Thermoelectric device and methods for manufacture and use

• US 10,825,976 B2
• Filed: 08/12/2015
• Issued: 11/03/2020
• Est. Priority Date: 08/12/2014
• Status: Active Grant

• Current Assignee: The Board of Trustees of Michigan State University (Michigan State University)
• Original Assignee: The Board of Trustees of Michigan State University (Michigan State University)
• Inventors: Timm, Edward J., Schock, Harold J., Zhu, Guoming G., Ruckle, Trevor, Moran, Kevin D.
• Primary Examiner(s): Gonzalez Ramos, Mayla
• Application Number:
  US15/328,145
• Publication Number:
  US 20170222114A1
• Time in Patent Office: 1,910 Days
• CPC Class Codes: H10N 10/17 characterised by the structure or configuration of the cell or thermocouple forming the device
• CPC Class Codes: H10N 10/82 Connection of interconnections
• CPC Class Codes: H10N 10/854 comprising only metals H10N10/852, H10N10/853 take precedence

Abstract

A thermoelectric device (20) and a method for manufacturing and using the same are disclosed. The thermoelectric device (20) includes a hot shoe (24) and a cold shoe (28) disposed about the hot shoe. A heat conducting member (32) formed of a thermoelectric material extends between the hot shoe (24) and the cold shoe (28) and generates electricity in response to a temperature difference therebetween. The hot shoe (24) is heated and expands at a greater rate than the cold shoe (28) does during operation. The structural and spatial relationship of the hot shoe (24) and the cold shoe (28) maintains the thermoelectric material of the heat conducting member (32) in compression during operation of the thermoelectric device (20).

Claims

1. A thermoelectric coupling comprising:

a hot shoe;

a cold shoe extending about said hot shoe;

a plurality of heat conducting members located between said shoes, said members each contain a thermoelectric material and extend outwardly from said hot shoe to said cold shoe such that said plurality of heat conducting members are compressed between said hot shoe and said cold shoe in response to greater thermal expansion of said hot shoe relative to said cold shoe during operation of said thermoelectric coupling;

wherein said cold shoe includes a first portion and a second portion, each having a cylindrical shape, said first portion and said second portion of said cold shoe being aligned with one another and axially spaced to define an annular slot between said first portion of said cold shoe and said second portion of said cold shoe, and peripheries of said first and second portions of said cold shoe having a common diameter with said annular slot being axially located between and axially separating said first and second portions of said cold shoe, said annular slot being on a plane intersecting a centerline axis of said hot shoe; and

a first set of said heat conducting members being radially aligned with said first portion of said cold shoe, and a second set of said heat conducting members being radially aligned with said second portion of said cold shoe, and said annular slot also being axially located between and axially separating said first and second sets of said heat conducting members.

2. A thermoelectric coupling as set forth in claim 1 wherein said heat conducting members comprises at least one positive leg extending radially between said hot shoe and said second portion of said cold shoe, and said heat conducting members comprises at least one negative leg extending radially between said hot shoe and said first portion of said cold shoe, said legs being circumferentially spaced apart from each other.

3. A thermoelectric coupling as set forth in claim 1 further comprising:

an insulating member having a disc shape extending radially between said hot shoe and said cold shoe that is positioned axially between said first portion of said cold shoe and said second portion of said cold shoe such that said insulating member is disposed within said annular slot; and

said insulating member also being positioned axially between said first set of said heat conducting members and said second set of said heat conducting members.

4. A thermoelectric coupling as set forth in claim 3 wherein:

said heat conducting members include positive legs and negative legs being disposed on opposite sides of said insulating member;

said heat conducting members comprise skutterudite; and

said insulating member comprises Mica.

5. A thermoelectric coupling as set forth in claim 1 wherein said at least one of said heat conducting members has a rectangular cross-section and has a pair of ends faced with a copper foil, a pair of outer layers disposed at said pair of ends directly adjacent said copper foil that contain titanium, a pair of intermediate layers directly adjacent and inward of said pair of outer layers that contain cobalt, and a middle layer disposed between said pair of intermediate layers that contains skutterudite.

6. A thermoelectric coupling as set forth in claim 1 wherein said heat conducting members each have ends faced with a copper foil, a pair of outer layers disposed at said pair of ends directly adjacent said copper foil that contain titanium, and a middle layer disposed between said pair of outer layers that contains skutterudite.

7. A thermoelectric coupling as set forth in claim 1 wherein said first set of said heat conducting members are circumferentially spaced from one another within a cavity defined between said hot shoe and said cold shoe, and said first set of said heat conducting members are all located on a plane which intersect said centerline axis of said hot shoe.

8. A thermoelectric coupling as set forth in claim 3 wherein:

said hot shoe and said cold shoe are co-axially aligned about said centerline axis; and

said hot shoe continuously axially extends under said first and second sets of heat conducting members, under said first and second portions of said cold shoe and under said insulating member.

9. A thermoelectric coupling as set forth in claim 1 wherein said hot shoe presents an outer surface facing said cold shoe that includes a plurality of mating surfaces that are circumferentially spaced from one another and that have a flat shape to receive said plurality of heat conducting members in an abutting relationship.

10. A thermoelectric coupling as set forth in claim 1 wherein said hot shoe has a cylindrical shape and contains titanium and said cold shoe has a cylindrical shape and contains brass.

