Thermal management system containing a graphene oxide-coated graphitic foil laminate for electronic device application

• US 10,229,862 B2
• Filed: 11/02/2012
• Issued: 03/12/2019
• Est. Priority Date: 11/02/2012
• Status: Active Grant

• Current Assignee: Global Graphene Group, Inc.
• Original Assignee: Nanotek Instruments, Inc.
• Inventors: Zhamu, Aruna, Wang, Mingchao, Xiong, Wei, Jang, Bor Z.
• Primary Examiner(s): Ruppert, Eric
• Application Number:
  US13/694,162
• Publication Number:
  US 20140124176A1
• Time in Patent Office: 2,321 Days
• Field of Search: 165185, 361704
• CPC Class Codes: F28F 21/02 of carbon, e.g. graphite
• CPC Class Codes: F28F 3/00 Plate-like or laminated elements; Assemblies of plate-like or laminated elements specially adapted for movement F28F5/00
• CPC Class Codes: H01L 23/373 Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/0002 Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00

Abstract

A heat dissipation system, comprising: (a) an electronic device comprising a heat source, wherein the heat source transmits heat to a second component or an external surface of the device; (b) a heat-conducting layer being positioned such that one of its major surfaces is in operative contact with the heat source such that it is interposed between the heat source and the second component or the external surface. The heat-conducting layer comprises at least one graphene oxide-coated graphitic foil laminate which thermally shields the second component or the external surface from heat generated by the heat source, and wherein the laminate is composed of a graphitic substrate/core layer with at least one primary surface coated with a graphene oxide coating layer. This graphene oxide-coated laminate exhibits a combination of exceptional thermal conductivity, electrical conductivity, mechanical strength, surface hardness, and scratch resistance, making this the most effective heat dissipation system.

Claims

1. A heat dissipation system, comprising:

(a) an electronic device comprising a heat source, wherein the heat source transmits heat to a second component or an external surface of the electronic device;

(b) a heat-conducting layer comprising two major surfaces, wherein one of said major surfaces is in operative contact with the heat source such that the heat-conducting layer is interposed between the heat source and the second component or the external surface of the electronic device;

wherein the heat-conducting layer comprises at least one graphene oxide-coated graphitic foil laminate, and wherein the laminate is composed of a graphitic substrate or core layer having two opposed primary surfaces and at least a graphene oxide coating layer deposited directly on at least one of said two primary surfaces, wherein said graphitic substrate or core layer has a thickness greater than 1 nm, and said graphene oxide coating layer has a thickness greater than 1 nm and an oxygen content of 0.01%-40% by weight based on the total graphene oxide coating weight, wherein said graphitic substrate or core layer is selected from the group consisting of flexible graphite foil, graphite particle paper, carbon-carbon composite film, carbon nanofiber paper, carbon nanotube paper, graphene fluoride paper, hydrogenated graphene paper, doped graphene paper, and functionalized graphene paper, wherein said graphene oxide coating layer comprises a unitary graphene layer or a single crystal of graphene planes that are parallel to a graphene oxide coating layer surface, and wherein each unitary graphene layer is a large-scale entity, no less than 10 μ

m in length or width, and having an integrated layer of highly ordered structure of carbon atoms wherein said graphene oxide-coated graphitic foil laminate exhibits an in-plane thermal conductivity greater than 1,000 W/mK and an in-plane electric conductivity greater than 1,500 S/cm and a thickness-direction thermal conductivity lower than 10 W/mK.

2. The heat dissipation system as defined in claim 1, wherein said oxygen content is from 0.01% to 10% by weight.

3. The heat dissipation system of claim 1, wherein the electronic device further comprises a heat dissipation device positioned in a location not directly adjacent to the heat source and wherein one of the major surfaces of the heat-conducting layer is in operative contact with the heat dissipation device.

4. The heat dissipation system of claim 3, wherein the heat dissipation device comprises a heat sink, a heat pipe, a heat plate, or a combination thereof.

5. The heat dissipation system of claim 1, wherein a thermal transfer material is positioned between the heat-conducting layer and the heat source.

6. The heat dissipation system of claim 5, wherein the thermal transfer material comprises a metal or a thermal interface material.

7. The heat dissipation system of claim 1, wherein the electronic device is a portable computing device containing a central processing unit (CPU), a battery, or a supercapacitor as a heat source.

