Methods for the manufacture of colorfast masonry

• US 10,717,674 B2
• Filed: 03/10/2017
• Issued: 07/21/2020
• Est. Priority Date: 04/27/2010
• Status: Active Grant

• Current Assignee: bioMASON, Inc.
• Original Assignee: bioMASON, Inc.
• Inventors: Hill, Thomas A., McAllister, Steven W., Dosier, J. Michael, Dosier, Ginger K.
• Primary Examiner(s): Raghu, Ganapathirama
• Application Number:
  US15/455,689
• Publication Number:
  US 20170190617A1
• Time in Patent Office: 1,229 Days
• CPC Class Codes: B05D 1/02 performed by spraying
• CPC Class Codes: C04B 12/00 Cements not provided for in groups C04B7/00 - C04B11/00
• CPC Class Codes: C04B 14/04 Silica-rich materials; Silicates
• CPC Class Codes: C04B 14/06 Quartz; Sand
• CPC Class Codes: C04B 14/22 Glass ; Devitrified glass
• CPC Class Codes: C04B 14/34 Metals , e.g. ferro-silicon
• CPC Class Codes: C04B 18/12 from quarries, mining or the like
• CPC Class Codes: C04B 18/16 from building or ceramic industry
• CPC Class Codes: C04B 18/20 from macromolecular compounds
• CPC Class Codes: C04B 18/24 Vegetable refuse, e.g. rice husks, maize-ear refuse; Cellulosic materials, e.g. paper , cork
• CPC Class Codes: C04B 18/241 Paper, e.g. waste paper; Paper pulp
• CPC Class Codes: C04B 18/26 Wood, e.g. sawdust, wood shavings
• CPC Class Codes: C04B 20/1092 with pigments or dyes C04B20/1059 takes precedence
• CPC Class Codes: C04B 2103/0001 Living organisms, e.g. microorganisms, or enzymes
• CPC Class Codes: C04B 2103/0075 Anti-dusting agents
• CPC Class Codes: C04B 2111/00146 Sprayable or pumpable mixtures
• CPC Class Codes: C04B 2111/60 Flooring materials
• CPC Class Codes: C04B 28/10 Lime cements or magnesium oxide cements
• CPC Class Codes: C04B 38/10 by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam
• CPC Class Codes: C12N 1/20 Bacteria; Culture media therefor
• CPC Class Codes: C12N 11/02 : Enzymes or microbial cells immobilised on or in an organic carrier
• CPC Class Codes: C12N 11/14 : Enzymes or microbial cells immobilised on or in an inorganic carrier
• CPC Class Codes: C12P 3/00 : Preparation of elements or inorganic compounds except carbon dioxide recovery of carbon dioxides as by-products C12F3/02
• CPC Class Codes: C12Y 305/01005 : Urease (3.5.1.5)
• CPC Class Codes: Y02W 30/91 : Use of waste materials as fillers for mortars or concrete

Abstract

The invention is directed to compositions and methods for the manufacture of pigmented solids structures for which can be used for construction and/or decoration. Manufacturing comprises fixing one or more pigments to an aggregate material such as crushed rock, stone or sand. The pigmented aggregate is incubated with urease or urease producing microorganisms, an amount of a nitrogen source such as urea, and an amount of calcium source such as calcium chloride forming calcite bridges between particles of aggregate. The resulting solid has a hardness and colorfastness for most any construction material. Using selected aggregate and pigment, the process also provides for the manufacture of simulated-stone materials such as clay or granite bricks or blocks, marble counter-tops, and more. The invention is also directed to composition containing microorganisms and pigment as kits that can be added to most any aggregate materials.

Claims

1. A method for manufacture of pigmented masonry comprising:

combining a pigment with particles of an aggregate material to form a mixture, wherein the mixture contains 5% or less of water by weight;

agitating the mixture to disburse the pigment over surfaces of the particles;

adding 1% or less of water by weight and continuing agitating the mixture;

combining the pigment and the particles with urease enzyme or urease-producing cells or spores, nutrients, a calcium source and a nitrogen source to form a composition;

incubating the composition at ambient temperature for a period of time to form calcium carbonate, whereby the calcium carbonate affixes the pigment to the particles of aggregate material; and

forming the pigmented masonry.

