Multi-pane window with a low emissivity layer and a photochromic glass

• US 10,393,934 B2
• Filed: 09/08/2016
• Issued: 08/27/2019
• Est. Priority Date: 09/11/2015
• Status: Active Grant

• Current Assignee: Corning Incorporated
• Original Assignee: Corning Incorporated
• Inventors: Borrelli, Nicholas Francis, Lonnroth, Nadja Teresia, Prassas, Michel, Then, Paul Michael, Zenteno, Luis Alberto
• Primary Examiner(s): Deherrera, Kristina M
• Application Number:
  US15/259,572
• Publication Number:
  US 20170075049A1
• Time in Patent Office: 1,083 Days
• Field of Search: 359359-360, 35115903, 35115961-15962
• CPC Class Codes: B32B 17/10055 with at least one intermediate air space
• CPC Class Codes: B32B 17/10119 having a composition deviating from the basic composition of soda-lime glass, e.g. borosilicate
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10486 photochromic
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 3/093 containing zinc or zirconium
• CPC Class Codes: C03C 3/11 containing halogen or nitrogen
• CPC Class Codes: C03C 4/06 for phototropic or photochromic glass
• CPC Class Codes: E06B 2009/2417 Light path control; means to control reflection
• CPC Class Codes: E06B 2009/2464 featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
• CPC Class Codes: E06B 3/6715 specially adapted for increased thermal insulation or for controlled passage of light E06B3/66323 takes precedence; coating of glass pains C03C17/00; devices or arrangements for controlling the intensity, colour, phase, polarisation or direction of light G02F1/00
• CPC Class Codes: E06B 9/24 Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blindsoperating, guiding or securing devices or arrangements for roll-type closures E06B9/56; free-hanging flexible screens A47H23/00
• CPC Class Codes: G02B 5/23 Photochromic filters
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
• CPC Class Codes: G02B 5/285 comprising deposited thin solid films G02B5/281 - G02B5/289 take precedence; multilayered film filters for fibre optic multiplexing G02B6/29361

Abstract

A multi-pane window having a low emissivity layer and a photochromic glass. The window includes at least two panes of glass. An outside pane for interaction with the outdoors and an inside pane spaced apart from the outside pane. The outside pane includes a low emissivity coating. The inside pane includes a photochromic glass. The outside pane transmits solar light wavelengths. The photochromic glass is darkened upon exposure to light transmitted by the outside pane.

Claims

1. A window comprising:

an outside glass pane for interaction with outdoors comprising a low emissivity layer that transmits actinic radiation,

an inside glass pane for interaction with indoors comprising a photochromic glass and a non-photochromic glass separated by a low emissivity interface positioned therebetween,

the inside glass pane is spaced apart from and disposed substantially parallel to the outside glass pane, and

the actinic radiation transmitted by the outside glass pane and low emissivity layer reduces visible light transmittance through the photochromic glass.

2. The window of claim 1 wherein the outside glass pane reflects light comprising a wavelength from 701 nm to 2000 nm, and transmits light comprising a wavelength from 350 nm to 700 nm.

3. The window of claim 2 wherein the actinic radiation transmitted by the outside glass pane and low emissivity layer comprises a wavelength from 350 nm to 420 nm.

4. The window of claim 2 wherein the actinic radiation transmitted by the outside glass pane and low emissivity layer contacts the photochromic glass to reduce visible light transmittance there through by 40% or more.

5. The window of claim 1 wherein visible light transmittance through the photochromic glass reduces when the photochromic glass is at room temperature.

6. The window of claim 1 wherein the low emissivity layer comprises metallic silver, metallic nickel, silicon nitride, tin oxide, zirconium oxide, zinc oxide, or combinations thereof.

7. The window of claim 1 wherein the outside glass pane comprises a soda-lime glass, an aluminosilicate glass, a borosilicate glass, or combinations thereof.

