Capacitor and method of production thereof

• US 10,340,082 B2
• Filed: 03/03/2017
• Issued: 07/02/2019
• Est. Priority Date: 05/12/2015
• Status: Active Grant

• Current Assignee: Capacitor Sciences Incorporated (Bolloré SE)
• Original Assignee: Capacitor Sciences Incorporated (Bolloré SE)
• Inventors: Lazarev, Pavel Ivan, Sharp, Barry K, Furuta, Paul, Li, Yan, Kelly-Morgan, Ian SG, Robinson, Matthew R., Membreno, Daniel
• Primary Examiner(s): Ferguson, Dion
• Application Number:
  US15/449,524
• Publication Number:
  US 20170301467A1
• Time in Patent Office: 851 Days
• Field of Search: None
• CPC Class Codes: C08G 73/0266 Polyanilines or derivatives thereof
• CPC Class Codes: H01G 4/002 Details
• CPC Class Codes: H01G 4/008 Selection of materials
• CPC Class Codes: H01G 4/01 Form of self-supporting electrodes
• CPC Class Codes: H01G 4/14 Organic dielectrics
• CPC Class Codes: H01G 4/18 of synthetic material, e.g. derivatives of cellulose H01G4/16 takes precedence
• CPC Class Codes: H01G 4/186 halogenated H01G4/145 takes precedence
• CPC Class Codes: H01G 4/32 Wound capacitors
• CPC Class Codes: H01G 4/38 Multiple capacitors, i.e. structural combinations of fixed capacitors
• CPC Class Codes: H01G 4/40 Structural combinations of fixed capacitors with other electric elements, the structure mainly consisting of a capacitor, e.g. RC combinations
• CPC Class Codes: H01L 29/00 Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor H01L31/00 - H01L33/00, H10K10/00, H10N take precedence; details other than of semiconductor bodies or of electrodes thereof H01L23/00; devices consisting of a plurality of solid state components formed in or on a common substrate H01L27/00
• CPC Class Codes: H02J 7/0068 Battery or charger load switching, e.g. concurrent charging and load supply H02J7/0013 takes precedence
• CPC Class Codes: H02J 7/345 using capacitors as storage or buffering devices

Abstract

A capacitor includes a first electrode, a second electrode, and a dielectric layer of molecular material disposed between said first and second electrodes. The molecular material is described by the general formula:
D_p-(Core)-H_q,
where Core is a polarizable conductive anisometric core, having conjugated π-systems, and characterized by a longitudinal axis, D and H are insulating substituents, and p and q are numbers of the D and H substituents accordingly. And Core possesses at least one dopant group that enhances polarizability.

Claims

1. A capacitor comprising:

a first electrode,

a second electrode, and

a dielectric layer of molecular material disposed between said first and second electrodes,

wherein said electrodes are substantially planar surface and positioned parallel to each other, and

the molecular material is described by the general formula

D_p-(Core)-H_q 

 

(I)

where Core is a polarizable conductive anisometric core, having conjugated π

-systems, and characterized by a longitudinal axis,

D and H are insulating substituents, and

p and q are numbers of the D and H substituents accordingly,

wherein said substituents are selectively attached to any available positions on the polarizable anisometric core including apex positions and lateral positions as related to the longitudinal axis, p and q are independently selected from values 1, 2, 3, 4, and 5, and Core possesses one or more selectively attached dopant groups that enhance polarizability.

2. A capacitor, according to claim 1, wherein the conductive anisometric core conjugated π

-systems form supramolecular structures by means of π

-π

-interactions.

3. A capacitor, according to claim 1, wherein the insulating substituents D and H are selected independently from the group consisting of alkyl, fluorinated alkyl, chlorinated alkyl, branched and complex alkyl, branched and complex fluorinated alkyl, branched and complex chlorinated alkyl groups, and any combination thereof.

4. A capacitor, according to claim 1, wherein one or more of the insulating groups D and one or more of the insulating groups H are each selected independently from the group consisting of alkyl, fluorinated alkyl, chlorinated alkyl, branched and complex alkyl, branched and complex fluorinated alkyl, branched and complex chlorinated alkyl groups, and any combination thereof.