2. The method of claim 1, wherein the pigment comprises a natural pigment, a synthetic pigment, an organic pigment, an inorganic pigment, a mineral pigment, a metal-based pigment, an iron-based pigment, a carbon-based pigment, a fluorescent pigment, a phosphorescent pigment, a luminescent pigment, or a combination thereof.

3. The method of claim 1, wherein the pigment comprises a solid, a liquid, a paste or a gel.

4. The method of claim 1, wherein the particles comprise natural or manufactured materials, sand, ore, crushed rock or stone, minerals, crushed or fractured glass, mine tailings, paper, waste materials, waste from a manufacturing process, plastics, polymers, roughened materials, recycled materials, and/or combinations thereof.

5. The method of claim 1, wherein the particles have average diameters of less than 1.0 mm and a hydration of less than 2% by weight.

6. The method of claim 1, wherein the particles have average diameter of less than 0.5 mm and a hydration of less than 1% by weight.

7. The method of claim 1, wherein agitating comprises stirring or rotating the mixture.

8. The method of claim 1, wherein 0.5% of water is added to the mixture of particles and pigment and agitation is continued.

9. The method of claim 1, wherein the urease-producing cells or spores are derived from Sporosarcina pasteurii, Sporosarcina ureae, Proteus vulgaris, Bacillus sphaericus, Myxococcus xanthus, Proteus mirabilis, Helicobacter pylori and combinations thereof.

10. The method of claim 1, wherein the nutrients promote proliferation of the urease-producing cells or spores and/or stimulate conversion of spores to a vegetative state.

11. The method of claim 1, wherein the nutrients comprise one or more of amino acids, proteins, peptides, carbohydrates, saccharides, polysaccharides, fatty acids, vitamins and minerals.

12. The method of claim 1, wherein the calcium source comprises calcium chloride, calcium acetate, calcium phosphate, calcium carbonate, calcium lactate, calcium nitrate, or a calcium salt.

13. The method of claim 1, wherein the nitrogen source comprises urea.

14. A method of manufacture of simulated-stone masonry comprising:

combining a pigment with particles of an aggregate material to form a mixture wherein the mixture contains 5% or less of water by weight;

agitating the mixture to disburse the pigment over surfaces of the particles;

adding 1% of water to the mixture and continue agitating the mixture;

combining the pigmented particles with urease enzyme or urease-producing cells or spores, nutrients, a calcium source and a nitrogen source to form a composition;

adding one or more additional pigments to the surface of the composition;

incubating the composition for a period of time to form calcium carbonate;

forming the simulated-stone masonry.

15. The method of claim 14, wherein the simulated-stone masonry simulates clay, slate, concrete, granite, or marble.

16. The method of claim 14, wherein the simulated-stone masonry is one or more bricks, thin bricks, pavers, panels, tiles, a veneer, cinder, breeze, besser, clinker or aerated blocks, counter- or table-tops, or designer structures.

17. The method of claim 14, wherein the pigmented simulated-stone masonry comprises an identification tag.

18. A method of manufacturing a pigmented masonry comprising:

mixing a combination of at least one pigment and particles of at least one aggregate material with urease and/or urease-producing cells or spores, water, nutrients, a calcium source and a nitrogen source;

depositing or extruding the mixture into a form; and

incubating the mixture for a period of time to allow the formation of covalent bonds between the particles, wherein the covalent bonds affix the at least one pigment to surfaces of the particles; and

forming the pigmented masonry.

19. The method of claim 18, further comprising roughening the particles prior to forming the mixture.

20. The method of claim 18, wherein the calcium source comprises calcium chloride, calcium acetate, calcium phosphate, calcium carbonate, calcium lactate, calcium nitrate, or a calcium salt.

21. The method of claim 18, wherein the nitrogen source comprises urea.

22. The method of claim 18, wherein the at least one pigment comprises multiple different pigments.

23. The method of claim 18, wherein the particles of at least one aggregate material comprises particles of multiple different aggregate materials.

24. The method of claim 18, wherein the at least one pigment comprises fluorescent, phosphorescent, or luminescent pigment.

25. The method of claim 18, wherein the pigmented masonry comprises blocks, boards, bricks, pavers, panels, tiles, counter tops, or veneer.