8. The window of claim 1 wherein the photochromic glass comprises, in terms of weight percent:

SiO₂ 54-66;

Al₂O₃ 7-15;

B₂O₃ 10-25;

Li₂O 0.5-4;

Na₂O 1-15;

K₂O 0-12;

ZrO₂ 0-6;

TiO₂ 0-3;

PbO 0-1;

Ag 0.1-1;

Cl 0.1-1;

Br 0-3;

CuO 0.006-0.02;

Sb₂O₃0-0.2;

SnO₂ 0-0.2;

CeO₂ 0-2.5; and

F 0-2.5.

9. The window of claim 1 wherein the outside glass pane is spaced apart from the inside glass pane by an insulating gas.

10. The window of claim 1 wherein the outside glass pane is spaced apart from the inside glass pane by a first distance.

11. The window of claim 10 wherein the first distance between the outside and inside glass panes is from 5 mm to 25 mm.

12. The window of claim 1 wherein the photochromic glass transmits ≥

20% of visible light that contacts the outside glass pane there through when visible light transmittance through the photochromic glass is reduced.

13. The window of claim 1 wherein the low emissivity interface extends between and contacts both the photochromic glass and the non-photochromic glass of the inside glass pane.

14. The window of claim 13 wherein the non-photochromic glass comprises a soda-lime glass, an alurninosilicate glass, a borosilicate glass, or combinations thereof.

15. The window of claim 13 further comprising a low emissivity layer on a surface of the non-photochromic glass of the inside glass pane opposite the low emissivity interface.

16. The window of claim 1 further comprising a third glass pane,

the third glass pane spaced apart from and disposed substantially parallel to the outside glass pane by a second distance, and

the third glass pane spaced apart from and disposed substantially parallel to the inside glass pane by a third distance.

17. The window of claim 16 wherein the third glass pane comprises a low emissivity coating or a photochromic glass.

18. A method of installing the window of claim 1 comprising:

arranging the outside glass pane relative to the inside glass pane,

wherein the outside glass pane is adjacent a building exterior and the inside glass pane is adjacent the building interior.

19. A window comprising:

an external glass pane comprising a low emissivity layer, the external glass pane transmits solar light from a building exterior comprising actinic radiation,

an internal glass pane comprising a photochromic glass and a non-photochromic glass separated by a low emissivity interface, the internal glass pane is spaced apart from and disposed substantially parallel to the external glass pane, and

the actinic radiation transmitted by the external glass pane darkens the photochromic glass and reduces visible light transmittance through the photochromic glass.

20. The window of claim 19 wherein the low emissivity layer reflects light comprising a wavelength from 701 nm to 2000 nm.

21. The window of claim 19 wherein the actinic radiation transmitted by the external glass pane and low emissivity layer contacts the photochromic glass to reduce visible light transmittance there through by 40% or more.

22. The window of claim 19 wherein visible light transmittance through the photochromic glass reduces for room temperature photochromic glass.

23. The window of claim 19 wherein the low emissivity layer transmits ≤

20% of infrared light contacting the external glass pane.

24. The window of claim 19 wherein the photochromic glass transmits ≤

35% of visible light that contacts the external glass pane when darkened.

25. The window of claim 19 wherein the external glass panes comprises soda-lime glass.

26. The window of claim 19 further comprising a spacer between the external glass pane and the internal glass pane.

27. The window of claim 26 wherein the spacer is one of an edge seal formed around at least respective portions of the external and internal glass panes, a metallic pillar, or a glass bump formed integrally in the external or internal glass pane.

28. The window of claim 19, wherein the actinic radiation comprises a wavelength from 350 nm to 420 nm.

29. A building including a multi-pane window installed between an interior and an exterior of the building, the window comprising:

an exterior glass pane comprising a low emissivity layer, the exterior glass pane and low emissivity layer transmit actinic radiation from the building exterior,

an interior glass pane comprising a photochromic glass, a non-photochromic glass, and an interface disposed therebetween including low emissivity composition, the interior glass pane is spaced apart from and disposed substantially parallel to the exterior glass pane, and

the actinic radiation transmitted by the exterior glass pane activates the photochromic glass to reduce visible light transmittance through the photochromic glass by 40% or more.

30. The building of claim 29, wherein the actinic radiation comprise a wavelength from 350 nm to 420 nm.