8. The heat dissipation system of claim 1, wherein the electronic device is a digital camera, a mobile phone, a laptop computer, a tablet, an electronic book or e-book, a power tool, or a hand-held video recording device.

9. The heat dissipation system as defined in claim 1, wherein the graphitic substrate layer or graphene oxide coating layer has a thickness less than 200 μ

m.

10. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic layer has an in-plane electric conductivity greater than 2,000 S/cm.

11. The heat dissipation system as defined in claim 10, wherein said unitary graphene layer or single crystal has a lateral dimension greater than 100 μ

m.

12. The heat dissipation system as defined in claim 10, wherein said unitary graphene layer or single crystal has a lateral dimension greater than 10 mm.

13. The heat dissipation system as defined in claim 1, wherein said graphene oxide is a reduced graphene oxide having an oxygen content less than 5% by weight.

14. The heat dissipation system as defined in claim 1, wherein said graphene oxide contains a reduced graphene oxide.

15. The heat dissipation system as defined in claim 1, wherein said graphene oxide has an oxygen weight fraction of 23% to 35% and is thermally conductive but not electrically conductive.

16. The heat dissipation system as defined in claim 1, wherein said graphitic foil contains a material selected from natural graphite, artificial graphite, meso-phase carbon, meso-phase pitch, meso-carbon micro-bead, soft carbon, hard carbon, coke, carbon fiber, carbon nano-fiber, carbon nano-tube, or a combination thereof.

17. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic foil laminate has a Rockwell hardness value greater than 60.

18. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic foil laminate has an in-plane thermal conductivity greater than 1,700 W/mK or through-plane thermal conductivity less than 5 W/mK.

19. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic foil laminate has an in-plane electrical conductivity greater than 5,000 S/cm.

20. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic foil laminate has an in-plane electrical conductivity greater than 3,000 S/cm.

21. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic foil laminate has an electrical conductivity greater than 1,500 S/cm, a physical density greater than 1.4 g/cm3, and a tensile strength greater than 10 MPa.

22. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic foil laminate has an in-plane electrical conductivity greater than 2,000 S/cm, a physical density greater than 1.8 g/cm3, and a tensile strength greater than 40 MPa.

23. The heat dissipation system as defined in claim 1, wherein said graphene oxide-coated graphitic foil laminate has an in-plane electrical conductivity greater than 5,000 S/cm, an in-plane thermal conductivity greater than 1,500 W/mK, a physical density greater than 2.0 g/cm³, and a tensile strength greater than 60 MPa.

24. The heat dissipation system of claim 1, wherein said graphene oxide coating layer is deposited on each of said two primary surfaces of said graphitic core layer.

25. The heat dissipation system of claim 1, wherein at least one of said graphene oxide coating layer is further deposited with a layer of electrically insulating material.

26. A heat dissipation system, comprising:

(A) an electronic device comprising a heat source, wherein the heat source transmits heat to a second component or an external surface of the electronic device;

(B) a heat-conducting layer comprising two major surfaces, the heat-conducting layer being positioned such that one of its major surfaces is in operative contact with the heat source such that it is interposed between the heat source and the second component or the external surface of the electronic device;

wherein the heat-conducting layer comprises at least one graphene oxide-coated graphitic foil laminate, and wherein the laminate is composed of a graphitic substrate or core layer having two opposed primary surfaces and at least a graphene oxide coating layer deposited on at least one of said two primary surfaces, wherein said graphene oxide coating layer contains a unitary graphene layer or graphene single crystal and has an oxygen content of less than 5% by weight based on the total graphene oxide weight, wherein said graphitic substrate or core layer is selected from the group consisting of flexible graphite foil, graphite particle paper, carbon-carbon composite film, carbon nanofiber paper, carbon nanotube paper, graphene fluoride paper, hydrogenated graphene paper, doped graphene paper, and functionalized graphene paper, wherein said graphene oxide coating layer comprises a unitary graphene layer or a single crystal of graphene planes that are parallel to a graphene oxide coating layer surface, and wherein each unitary graphene layer is a large-scale entity, no less than 10 μ

m in length, and having an integrated layer of highly ordered structure of carbon atoms wherein said graphene oxide-coated graphitic foil laminate exhibits an in-plane thermal conductivity greater than 1,000 W/mK and an in-plane electric conductivity greater than 1,500 S/cm and a thickness-direction thermal conductivity lower than 10 W/mK.