Inorganic material composite

• US 10,508,187 B2
• Filed: 05/24/2016
• Issued: 12/17/2019
• Est. Priority Date: 04/29/2009
• Status: Active Grant

• Current Assignee: Tundra Composites, LLC.
• Original Assignee: Tundra Composites, LLC.
• Inventors: Heikkila, Kurt E., Williams, Rodney K., Kroll, John S.
• Primary Examiner(s): Cain, Edward J
• Application Number:
  US15/162,787
• Publication Number:
  US 20160376417A1
• Time in Patent Office: 1,302 Days
• Field of Search: 523210, 523218, 523219, 523220
• CPC Class Codes: B60C 1/00 Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
• CPC Class Codes: C08J 2327/16 Homopolymers or copolymers of vinylidene fluoride
• CPC Class Codes: C08J 2327/18 Homopolymers or copolymers of tetrafluoroethylene
• CPC Class Codes: C08J 2327/20 Homopolymers or copolymers of hexafluoropropene
• CPC Class Codes: C08J 5/04 Reinforcing macromolecular compounds with loose or coherent fibrous material
• CPC Class Codes: C08K 2003/2227 of aluminium
• CPC Class Codes: C08K 2201/005 Additives being defined by their particle size in general
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 7/28 Glass
• CPC Class Codes: C08K 9/00 Use of pretreated ingredients
• CPC Class Codes: C08K 9/04 Ingredients treated with organic substances treated with macromolecular compounds C08K9/08
• CPC Class Codes: C08L 21/00 Compositions of unspecified rubbers
• CPC Class Codes: Y10T 428/249974 Metal- or silicon-containing element

Abstract

The invention relates to a ceramic particulate and polymer composite having enhanced viscoelastic and rheological properties.

Claims

1. A method of making an inorganic material particulate and polymer composite comprising:

(a) coating about 40 to 90 vol. % of an inorganic material particulate having a particle size greater than about 5 microns with an interfacial modifier, the percentage based on the composite, to form an interfacial modifier coated particle;

(b) combining the coated particle with a polymer phase under melt processing conditions to make the composite, and;

(c) forming a pellet by melt processing the composite.

2. The method of claim 1 wherein the composite has a tensile strength of about 0.1 to 30 times that of the base polymer.

3. The method of claim 1 wherein the composite has a tensile elongation of about 5% to 100% of the base polymer.

4. The method of claim 3 wherein the composite has a thermoplastic shear of at least 5 sec⁻

1.

5. The method of claim 1 wherein the composite comprises greater than 30 vol-% of a glass microsphere, a ceramic particulate or an inorganic mineral particulate.

6. The method of claim 1 wherein the coated particle is combined with the polymer phase to make the composite in an extruder.

7. The method of claim 1 wherein the particulate has a P_s of about 10 to 1000 microns.

8. The method of claim 1 wherein the particulate has a particle size P_s of about 10 to 500 microns and the composite additionally comprises a second particulate with a second particle size P_s¹ that differs from P_s by at least 5 microns.

9. The method of claim 8 wherein the second particulate comprises a metal particulate, a second solid inorganic particulate, a glass particulate, or a ceramic particulate.

10. The method of claim 8 wherein the second particulate comprises a hollow glass sphere having a particle size (P_s) of about 10 to 500 microns.

11. The method of claim 8 wherein the second particulate comprises a silica having a particle size (P_s) of about 75 to 500 microns.

12. The method of claim 1 wherein the polymer is selected from the group of thermoplastic polymers consisting of a polyamide, a nylon, a poly (ethylene-co-vinyl acetate), a synthetic rubber, a polyvinyl chloride, a fluoropolymer, a polyolefin, a thermoset polymer, a fluoroelastomer, and a high-density polyolefin.

13. The method of claim 1 wherein the particulate comprises a coating comprising about 0.01 to 4 wt. % of an interfacial modifier the percentage based on the composite.

14. The method of claim 1 wherein the particle has an excluded volume of about 13 vol.-% to about 70 vol.-%.

15. A particulate polymer composite comprising an inorganic material particle in a polymer phase, the composite comprising:

(a) about 90 to 40 volume-% of the inorganic material particle, having a density greater than 0.10 gm-cm<sup>−

3</sup> and less than 10 gm-cm<sup>−

3</sup>, a particle size greater than 5 microns, a circularity greater than 12.5; and

(b) about 10 to 70 volume-% of a polymer phase;

wherein the particle has a coating comprising about 0.005 to 8 wt.-% of an interfacial modifier, the percentage based on the composite; and

a composite density of about 0.4 to 5 gm-cm<sup>−

3</sup>.

16. The composite of claim 15 wherein the inorganic material particle is an inorganic mineral particle.

17. The composite of claim 15 further comprising fiber with the coating of the interfacial modifier.

18. A method of making an inorganic material particulate, fiber, and polymer composite comprising:

(a) coating about 40 to 90 vol. % of an inorganic material particulate having a particle size greater than about 5 microns and fiber with an aspect ratio greater than 10, with an interfacial modifier, the percentage based on the composite, to form coated particle and fiber;

(b) combining the coated particle and the fiber with a polymer phase to make the composite, and;

(c) forming a pellet by melt processing the composite.