Intermediate film for laminated glass, and laminated glass

• US 10,596,785 B2
• Filed: 09/28/2015
• Issued: 03/24/2020
• Est. Priority Date: 09/29/2014
• Status: Active Grant

• Current Assignee: Sekisui Chemical Company Limited (Sekisui)
• Original Assignee: Sekisui Chemical Company Limited (Sekisui)
• Inventors: Oota, Yuusuke, Tsunoda, Ryuta
• Primary Examiner(s): Khan, Tahseen
• Application Number:
  US15/509,057
• Publication Number:
  US 20170274631A1
• Time in Patent Office: 1,639 Days
• Field of Search: 428213
• CPC Class Codes: B32B 17/10568 varying in thickness
• CPC Class Codes: B32B 17/10605 Type of plasticiser
• CPC Class Codes: B32B 17/10633 Infrared radiation absorbing or reflecting agents
• CPC Class Codes: B32B 17/10651 comprising colorants, e.g. dyes or pigments
• CPC Class Codes: B32B 17/10678 comprising UV absorbers or stabilizers, e.g. antioxidants
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2307/306 Resistant to heat
• CPC Class Codes: B32B 2605/006 Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/30 comprising vinyl (co)polymers; comprising acrylic (co)polymers
• CPC Class Codes: B60J 1/00 Windows; Windscreens; Accessories therefor B60J10/00 takes precedence; air curtains instead of windows B60J9/04 ; sealing strips for windshields B60J10/70; sealing sash guides for sliding window panes B60J10/74; glass partitions inside vehicles to protect occupants against personal attack B60R21/12
• CPC Class Codes: B60J 1/02 arranged at the vehicle front , e.g. structure of the glazing, mounting of the glazing on windscreen mounted antenna wire H01Q1/1271
• CPC Class Codes: C01G 41/02 Oxides; Hydroxides
• CPC Class Codes: C08K 2003/2258 of tungsten
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 5/0041 Optical brightening agents, organic pigments
• CPC Class Codes: C08L 29/14 Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols

Abstract

There is provided an interlayer film for laminated glass with which a low yellow index value, low excitation purity and high heat shielding properties can be achieved in spite of the thickness varying with places. The interlayer film for laminated glass according to the present invention has a two or more-layer structure, has a thickness of one end thinner than a thickness of the other end at the opposite side of the one end and includes a first layer containing a thermoplastic resin and a second layer containing a thermoplastic resin, the difference between the maximum thickness and the minimum thickness in the first layer is smaller than the difference between the maximum thickness and the minimum thickness in the second layer, and the first layer contains a heat shielding compound.

Claims

1. An interlayer film for laminated glass having a two or more-layer structure and having a thickness of one end thinner than a thickness of the other end at the opposite side of the one end, comprising a first layer containing a polyvinyl butyral resin as a thermoplastic resin, triethylene glycol di-2-ethylhexanoate as a plasticizer, an ultraviolet ray screening agent, and an oxidation inhibitor;

and a second layer containing a polyvinyl butyral resin as a thermoplastic resin, triethylene glycol di-2-ethylhexanoate as a plasticizer, an ultraviolet ray screening agent, and an oxidation inhibitor;

wherein the difference between the maximum thickness and the minimum thickness in the first layer is smaller than the difference between the maximum thickness and the minimum thickness in the second layer,

the first layer contains cesium-doped tungsten oxide particles as a heat shielding compound, and

when a distance between the one end and the other end of the interlayer film is defined as X, an excitation purity is 2.9 or less at a point positioned at a distance of 0.1X from the other end being thick in thickness of the interlayer film toward the one end of the interlayer film.

2. The interlayer film for laminated glass according to claim 1, wherein the sectional shape in the thickness direction of the first layer is a rectangular shape, the wedge angle of the first layer is smaller than the wedge angle of the second layer, or the difference between the maximum thickness and the minimum thickness of the first layer is 100 μ

m or less.

3. The interlayer film for laminated glass according to claim 1, wherein the thickness of the one end of the first layer of the interlayer film is thinner than the thickness of the other end of the first layer of the interlayer film.

4. The interlayer film for laminated glass according to claim 1, wherein the first layer has a portion in which the sectional shape in the thickness direction is a wedge-like shape.

5. The interlayer film for laminated glass according to claim 1, further having a portion in which the sectional shape in the thickness direction is a wedge-like shape.

6. A laminated glass, comprising:

a first laminated glass member;

a second laminated glass member; and

the interlayer film for laminated glass according to claim 1,

the interlayer film for laminated glass being arranged between the first laminated glass member and the second laminated glass member.

7. The interlayer film for laminated glass according to claim 1, further comprising an Ingredient X,

wherein the Ingredient X is at least one selected from the group consisting of phthalocyanine, a derivative of phthalocyanine, naphthalocyanine, a derivative of naphthalocyanine, anthracyanine, and a derivative of anthracyanine.

8. The interlayer film for laminated glass according to claim 7, wherein in 100% by weight of a layer containing the Ingredient X, the content of the Ingredient X is 0.001% by weight or more and 0.2% by weight or less.

9. The interlayer film for laminated glass according to claim 1, wherein each of the oxidation inhibitor in the first layer and the oxidation inhibitor in the second layer comprises at least one of a phenol-based oxidation inhibitor and a phosphorus-based oxidation inhibitor.

10. The interlayer film for laminated glass according to claim 9, wherein the content of the oxidation inhibitor in the first layer is 0.1% by weight or more and 2% by weight or less in 100% by weight of the first layer, and the content of the oxidation inhibitor in the second layer is 0.1% by weight or more and 2% by weight or less in 100% by weight of the second layer.

11. The interlayer film for laminated glass according to claim 1, an excitation purity is 3.0 or less at a point positioned at a distance of 0.1X from the one end being thin in, thickness of the interlayer film toward the other end of the interlayer film.

12. The interlayer film for laminated glass according to claim 1, an absolute value of a difference between an excitation purity at a point positioned at a distance of 0.1X from the one end being thin in thickness of the interlayer film toward the other end of the interlayer film and the excitation purity at a point positioned at a distance of 0.1X from the other end being thick in thickness of the interlayer film toward the one end of the interlayer film is more than zero and 0.7 or less.

13. The interlayer film for laminated glass according to claim 1, further comprising a flame retardant, an antistatic agent, and, a fluorescent brightening agent.

14. The laminated glass according to claim 6, wherein each of the first laminated glass member and the second laminated glass member are net-reinforced plate glass or wired plate glass.