Process for recovering heat from a hydrocarbon separation

• US 10,214,695 B2
• Filed: 07/29/2014
• Issued: 02/26/2019
• Est. Priority Date: 10/16/2013
• Status: Active Grant

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: King, Stephen T., Kanyuh, Adam J., Zhu, Xin X.
• Primary Examiner(s): Miller, Jonathan
• Assistant Examiner(s): Pilcher, Jonathan Luke
• Application Number:
  US14/445,512
• Publication Number:
  US 20150101921A1
• Time in Patent Office: 1,673 Days
• CPC Class Codes: B01D 1/28 with vapour compression
• CPC Class Codes: B01D 1/2856 The compressed vapour is used for heating a reboiler or a heat exchanger outside an evaporator
• CPC Class Codes: B01D 3/14 Fractional distillation or use of a fractionation or rectification column
• CPC Class Codes: B01D 3/143 by two or more of a fractionation, separation or rectification step
• CPC Class Codes: B01D 3/148 in combination with at least one evaporator
• CPC Class Codes: B01D 5/0039 Recuperation of heat, e.g. use of heat pump(s), compression
• CPC Class Codes: C07C 7/00 Purification; Separation; Use of additives working-up undefined gaseous mixtures obtained by cracking hydrocarbon oils C10G70/00
• CPC Class Codes: C07C 7/04 by distillation
• CPC Class Codes: C10G 53/02 plural serial stages only
• CPC Class Codes: C10G 7/00 Distillation of hydrocarbon oils
• CPC Class Codes: Y02P 70/10 Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

A process for recovering heat from the separation of hydrocarbons. The overhead vapor stream from a fractionation column is passed to a two stage heat pump compressor. The first stage of compression is used to reboil the fractionation column. The second stage is compressed and cooled passed to a separation zone. The liquid in the separation zone may be passed back to the fractionation column as secondary reflux, and/or recovered as liquid product. Heat may also be removed from the second stage. A suction drum on the first stage may be used to protect the heat pump compressor from any droplets in the overhead stream.

Claims

1. A process for separating hydrocarbons and recovering heat from a stream, the process comprising:

separating a feed stream comprising hydrocarbons in a first separation zone into an overhead stream and a bottoms stream, the overhead stream being a vapor stream and the bottom stream being a liquid stream;

passing at least a portion of the overhead stream to a compressor configured to produce a first output stream and a second output stream, wherein the second output stream has a greater pressure than the first output stream;

transferring heat from at least a first portion of the first output stream of the compressor to the first separation zone and then passing the first portion of the first output stream of the compressor to the first separation zone;

passing a second portion of the first output stream of the compressor to a second separation zone;

removing heat from the second output stream of the compressor; and

,

passing the second output stream of the compressor to the second separation zone,

wherein the second output stream of the compressor is cooled by contact cooling with the second portion of the first output stream of the compressor, the second separation zone has a pressure higher than a pressure of the overhead stream, and the second separation zone is configured such that any vapor in the second separation zone is from the compressor.

2. The process of claim 1, wherein the first separation zone is a fractionation column.

3. The process of claim 1 further comprising:

recovering a liquid stream from the second separation zone.

4. The process of claim 1 wherein the first portion of the first output stream of the compressor comprises between approximately 75% to 90% by volume of the first output stream of the compressor.

5. The process of claim 1 wherein the second separation zone provides an overhead stream and a bottoms stream, and the process further comprising:

passing the overhead stream to the compressor.

6. The process of claim 1 further comprising:

recovering liquid from the overhead stream of the first separation zone prior to passing the overhead stream to the compressor.

7. The process of claim 6 further comprising:

recovering liquid from the overhead stream of the first separation zone in a third separation zone, the third separation zone being disposed between the first separation zone and the compressor.

8. The process of claim 1 further comprising:

cooling the second output stream of the compressor in a cooling zone after removing heat from the second output stream and before the second output stream is passed to the second separation zone.

9. A process for separating hydrocarbons and recovering heat, the process comprising:

separating a feed stream comprising hydrocarbons in a first separation zone into an overhead stream and a bottoms stream;

separating the overhead stream from the first separation zone into a vapor stream and a liquid stream;

passing the vapor stream to a compressor configured to produce a first output stream and a second output stream, wherein the second output stream has a greater pressure than the first output stream;

passing a first portion of the first output stream of the compressor to a second separation zone;

recovering heat from a second portion the first output stream of the compressor;

condensing and recycling the second portion of the first output stream of the compressor to the first separation zone;

removing heat from the second output stream of the compressor; and

,

passing the second output stream of the compressor to the second separation zone,

wherein the second output stream of the compressor is cooled by contact cooling with the portion of the first output stream of the compressor and the second separation zone is configured such that any vapor in the second separation zone is from the compressor.

10. The process of claim 9, wherein the first portion of the first output stream passed to the second separation zone comprises between approximately 10-25% by volume of the first output stream.

11. The process of claim 9 further comprising:

cooling the second output stream of the compressor in a cooling zone after removing heat from the second output stream and before the second output stream is passed to the second separation zone.

12. The process of claim 9 wherein the second separation zone provides an overhead stream and a bottoms stream, and further comprising:

passing the overhead stream to the compressor.

13. The process of claim 9 further comprising:

recovering a liquid stream from the second separation zone.

14. The process of claim 9 wherein the overhead stream from the first separation zone is separated into a vapor stream and a liquid stream in a third separation zone.

15. The process of claim 14 wherein the third separation zone is disposed between the first separation zone and the compressor.

16. The process of claim 15 wherein the first separation zone comprises a distillation column.

17. The process of claim 16 wherein a pressure in the third separation zone is lower than in a pressure in the second separation zone.