Refinish coating composition

• US 10,358,573 B2
• Filed: 01/25/2018
• Issued: 07/23/2019
• Est. Priority Date: 10/31/2016
• Status: Active Grant

• Current Assignee: PPG Architectural Finishes, Inc (Nouryon BV)
• Original Assignee: PPG Architectural Finishes, Inc (Nouryon BV)
• Inventors: Kordosh, John R.
• Primary Examiner(s): Bernshteyn, Michael
• Application Number:
  US15/880,053
• Publication Number:
  US 20180148598A1
• Time in Patent Office: 544 Days
• Field of Search: 524 92
• CPC Class Codes: B05D 3/007 After-treatment
• CPC Class Codes: C08K 5/0091 Complexes with metal-heteroatom-bonds
• CPC Class Codes: C08K 5/544 containing nitrogen
• CPC Class Codes: C08L 33/10 Homopolymers or copolymers of methacrylic acid esters
• CPC Class Codes: C09D 167/08 Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: C09D 5/021 Aerosols aerosol compositions C09K3/30
• CPC Class Codes: C09D 7/20 Diluents or solvents
• CPC Class Codes: C09D 7/45 Anti-settling agents
• CPC Class Codes: C09D 7/46 Anti-skinning agents
• CPC Class Codes: C09D 7/63 organic
• CPC Class Codes: C09F 9/00 Compounds to be used as driers, i.e. siccatives

Abstract

The present invention is directed to a coating composition comprising an alkyd resin; an acrylic polymer; a metallic drier; an adhesion promoter; and a solvent. Also disclosed are coatings formed from the coating composition. Also disclosed are methods of coating a substrate.

Claims

1. A coating composition comprising:

a chain-stopped alkyd resin;

an acrylic polymer;

a metallic drier; and

a solvent.

2. The coating composition of claim 1, wherein the chain-stopped alkyd resin has a hydroxyl equivalent weight of 200 g/OH to 800 g/OH.

3. The coating composition of claim 1, wherein the acrylic polymer comprises a copolymer comprising the residue of methyl methacrylate and butyl methacrylate.

4. The coating composition of claim 1, wherein the acrylic polymer has a weight average (M_w) molecular weight of 15,000 g/mol to 40,000 g/mol.

5. The coating composition of claim 1, wherein the acrylic polymer comprises acrylic polymer comprising hydroxyl functional groups in an amount of 1% by weight or less, based on the total weight of the acrylic polymer.

6. The coating composition of claim 1, wherein the weight ratio of chain-stopped alkyd resin to acrylic polymer is 1:

1 to 10;

1.

7. The coating composition of claim 1, wherein the metallic drier comprises a metal ligand complex comprising [(bispidon)Fe(II)Cl]Cl, chloro[dimethyl-9,9-dihydroxy-3-methyl-2,4-di(2-pyridyl-κ

N)-7-[(2-pyridinyl-κ

N)methyl]-3,7-diazabicyclo[3.3.1]nonane-1,5-dicarboxylate-κ

N3, κ

N7].

8. The coating composition of claim 1 further comprising an adhesion promoter.

9. The coating composition of claim 8, wherein the adhesion promoter comprises a silane.

10. The coating composition of claim 1 comprising:

20% to 45% by weight of the alkyd resin, based on the total weight of the coating composition;

2% to 10% by weight of the acrylic polymer, based on the total weight of the coating composition;

0.20% to 0.65% by weight of the metallic drier, based on the total weight of the coating composition; and

23% to 55% by weight of the solvent, based on the total weight of the coating composition.

11. The coating composition of claim 10, wherein the solvent comprises a high-evaporating solvent present in an amount of 20% to 40% by weight, based on the total weight of the coating composition.

12. The coating composition of claim 11, wherein the solvent further comprises a slow-evaporating solvent present in an amount of 3% to 15% by weight, based on the total weight of the coating composition.

13. The coating composition of claim 10, further comprising 18% to 35% by weight of a pigment, based on the total weight of the coating composition.

14. The coating composition of claim 10, further comprising 0.10% to 1.00% by weight of a dispersant, based on the total weight of the coating composition.

15. The coating composition of claim 10, further comprising 0.50% to 1.10% by weight of an anti-settling agent, based on the total weight of the coating composition.

16. The coating composition of claim 10, further comprising 0.10% to 0.50% by weight of an anti-skinning agent, based on the total weight of the coating composition.

17. The coating composition of claim 1, further comprising a propellant, wherein the coating composition is an aerosol coating composition.

18. The coating composition of claim 1, wherein the coating composition has a viscosity of 50 to 60 KU as measured by a Stormer-type viscometer according to ASTM D 562 at 77°

F.

19. The coating composition of claim 1, wherein the coating composition has a sag resistance of less than 7 wet mils, as measured by an anti-sag meter according to ASTM D4400.

20. The coating composition of claim 1, wherein the coating composition exhibits a 20°

gloss value of at least 70 gloss units as measured according to ASTM D523 after cure.

21. The coating composition of claim 1, wherein the coating composition exhibits a whiteness value of at least 65 as measured according to ASTM E-313 after cure.

22. The coating composition of claim 1, wherein the coating composition exhibits a yellowness value of no more than 6 as measured according to ASTM E-313 after cure.

23. The coating composition of claim 1, wherein the coating composition exhibits a pencil hardness of at least HB as measured according to ASTM D3363 after 72 hours curing under ambient conditions.

24. The coating composition of claim 1, wherein the coated composition exhibits an adhesion of at least 800 psi (5,515.8 kPa) after 48 hours of curing under ambient conditions as measured according to the Adhesion Test Procedure.

25. A coating formed by curing the coating composition of claim 1.

26. A method of coating a substrate comprising:

applying the coating composition of claim 1 to the substrate; and

allowing the coating composition to cure to form a coating at ambient conditions.

27. The method of claim 26, wherein the coating composition cures to form a coating at ambient conditions in less than 72 hours.