5. A capacitor, according to claim 1, wherein the one or more dopant groups are selected from electrophilic (acceptor) groups and nucleophilic (donor) groups where the electrophilic groups are selected from —

NO₂, —

NH₃⁺ and —

NR₃⁺ (quaternary nitrogen salts), counterion Cl⁻

, counterion Br⁻

, —

CHO (aldehyde), —

CRO (keto group), —

SO₃H (sulfonic acids), —

SO₃R (sulfonates), SO₂NH₂ (sulfonamides), —

COOH (carboxylic acid), —

COOR (esters, from carboxylic acid side), —

COCl (carboxylic acid chlorides), —

CONH₂ (amides, from carboxylic acid side), —

CF₃, —

CCl₃, —

CN, wherein R is radical selected from the list comprising alkyl (methyl, ethyl, isopropyl, tert-butyl, neopentyl, cyclohexyl etc.), allyl (—

CH₂—

CH═

CH₂), benzyl (—

CH₂C₆H₅) groups, phenyl (+substituted phenyl) and other aryl (aromatic) groups and the nucleophilic groups (donors) are selected from —

O⁻

(phenoxides, like —

ONa or —

OK), —

NH₂, —

NHR, —

NR₂, —

OH, —

OR (ethers), —

NHCOR (amides, from amine side), —

OCOR (esters, from alcohol side), alkyls, —

C₆H₅, vinyls, wherein R is radical selected from the list comprising alkyl (methyl, ethyl, isopropyl, tert-butyl, neopentyl, cyclohexyl etc.), allyl (—

CH2-CH═

CH2), benzyl (—

CH2C6H5) groups, phenyl (+substituted phenyl) and other aryl (aromatic) groups.

6. A capacitor according to claim 1, wherein Core includes one or more rylene fragments.

7. A capacitor according to claim 1, wherein Core includes one or more rylene fragments selected from the list:

8. A capacitor according to claim 1, wherein one or more of said insulating substituents is connected to the Core via one or more of said one or more dopant groups.

9. A capacitor according to claim 6, wherein one or more of said insulating substituents is connected to the Core via one or more of said dopant groups.

10. A capacitor according to claim 1, wherein said Core is comprised of a conjugated system wherein aromatic rings are connected via alternating single and double chain bonds and a repeating backbone, wherein any, and up to all, of the conjugated chemical structure may simultaneously be the repeating backbone.

11. A capacitor according to claim 1, wherein said Core is selected from the group consisting of the following structural formulas 1 to 13:

12. A capacitor according to claim 1, wherein the first and second electrodes are made of a metal.

13. A capacitor according to claim 1, wherein the first and second electrodes are made of any metal and further comprises one or more molecular layers selected from an electro-conductive layer, a field-planarization layer, a tunneling injection blocking layer, a coulomb blocking layer or any combination thereof.

14. A capacitor according to claim 1, wherein one or both of the first and second electrodes are made of copper, said Core includes polyaniline (PANT), and the insulating substituents D and H include fluorinated alkyl substituents.

15. A capacitor according to claim 1, wherein said first electrode includes a metalized tape having a plastic substrate and a metal layer.

16. A capacitor according to claim 15, wherein said plastic substrate has a thickness between about 3 μ

m and about 12 μ

m.

17. A capacitor according to claim 16, wherein said plastic substrate includes a

molecular material described by the general formula

D_p-(Core)-H_q 

 

(I)

where Core is a polarizable conductive anisometric core, having conjugated π

-systems, and characterized by a longitudinal axis, which form supramolecular structures by means of π

-π

-interaction,

D and H are insulating substituents, and

p and q are numbers of the D and H substituents accordingly,

wherein said substituents are selectively attached to any available positions on the polarizable anisometric core including apex positions and lateral positions as related to the longitudinal axis, p and q are independently selected from values 1, 2, 3, 4, and 5, Core possesses two or more dopant groups that enhances polarizability;

wherein one or more of the insulating groups D and one or more of the insulating groups H is each selected independently from the group consisting of alkyl, fluorinated alkyl, chlorinated alkyl, branched and complex alkyl, branched and complex fluorinated alkyl, branched and complex chlorinated alkyl groups, and any combination thereof;

and wherein the at two or more dopant groups are independently selected from electrophilic (acceptor) groups and nucleophilic (donor) groups;

where the electrophilic groups are selected from;

—

NO₂, —

NH₃⁺ and —

NR₃⁺ (quaternary nitrogen salts), counterion Cl⁻

, counterion Br⁻

, —

CHO (aldehyde), —

CRO (keto group), —

SO₃H (sulfonic acids), —

SO₃R (sulfonates), SO₂NH₂ (sulfonamides), —

COOH (carboxylic acid), —

COOR (esters, from carboxylic acid side), —

COCl (carboxylic acid chlorides), —

CONH₂ (amides, from carboxylic acid side), —

CF₃, —

CCl₃, —

CN, wherein R is radical selected from the list comprising alkyl (methyl, ethyl, isopropyl, tert-butyl, neopentyl, cyclohexyl etc.), allyl (—

