Method and system for recycling spent ethylene glycol from recovered aircraft de-icing solution

• US 10,513,481 B2
• Filed: 09/05/2018
• Issued: 12/24/2019
• Est. Priority Date: 03/16/2016
• Status: Active Grant

• Current Assignee: AÉro Mag 2000 Rrr Inc.
• Original Assignee: AÉro Mag 2000 Rrr Inc.
• Inventors: Lepine, Mario, Bergeron, Ghislain, Guy, Michel
• Primary Examiner(s): Miller, Jonathan
• Application Number:
  US15/999,771
• Publication Number:
  US 20190010105A1
• Time in Patent Office: 475 Days
• CPC Class Codes: B01D 15/08 Selective adsorption, e.g. chromatography
• CPC Class Codes: B01D 2311/246 Concentration control
• CPC Class Codes: B01D 2311/2626 Absorption or adsorption
• CPC Class Codes: B01D 2311/2649 Filtration
• CPC Class Codes: B01D 3/148 in combination with at least one evaporator
• CPC Class Codes: B01D 3/42 Regulation; Control
• CPC Class Codes: B01D 61/145 Ultrafiltration
• CPC Class Codes: B64F 5/23 by liquid application; Spraying installations therefor, e.g. fitted on vehicles
• CPC Class Codes: C07C 29/76 by physical treatment
• CPC Class Codes: C07C 29/80 by distillation
• CPC Class Codes: C07C 31/202 Ethylene glycol
• CPC Class Codes: C07C 31/205 1,3-Propanediol; 1,2-Propanediol
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product

Abstract

A method and a system for recycling spent ethylene or propylene glycol recovered from aircraft deicing solutions is described. The recovered spent ethylene or propylene glycol contains water and other undesirable substances which require to be removed to produce a solution free of these substances which can be further processed to remove substantially all of the water content and to blend-in additives required to certify the final glycol solution for aircraft deicing. The method and system employs a computer controller for continuous automatic batch processing of the spent glycol, including, in combination, filtering, distillation, blending and testing in specific sequences and achieves an improved quality recycled glycol of a purity of at least 99.5% and preferably between 99.6% to 99.9% glycol concentration.

Claims

1. A method of treating spent ethylene or propylene glycol recovered from aircraft de-icing solutions containing glycol, water, solids and other substances to produce substantially virgin glycol, said method comprising, in combination, the steps of:

i) recovering in a collection reservoir, having a segmented storage compartments, spent glycol from a tarmac of aircraft de-icing area to permit sampling by pumping said spent glycol solution through a densimeter to determine the glycol concentration in said spent glycol,

ii) removing spent glycol having a predetermined low % concentration from the collection reservoir to produce a working spent glycol and pumping said working spent glycol in one or more storage a-tanks,

iii) filtering said working spent glycol from said one or more storage tanks through at least two filtering stages to substantially remove all remaining solids and substances followed by an evaporation step wherein said working spent glycol is heated to a temperature sufficient to evaporate only water to bring said working spent glycol to a glycol concentration of about 50% for storage in a buffer tank,

iv) transferring said glycol having a concentration of about 50% purity to said buffer tank,

v) transferring a predetermined volume of said glycol having a concentration of about 50% purity from said buffer tank to a pH adjusting mixing and sampling tank,

vi) sampling and adjusting the pH of said glycol concentration of about 50% purity in said pH adjusting mixing and sampling tank by agitation and the introduction of an additive to adjust the pH to a desired value and then carbon filtering said glycol concentration of about 50% purity and feeding same to a distillation tower holding tank,

vii) feeding a predetermined volume of said carbon filtered glycol concentration of about 50% purity from said distillation tower holding tank to an evaporator section of a distillation tower operating under vacuum,

viii) heating in an evaporator section of said distillation tower said batch at a predetermined temperature to evaporate said glycol concentration of about 50% purity in a continuous stream of vapors,

ix) sensing the temperature of said stream of vapors in a hot packing section of a chimney section spaced above said evaporator section to monitor the actual temperature of said stream of vapors and feeding temperature signals representative thereof to a computer controller,

x) condensing said stream of vapors after said stream of vapors exits said chimney section to condense said stream of vapors and cooling it into a condensed liquid,

xi) monitoring on a continuous basis by said computer controller (a) said temperature signals to correlate same with the evaporation temperature of water and glycol, and (b) glycol concentration signals form a refractometer located in a conduit through which flows said condensed liquid, to recover from said condensed liquid, in separate reservoirs, and by the operation of valves, water, water mixed with glycol below a concentration of 99.5% purity, and substantially virgin glycol having a concentration of at least 99.5%,

xii) directing said substantially virgin glycol from its associated reservoir for further testing and certification of the purity thereof and storing same in certified holding tanks for use by aircraft de-icing vehicles, and directing said water from said separate reservoirs to a storage tank for disposal or re-use and directing said water mixed with glycol having a glycol concentration less than 99.5% purity to a holding tank feeding said evaporator, and

xiii) quality testing said substantially virgin glycol having a concentration of at least 99.5% purity to certify and store same in certified holding tanks for use by aircraft de-icing vehicles.

