Methods for fuel conversion

• US 10,501,318 B2
• Filed: 10/22/2018
• Issued: 12/10/2019
• Est. Priority Date: 02/05/2013
• Status: Active Grant

• Current Assignee: Ohio State Innovation Foundation (Ohio State University)
• Original Assignee: Ohio State Innovation Foundation (Ohio State University)
• Inventors: Fan, Liang-Shih, Luo, Siwei, Zeng, Liang
• Primary Examiner(s): Call, Douglas B
• Application Number:
  US16/166,746
• Publication Number:
  US 20190055123A1
• Time in Patent Office: 414 Days
• CPC Class Codes: B01J 8/12 moved by gravity in a downward flow
• CPC Class Codes: C01B 2203/02 Processes for making hydrogen or synthesis gas
• CPC Class Codes: C01B 2203/0255 containing a non-catalytic partial oxidation step
• CPC Class Codes: C01B 2203/1241 Natural gas or methane
• CPC Class Codes: C01B 3/344 using non-catalytic solid particles
• CPC Class Codes: C10J 2300/0916 Biomass
• CPC Class Codes: C10J 2300/093 Coal
• CPC Class Codes: C10J 2300/0953 Gasifying agents
• CPC Class Codes: C10J 2300/1807 Recycle loops, e.g. gas, solids, heating medium, water
• CPC Class Codes: C10J 3/57 Gasification using molten salts or metals C10J3/02, C10J3/46 take precedence
• CPC Class Codes: Y02E 60/32 Hydrogen storage
• CPC Class Codes: Y02P 20/133 Renewable energy sources, e.g. sunlight

Abstract

In one embodiment described herein, fuel may be converted into syngas by a method comprising feeding the fuel and composite metal oxides into a reduction reactor in a co-current flow pattern relative to one another, reducing the composite metal oxides with the fuel to form syngas and reduced composite metal oxides, transporting the reduced composite metal oxides to an oxidation reactor, regenerating the composite metal oxides by oxidizing the reduced composite metal oxides with an oxidizing reactant in the oxidation reactor, and recycling the regenerated composite metal oxides to the reduction reactor for subsequent reduction reactions to produce syngas. The composite metal oxides may be solid particles comprising a primary metal oxide and a secondary metal oxide.

Claims

1. A method for converting carbonaceous fuel into syngas, the method comprising:

feeding composite metal oxides and the carbonaceous fuel into a reduction reactor having a top and a bottom, wherein the carbonaceous fuel and the composite metal oxides are fed into the top of the reduction reactor, whereupon the composite metal oxides form a packed bed and the composite metal oxides and the carbonaceous fuel flow downward through the reactor in a co-current flow pattern relative to one another;

reducing the composite metal oxides with the carbonaceous fuel in the reduction reactor to form syngas and reduced composite metal oxides;

removing the syngas and the reduced composite metal oxides from the bottom of the reduction reactor wherein the syngas comprises hydrogen and carbon monoxide;

transporting the reduced composite metal oxides to an oxidation reactor;

regenerating the composite metal oxides by oxidizing the reduced composite metal oxides with an oxidizing reactant in the oxidation reactor; and

recycling the regenerated composite metal oxides to the reduction reactor for subsequent reduction reactions to produce syngas in the reduction reactor;

wherein the composite metal oxides comprise iron, titanium and oxygen and the reduced metal oxides comprise FeO·

TiO₂, or wherein the composite metal oxides comprise iron aluminum and oxygen and the reduced metal oxides comprise FeO·

Al₂O₃.

2. The method of claim 1, wherein the oxidizing reactant comprises air, oxygen, steam, carbon dioxide, or any combination thereof.

3. The method of claim 1, wherein a ratio of hydrogen to carbon monoxide can be controlled.

4. The method of claim 1, wherein the syngas comprises a stoichiometric ratio of carbon monoxide to hydrogen of about 1:

2.

5. The method of claim 1, wherein the carbonaceous fuel is co-injected with a carbon-rich or hydrogen-rich reactant to change a carbon monoxide to hydrogen ratio of the syngas.

6. The method of claim 1, wherein oxygen or oxygen releasing material is introduced into the reduction reactor to increase reaction kinetics for syngas production.

7. The method of claim 1, wherein the reducing of the composite metal oxides occurs at a temperature in the range of between about 500°

C. and about 1200°

C.

8. The method of claim 1, wherein the syngas comprises at least about 85 mol % carbon monoxide and hydrogen.

9. The method of claim 1, wherein the syngas comprises carbon dioxide in an amount that is less than about 10 mol % of the syngas, and steam in an amount that is less than about 10 mol % of the syngas.

10. The method of claim 1, wherein the composite metal oxides further comprises a dopant/promoter comprising Ca, Ce, Pt, Ru, Rh, La, Fe, Cu, oxides thereof, or any combination thereof.