3/42 Regulation; Control
• CPC Class Codes: B01D 61/145 Ultrafiltration
• CPC Class Codes: B64F 5/23 by liquid application; Spraying installations therefor, e.g. fitted on vehicles
• CPC Class Codes: C07C 29/76 by physical treatment
• CPC Class Codes: C07C 29/80 by distillation
• CPC Class Codes: C07C 31/202 Ethylene glycol
• CPC Class Codes: C07C 31/205 1,3-Propanediol; 1,2-Propanediol
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A method and a system for recycling spent ethylene or propylene glycol recovered from aircraft deicing solutions is described. The recovered spent ethylene or propylene glycol contains water and other undesirable substances which require to be removed to produce a solution free of these substances which can be further processed to remove substantially all of the water content and to blend-in additives required to certify the final glycol solution for aircraft deicing. The method and system employs a computer controller for continuous automatic batch processing of the spent glycol, including, in combination, filtering, distillation, blending and testing in specific sequences and achieves an improved quality recycled glycol of a purity of at least 99.5% and preferably between 99.6% to 99.9% glycol concentration.

Claims

1. A system for treating spent ethylene or propylene glycol recovered from aircraft de-icing solutions containing glycol, water, solids and other substances to produce substantially virgin glycol, said system comprises, in combination, an underground conduit means for recovering spent glycol from a tarmac of an aircraft de-icing area;

said conduit means being connected to a collection reservoir having segmented storage chamber comprising a first compartment to separate sediments from said spent glycol to permit sampling by pumping said spent glycol solution through a densimeter to determine the glycol concentration in said spent glycol and to remove spent glycol having a predetermined low % purity concentration from said first chamber, one or more working tanks are also provided for storing said spent glycol having a glycol concentration above said predetermined low % purity concentration, filter means is also provided to filter said spent glycol from the one or more working tanks to remove substantially all said solids from said spent glycol from the one or more working tanks, said filter means having at least two filtering stages one of which is an ultra-filtering means, one or more evaporators to evaporate water from the spent glycol to produce a spent glycol having a glycol concentration of about 50% purity which is then transferred to a buffer tank to produce a batch of spent glycol having a glycol concentration of about 50% purity, a pump for transferring said spent glycol having a glycol concentration of about 50% purity from said buffer tank to a pH adjusting mixing and sampling tank to adjust the pH of said batch of spent glycol having a glycol concentration of about 50% purity to a desired pH value which is then carbon filtered and fed to a distillation tower holding tank to accumulate a predetermined volume of the pH adjusted spent glycol having a glycol concentration of about 50% purity concentration, a predetermined batch of said spent glycol having a concentration of about 50% purity concentration is transferred from said distillation tower holding tank to an evaporator section of a distillation tower which operates under vacuum, said distillation tower having an upper chimney section is provided with steel packings to retain heat above a condensation temperatures of an evaporated liquid from a lower evaporator section;

temperature sensors monitor the temperature of said upper chimney section and feed detected temperature signals, representative of the temperature of a stream of vapors drawn through said steel packings, to a computer controller;

said evaporator section evaporates said spent glycol having a concentration of about 50% purity to create said stream of vapors whose vapors are drawn through the upper chimney section and into a condensing coil downstream of said chimney section to produce condensed liquid from said stream of vapors which is fed through a vapor condensing cooler, a glycol purity concentration measuring means is connected to an outlet pipe of said vapor condensing cooler to measure on a continuous basis the glycol concentration in the condensed liquid and feed glycol concentration signals representative of the % purity of said condensed liquid to said computer controller to correlate with said detected temperature signals of said temperature sensors to determine the appropriate time to operate three valves secured to said outlet pipe, each of said valves having a conduit connection to a respective one of three reservoirs whereby the operation of said valves by said computer controller separates, in associated ones of said three reservoirs, water, water mixed with glycol having a glycol concentration of less than 99.5% purity, and substantially virgin glycol having a glycol concentration of at least 99.5% purity as detected by said glycol purity concentration measuring means, said water in one of said three reservoirs being directed to a storage tank for disposal or re-use, said water mixed with glycol having a glycol concentration less than 99.5% purity in another of said three reservoirs being directed back to said distillation tower holding tank feeding said evaporator section of said distillation tower, said substantially virgin glycol having a glycol concentration of at least 99.5% purity in another of said three reservoirs being directed to certified glycol holding tanks, and quality testing means to certify and store said substantially virgin glycol in further certified glycol holding tanks for use by aircraft de-icing vehicles.

2. The system of claim 1 wherein said first compartment of said segmented storage chamber is provided with an overflow conduit in an upper portion thereof to permit the removal of said spent glycol having a predetermined low % purity, and a pump adapted to pump spent glycol from a predetermined region of said collection means to said densimeter to feed spent glycol concentration signals to said computer controller which determines if spent glycol requires to be discharged into said overflow conduit or if spent glycol having a concentration of at least 5% should be transferred to said one or more working tanks.

3. The system of claim 1 wherein said filter means includes a bag filter to produce a first filtered batch of spent glycol for collection in a first working tank for containing said filtered batch of spent glycol, and said ultra-filtering means being a ceramic filter connected in a loop with said first working tank for further filtering spent glycol from said first working tank to remove very fine solid particles and other substances above 0.5 micron from said filtered spent glycol to feed an evaporator holding tank.

4. The system of claim 3 wherein said substantially virgin glycol having a glycol concentration of at least 99.5% purity is transferred to a blending tank until a predetermined volume is attained for receiving final additives to produce type I de-icing glycol.

5. The system of claim 4 wherein said pH adjusting mixing and sampling tank is provided with sampling valves for sampling said substantially virgin glycol having a glycol concentration of at leas 99.5% purity to test the pH of said spent glycol having a glycol concentration of about 50% purity and an additive reservoir connected to said pH adjusting mixing and sampling tank to introduce additives to produce a desired pH value for said spent glycol having a glycol concentration of about 50% purity prior to transferring said spent glycol having a glycol concentration of about 50% purity to the distillation tower holding tank to feed batches of said spent glycol having a glycol concentration of about 50% purity into said evaporator section of said distillation tower.

6. The system of claim 1 wherein said glycol purity concentration measuring means to monitor the percentage concentration of glycol is a refractometer to measure the refractive index of glycol in said condensed liquid, said refractometer providing refractive index value signals to said computer controller.

7. The system of claim 6 wherein the valves are automatically operated by said computer controller based on received index value signals from said refractometer whereby to operate said valves to direct said condensed liquid to said associated reservoirs.

8. The system of claim 1 wherein the quality testing means is a quality control testing holding tank to provide for the quality control testing for certification of said substantially virgin glycol, and a mixing tank for adding further additives to said certified substantially virgin glycol for storage in additional reservoirs ready for use by vehicles adapted for blending a final aircraft de-icing glycol solution depending on climatic factors.

9. The system of claim 1 wherein the substantially virgin glycol has a glycol concentration in the order of from between 99.6% to 99.9%.