2. The method of claim 1 wherein said substantially virgin glycol of step (xi) has a concentration in the range of from about 99.6% to 99.9% purity and further wherein after step (xii) of certification of the purity thereof and storing same in certified holding tanks in step (xii), there is provided the further step of blending said certified glycol solution of from about 99.6% to 99.9% purity into a blending tank where additives are blended with said certified substantially virgin glycol.

3. The method of claim 1 wherein in step (xi) said separated water mixed with glycol below a concentration of 99.5% purity and collected in associated reservoirs is fed back to a holding tank of said distillation tower to be re-introduced into said distillation tower for further evaporation, said step (vii) further comprising feeding said predetermined volume of carbon filtered glycol concentration in said holding tank of said distillation tower.

4. The method of claim 1 wherein in said step (ii) said spent glycol having a predetermined low % purity has a concentration of below 5% purity, is caused to rise in a compartment of said segmented storage means to an overflow conduit for disposal to sewage.

5. The method of claim 1 wherein in said filtering step (iii) one of said at least two filtering stages comprises a 5 micron bag filter which feeds filtered glycol solution to a working tank and wherein said filtered glycol solution from said working tank is pumped in a continuous loop and through a 0.5 micron ceramic filter, said working spent glycol being filtered in said continuous loop to achieve a desired ultra-filtered spent glycol free of substances of particle size above 0.5 microns, and feeding said ultra-filtered spent glycol to a further holding tank which feeds said filtered spent glycol to one or more evaporators.

6. The method of claim 5 wherein said further holding tank is provided with level sensing means to provide level signals to said computer controller which controls the operation of said continuous filtering loop, said evaporators being operated on a continuous basis and having level sensing means to permit said computer controller to dispense filtered spent glycol solution thereto to maintain a predetermined volume of said filtered spent glycol solution in said one or more evaporators.

7. The method of claim 6 wherein said one or more evaporators are each provided with two electric resistive heating elements connected for independent operation through switch means operated by said computer controller to ensure continuous operation of said evaporator in the event of failure of one of said resistive heating elements, a densimeter associated with each said one or more evaporators to detect the glycol concentration in a predetermined area of said evaporators to feed glycol concentration signal values to said computer controller which operate valves connected to each said evaporators to discharge spent glycol solution having a concentration of 50% purity from a bottom region of said one or more evaporators into said buffer tank and to shut off said valves when said concentration signal values fall below a glycol concentration of 50% purity.

8. The method of claim 1 wherein said glycol concentration of about 50% purity stored in said buffer tank is subjected to a pre-treatment as defined by step (vi) by the addition of NaOH (sodium hydroxide) in an agitator tank as desired to adjust the pH to said desired value, said desired value being about 7.8 on the pH scale, and further wherein said carbon filtering of step (vii) is to remove color and odors from said glycol concentration before feeding same to a holding tank of said distillation tower where a control level of said pre-treated glycol concentration of 50% purity is maintained for batch feeding an evaporator section of said distillation tower.

9. The method of claim 1 wherein said evaporator section of said distillation tower has a heating coil in which is circulated hot steam from a boiler to evaporate in said stream of vapors said predetermined batch of glycol concentration of 50% purity, a vacuum pump connected to said distillation tower downstream of said evaporator section, said hot packing section having a plurality of stainless steel packings which are heated along said chimney section by said stream of vapors, and wherein after said step (x) and before said step (xi) there is provided the further step of feeding said condensed liquid into a cooler device to achieve complete condensation.

10. The method of claim 2 wherein said step (xiii) comprises feeding said substantially virgin glycol having a concentration of at least 99.5% purity for said certified holding tanks to a blending tank which is provided with level tap valves to permit testing of the pH, the clarity, the Brix and refracting index of said substantially virgin glycol at different levels of said blending tank, and wherein the volume of said substantially virgin glycol in said blending tank is determined by a scale disposed under said blending tank, and pumping means to pump said substantially virgin glycol from said blending tank to further certified holding tanks for use by said de-icing vehicles.