High-strength and high-conductivity copper alloy and applications of alloy as material of contact line of high-speed railway allowing speed higher than 400 kilometers per hour

• US 10,801,087 B2
• Filed: 05/15/2017
• Issued: 10/13/2020
• Est. Priority Date: 05/16/2016
• Status: Active Grant

• Current Assignee: Zhejiang University
• Original Assignee: Zhejiang University
• Inventors: Liu, Jiabin, Xu, Yuqing, Wang, Hongtao, Fang, Youtong, Meng, Liang, Wang, Litian, Tian, Yu
• Primary Examiner(s): Wu, Jenny R
• Application Number:
  US16/061,027
• Publication Number:
  US 20180363101A1
• Time in Patent Office: 1,247 Days
• CPC Class Codes: B60M 1/30 Power rails
• CPC Class Codes: C22C 1/03 using master alloys
• CPC Class Codes: C22C 9/00 Alloys based on copper
• CPC Class Codes: C22F 1/08 of copper or alloys based thereon

Abstract

The present invention discloses a super-strong high-conductivity copper alloy and applications thereof as the contact wire materials of high speed railways allowing a speed of over 400 km per hour. The copper alloy comprises niobium, chromium, zirconium, titanium and remaining copper; the copper alloy exists in the form of long bar or wire, wherein niobium is distributed in the copper matrix in the form of nanofibers and solid solution atoms, chromium is distributed around the niobium fibers and the copper matrix in the form of nano-particles and solid solution atoms, zirconium is distributed around the niobium fibers and in the copper matrix in the form of copper-zirconium compound nano-particles and solid solution atoms; titanium is distributed in the copper matrix in the form of copper-titanium GP zone and solid solution atoms; the total amount of niobium, chromium and zirconium solid solution atoms contained in the copper alloy is less than 0.2%.

Claims

1. A copper alloy, comprising 3 wt %-20 wt % niobium, 0.01 wt %-0.1 wt chromium, 0.01 wt %-0.5 wt % zirconium, 0.01 wt %-0.2 wt % titanium and remaining copper;

the copper alloy exists in the form of a bar or a wire, wherein niobium is distributed in the copper matrix in the form of nanofibers and solid solution atoms, and most of niobium nanofibers are arranged approximately in parallel in the copper matrix, these fibers are approximately parallel to copper alloy rods or wires in the axial direction;

chromium is distributed around the niobium fibers and the copper matrix in the form of nano-particles and solid solution atoms, zirconium is distributed around the niobium fibers and in the copper matrix in the form of copper-zirconium compound nanoparticles and solid solution atoms;

titanium is distributed in the copper matrix in the form of copper-titanium GP zone and solid solution atoms;

the total amount of niobium, chromium and zirconium solid solution atoms contained in the copper alloy is less than 0.2%;

part of chromium and copper zirconium compound nanoparticle are pinned on the phase interface of niobium nanofibers and copper matrix.

2. The copper alloy according to claim 1, wherein the strength of the copper alloy reaches over 800 MPa, its conductivity reaches over 78% IACS and the strength reduction rate<

10% after annealing at 400°

C. for 2 h.

3. The copper alloy according to claim 1, wherein the copper alloy is prepared according to the following steps:

(1) Melting raw materials of simple substance and/or master alloy in a vacuum induction melting furnace and rapidly casting in a water-cooled copper mold with a cooling rate greater than 20°

C./s;

(2) Carrying out multi-pass drawing of an ingot obtained in the step (1) at room temperature, with a single-time drawing deformation less than 0.3 and ultimately achieving a drawing deformation greater than 3.5;

(3) Annealing a drawn copper alloy rod or wire at 375-575°

C. for 1-100 h;

(4) Carrying out drawing of the annealed copper alloy again at room temperature, with a single-time drawing deformation at 0.1-0.2 and drawing deformation at 0.5-1.0;

(5) Placing the above copper alloy in liquid nitrogen freezing for 12-72 h, then slowly warming to room temperature, with a heating rate less than 10°

C./min, to get the copper alloy.

4. The copper alloy according to claim 3, wherein the master alloy in step (1) is one or more from Cu-(10 wt %˜

25 wt %)Nb master alloy, Cu-(5 wt %˜

13 wt %)Cr master alloy, Cu-(5 wt %˜

7 wt %)Zr master alloy, Cu-(3 wt %˜

10 wt %)Ti master alloy.

5. The copper alloy according to claim 3, wherein the cooling rate is 30-100°

C./s in the step (1).

6. The copper alloy according to claim 3, wherein the single-time drawing deformation is 0.1-0.2, and ultimately a drawing amount of 4 to 6 in step (2).

7. The copper alloy according to claim 3, wherein the annealing is performed at a temperature of 400 to 500°

C. for 4 to 64 h in step (3).

8. The copper alloy according to claim 3, wherein the preparation method comprises steps (1) to (5).

9. Applications of the copper alloy according to claim 1 as contact wire materials of high speed railways.

10. The applications according to claim 9, wherein the speed of the high speed railways is over 400 km per hour.

11. The copper alloy according to claim 2, wherein the copper alloy is prepared according to the following steps:

(1) Melting the raw materials of simple substance and/or master alloy in a vacuum induction melting furnace and rapidly casting in a water-cooled copper mold with a cooling rate greater than 20°

C./s;

(2) Carrying out multi-pass drawing of an ingot obtained in the step (1) at room temperature, with a single-time drawing deformation less than 0.3 and ultimately achieving a drawing deformation greater than 3.5;

(3) Annealing a drawn copper alloy rod or wire at 375-575°

C. for 1-100 h;

(4) Carrying out drawing of the annealed copper alloy again at room temperature, with a single-time drawing deformation at 0.1-0.2 and drawing deformation at 0.5-1.0;

(5) Placing the above copper alloy in liquid nitrogen freezing for 12-72 h, then slowly warming to room temperature, with a heating rate less than 10°

C./min, to get the copper alloy.

12. The copper alloy according to claim 11, wherein the master alloy in step (1) is one or more from Cu-(10 wt %˜

25 wt %)Nb master alloy, Cu-(5 wt %˜

13 wt %)Cr master alloy, Cu-(5 wt %˜

7 wt %)Zr master alloy, Cu-(wt 3%˜

10 wt %)Ti master alloy.

13. The copper alloy according to claim 11, wherein the cooling rate is 30-100°

C./s in the step (1).

14. The copper alloy according to claim 11, wherein the single-time drawing deformation is 0.1-0.2, and ultimately a drawing amount of 4 to 6 in step (2).

15. The copper alloy according to claim 11, wherein the annealing is performed at a temperature of 400 to 500°

C., for 4 to 64 h in step (3).

16. The copper alloy according to claim 11, wherein the preparation method comprises steps (1) to (5).