System and process for carbon dioxide removal of air of passenger cabins of vehicles

• US 10,646,815 B2
• Filed: 09/03/2015
• Issued: 05/12/2020
• Est. Priority Date: 09/12/2014
• Status: Active Grant

• Current Assignee: Johnson Matthey PLC
• Original Assignee: Johnson Matthey PLC
• Inventors: Luisman, Luke Alan, Amieiro-Fonseca, Alvaro, Van Lishout, Yolanda, Reed, Graham
• Primary Examiner(s): Jones, Christopher P
• Application Number:
  US15/510,780
• Publication Number:
  US 20170239609A1
• Time in Patent Office: 1,713 Days
• CPC Class Codes: B01D 2253/106 Silica or silicates
• CPC Class Codes: B01D 2253/108 Zeolites
• CPC Class Codes: B01D 2253/11 Clays
• CPC Class Codes: B01D 2253/202 Polymeric adsorbents
• CPC Class Codes: B01D 2253/204 Metal organic frameworks (MOF's)
• CPC Class Codes: B01D 2253/25 Coated, impregnated or composite adsorbents
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 2257/708 Volatile organic compounds V.O.C.'s
• CPC Class Codes: B01D 2258/06 Polluted air
• CPC Class Codes: B01D 2259/40086 by using a purge gas B01D2259/4009 takes precedence
• CPC Class Codes: B01D 2259/4009 using hot gas
• CPC Class Codes: B01D 2259/401 using a single bed
• CPC Class Codes: B01D 2259/402 using two beds
• CPC Class Codes: B01D 2259/414 using different types of adsorbents
• CPC Class Codes: B01D 2259/4566 for use in transportation means
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0423 Beds in columns
• CPC Class Codes: B01J 20/103 comprising silica
• CPC Class Codes: B01J 20/22 comprising organic material
• CPC Class Codes: B01J 20/265 modified or post-treated polymers polymer carriers or substrates subjected to further impregnating or coating B01J20/3208
• CPC Class Codes: B01J 20/28042 : Shaped bodies; Monolithic structures
• CPC Class Codes: B01J 20/3242 : Layers with a functional group, e.g. an affinity material, a ligand, a reactant or a complexing group
• CPC Class Codes: B01J 20/3244 : Non-macromolecular compounds
• CPC Class Codes: B01J 20/3425 : of sorbents or filter aids comprising organic materials
• CPC Class Codes: B01J 20/3483 : by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
• CPC Class Codes: B60H 2003/0691 : Adsorption filters, e.g. activated carbon
• CPC Class Codes: B60H 3/06 : Filtering B60H3/0078 takes precedence
• CPC Class Codes: B60H 3/0633 : with provisions for regenerating or cleaning the filter element
• CPC Class Codes: Y02C 20/40 : of CO2

Abstract

The present invention relates to systems and methods for controlling the atmosphere in the cabin (1) of a vehicle. The system comprises a carbon dioxide removal conduit (2) comprising a regenerable carbon dioxide removal chamber (5,6) containing a carbon dioxide sorbent material and a regeneration circuit (7) arranged to expel the desorbed carbon dioxide at a location exterior (8) of the cabin (1) The system is operable to maintain a carbon dioxide level below 1000 ppm in the passenger cabin for a period of at least 5 minutes while restricting the flow of air from outside the vehicle into the passenger cabin to 10 L/s or less.

Claims

1. A system for controlling the atmosphere in a passenger cabin of a vehicle, the system comprising;

a carbon dioxide removal assembly, comprising

a bed of regenerable carbon dioxide sorbent material, wherein the bed comprises a monolith having the sorbent material coated thereon, or the sorbent material in the form of pellets or beads;

a carbon dioxide removal conduit arranged to flow air from the interior of the passenger cabin over the regenerable carbon dioxide sorbent material and return the treated air to the passenger cabin; and

a regeneration conduit arranged to flow desorption gas over the regenerable carbon dioxide sorbent material to desorb carbon dioxide from the sorbent material and expel the desorbed carbon dioxide at a location exterior to the cabin;

whereby the system is operable to maintain a carbon dioxide level below 1500 ppm in the passenger cabin for a period of at least 5 minutes while restricting the flow of air from outside the vehicle into the passenger cabin to 10 L/s or less, and

wherein the sorbent material comprises benzylamine functional groups immobilized on a polystyrene solid support; and

wherein the system is configured to adsorb carbon dioxide onto the sorbent at a temperature of from −

10°

C. to 50°

C., and configured to heat the sorbent to a temperature of from 50°

C. to 80°

C. to desorb carbon dioxide.

2. A system according to claim 1, further comprising a contaminant removal assembly.

3. A system according to claim 2 wherein the contaminant removal assembly comprises one or more contaminant removal materials and is operable to flow air over and/or through the contaminant removal material(s) to remove contaminants and supply the treated air to the interior of the passenger cabin.

4. A system according to claim 1 wherein the carbon dioxide sorbent material has a carbon dioxide capacity in the range from 1 to 10 wt %.

5. A system according to claim 1 which comprises two or more beds of carbon dioxide sorbent material and wherein the system is configured to switch the beds between a carbon dioxide sorption mode and a regeneration mode at predetermined time intervals.

6. A system according to claim 1, wherein the system is configured to operate in a sorption mode and a regeneration mode and the cycle time is in the range from 5 minutes to 25 minutes, where the cycle time is defined as the length of time the bed of sorbent material is operated in the sorption mode before being regenerated.

7. A system according to claim 6 wherein between 5 g and 30 g of sorption material is provided per minute of cycle time.

8. A system according to claim 1 wherein the energy required to regenerate the bed of sorbent material is less than 1 kW.

9. A system according to claim 1 wherein the flow of air from the passenger cabin over the sorbent material is in the range from 8 L/s to 20 L/s.

10. A system according to claim 1 wherein the system is configured to provide at least 1 g of carbon dioxide removal per minute.

12. A vehicle comprising a passenger cabin and a system for controlling the atmosphere in the passenger cabin, wherein the system is as defined in claim 1.

13. A system according to claim 1 wherein the benzylamine functional group is a primary benzylamine functional group.

11. A process for controlling the atmosphere in a passenger cabin of a vehicle, the process comprising:

(i) at a temperature of from −

10°

C. to 50°

C., flowing a portion of the air from within the passenger cabin over a bed of regenerable carbon dioxide sorbent material to remove carbon dioxide by adsorbing the carbon dioxide onto the sorbent material, and returning the treated air to the passenger cabin,

wherein the bed of regenerable carbon dioxide sorbent material comprises a monolith having the sorbent material coated thereon, or the sorbent material in the form of pellets or beads; and

(ii) regenerating the regenerable carbon dioxide sorbent material by heating the sorbent material to a temperature of from 50°

C. to 80°

C. to desorb carbon dioxide, flowing desorption gas over the regenerable carbon dioxide sorbent material to desorb carbon dioxide from the sorbent material, and expelling the desorbed carbon dioxide at a location exterior to the passenger cabin,

wherein steps (i) and (ii) are repeated to maintain the carbon dioxide level below 1500 ppm in the passenger cabin for a period of at least 5 minutes while restricting the flow of air from outside the vehicle into the passenger cabin to 10 L/s or less, and

wherein the sorbent material comprises benzylamine functional groups immobilized on a polystyrene solid support.

14. A process according to claim 11 wherein the sorbent material comprises a moiety comprising a primary benzylamine functional group.

15. A process according to claim 14 wherein the sorbent material is regenerated at a temperature of less than 80°

C.