CH₂—

CH═

CH₂), benzyl (—

CH₂C₆H₅) groups, phenyl (+substituted phenyl) and other aryl (aromatic) groups and the nucleophilic groups (donors) are selected from —

O⁻

(phenoxides, like —

ONa or —

OK), —

NH₂, —

NHR, —

NR₂, —

OH, —

OR (ethers), —

NHCOR (amides, from amine side), —

OCOR (esters, from alcohol side), alkyls, —

C₆H₅, vinyls, wherein R is radical selected from the list comprising alkyl (methyl, ethyl, isopropyl, tert-butyl, neopentyl, cyclohexyl etc.), allyl (—

CH2-CH═

CH2), benzyl (—

CH2C6H5) groups, phenyl (+substituted phenyl) and other aryl (aromatic) groups.

18. An energy storage cell comprising:

one or more capacitive energy storage devices; and

a DC-voltage conversion device;

wherein each of the one or more capacitive energy storage devices includes one or more capacitors as in claim 1, wherein the output voltage of the capacitive energy storage device is an input voltage of the DC-voltage conversion device during discharging the capacitive energy storage device, wherein the input voltage of the capacitive energy storage device is an output voltage of the DC-voltage conversion device while charging the capacitive energy storage device.

19. A method of producing a capacitor, which comprises the steps of;

a) preparation of a conducting substrate serving as one of the electrodes;

b) application of a molecular material on the substrate;

c) formation of the solid layer of the molecular material; and

d) formation of the second electrode on the solid molecular material layer;

wherein the molecular material is described by the general formula

D_p-(Core)-H_q 

 

(I)

where Core is a polarizable conductive anisometric core, having conjugated π

-systems and characterized by a longitudinal axis,

D and H are insulating substituents,

p and q are numbers of the D and H substituents accordingly,

wherein said substituents are selectively attached to any available positions on the polarizable anisometric core including on apex positions and lateral positions as related to the longitudinal axis, and p and q are independently selected from values 1, 2, 3, 4, and 5, and Core possesses one or more selectively attached dopant groups that enhance polarizability.

20. A method according to claim 19, wherein the one or more dopant groups are selected from the group consisting electrophilic (acceptor) groups and nucleophilic (donor) groups;

where the electrophilic groups are selected from —

NO₂, —

NH₃⁺ and —

NR₃⁺ (quaternary nitrogen salts), counterion Cl⁻

, counterion Br⁻

, —

CHO (aldehyde), —

CRO (keto group), —

SO₃H (sulfonic acids), —

SO₃R (sulfonates), SO₂NH₂ (sulfonamides), —

COOH (carboxylic acid), —

COOR (esters, from carboxylic acid side), —

COCl (carboxylic acid chlorides), —

CONH₂ (amides, from carboxylic acid side), —

CF₃, —

CCl₃, —

CN, wherein R is radical selected from the list comprising alkyl (methyl, ethyl, isopropyl, tert-butyl, neopentyl, cyclohexyl etc.), allyl (—

CH₂—

CH═

CH₂), benzyl (—

CH₂C₆H₅) groups, phenyl (+substituted phenyl) and other aryl (aromatic) groups and the nucleophilic groups (donors) are selected from —

O⁻

(phenoxides, like —

ONa or —

OK), —

NH₂, —

NHR, —

NR₂, —

OH, —

OR (ethers), —

NHCOR (amides, from amine side), —

OCOR (esters, from alcohol side), alkyls, —

C₆H₅, vinyls, wherein R is radical selected from the list comprising alkyl (methyl, ethyl, isopropyl, tert-butyl, neopentyl, cyclohexyl etc.), allyl (—

CH2-CH═

CH2), benzyl (—

CH2C6H5) groups, phenyl (+substituted phenyl) and other aryl (aromatic) groups.

21. A method according to claim 19, wherein the application step b) comprises application of a solution of the molecular material, and the solid layer formation step c) comprises drying to form a solid molecular material layer.

22. A method according to claim 19, wherein the application step b) comprises application of a melt of the molecular material, and the solid layer formation step c) comprises cooling down to form a solid molecular material layer.