11. A thermoelectric coupling as set forth in claim 1 wherein multiple ones of said thermoelectric coupling are arranged adjacent to one another in an abutting end-to-end arrangement to form a thermoelectric module.

12. A thermoelectric coupling comprising:

a heat receiving structure disposed adjacent a heat source;

a heat sink comprising radially projecting fins;

a heat dissipating structure coupled to said heat sink;

at least one heat conducting member extending radially between said heat receiving structure and said heat dissipating structure that thermally couples said heat receiving structure and heat dissipating structure, said at least one heat conducting member being a semi-conductor;

said heat dissipating structure extending annularly about said heat receiving structure forming an annular cavity between said heat receiving structure and said heat dissipating structure wherein said at least one heat conducting member is disposed within said annular cavity and is radially compressed between said heat receiving structure and said heat dissipating structure in response to greater thermal expansion of said heat receiving structure relative to said heat dissipating structure;

at least one compression member located circumferentially about said heat dissipating structure that applies additional radial compression to said at least one heat conducting member by compressing said heat dissipating structure radially inwardly toward said heat receiving structure;

a slot being located between and axially separating portions of said heat dissipating structure; and

an internal combustion engine-exhaust pipe located within and contacting said heat receiving structure.

13. A thermoelectric coupling as set forth in claim 12 wherein:

said at least one heat conducting member generates electricity in response to temperature differences between said heat receiving structure and said heat dissipating structure;

said portions of said heat dissipating structure are each cylindrical and coaxial with said at least one heat receiving structure; and

said heat receiving structure is cylindrical and continuously axially extends under multiples of said at least one heat conducting member, under said portions of said heat dissipating structure.

14. A thermoelectric coupling as set forth in claim 12 wherein said at least one heat conducting member comprises at least one positive leg extends radially between said hot shoe and said second portion of said cold shoe, said at least one heat conducting member comprises at least one negative leg extends radially between said hot shoe and said first portion of said cold shoe, and at least some of said legs being axially spaced apart from each other and separated by said slot.

15. A thermoelectric coupling as set forth in claim 12 further comprising:

an insulating member having a disc shape extending radially between said heat receiving structure and said heat dissipating structure, and said insulating member being positioned axially between said portions of said heat dissipating structure such that said insulating member is disposed within said slot which is an annular slot defining a plane perpendicular to a centerline of said heat receiving structure.

16. A thermoelectric coupling as set forth in claim 12 wherein said at least one heat conducting member is a plurality of heat conducting members which are circumferentially spaced from one another within said cavity defined between said structures.

17. A thermoelectric coupling as set forth in claim 12 wherein:

said structures are co-axially aligned about a centerline;

said at least one compression member comprises metallic foil;

said heat dissipating structure comprises brass; and

said at least one heat conducting member is a plurality of heat conducting members which each comprise cobalt and antimony.

18. A thermoelectric coupling as set forth in claim 12 wherein:

said at least one heat conducting member at least partially comprises skutterudite; and

said structures are at least partially comprised of titanium.

19. A thermoelectric coupling as set forth in claim 12 further comprising:

an insulator within said slot comprises Mica; and

said at least one heat conducting member comprises skutterudite.

20. A thermoelectric apparatus comprising multiple thermoelectric generators in contact with a heat source, each of said thermoelectric generators comprising:

(a) a hot shoe disposed adjacent said heat source, said hot shoe comprising Titanium;

(b) a cold shoe disposed adjacent a heat sink, said cold shoe comprising Titanium or Brass;

(c) at least one semi-conductor extending between said hot shoe and said cold shoe that thermally couples said hot shoe and cold shoe, and that generates electricity in response to a temperature difference between said hot shoe and said cold shoe;

(d) at least one metallic compression member located about an outer diameter of said cold shoe that applies compression to said at least one semi-conductor by compressing said cold shoe inwardly toward said hot shoe;

(e) said cold shoe being located about said hot shoe such that expansion of said hot shoe during heating exceeds expansion of said cold shoe and compresses said at least one semi-conductor between said hot shoe and said cold shoe during operation of said thermoelectric device;

(f) said at least one semi-conductor at least partially comprising skutterudite;

(g) said hot shoe and said cold shoe being cylindrical and coaxial, and one of said shoes having a greater axial dimension than the other of said shoes for each of said thermoelectric generators; and

(h) an electrical circuit wired in series with said multiple thermoelectric generators.

21. An apparatus as set forth in claim 20 wherein said hot shoe has a cylindrical shape with a central bore therein and said cold shoe has a cylindrical shape that is located annularly about and co-axially with said hot shoe to define an annular cavity between said hot shoe and said cold shoe within which is located said at least one semi-conductor.

22. An apparatus as set forth in claim 20 further comprising:

an insulator being on a plane intersecting a centerline axis of said hot shoe; and

said cold shoe including a first portion and a second portion which are axially spaced from each other, peripheries of said first and second portions of said cold shoe having a common diameter, and said insulator being axially located between and axially separating said first and second portions of said cold shoe.

23. An apparatus as set forth in claim 22 wherein a first set of said at least one semi-conductor is radially aligned with said first portion of said cold shoe, and a second set of said at least one semi-conductor is radially aligned with said second portion of said cold shoe, with said insulator also being axially located between and axially separating said first and second sets of said semi-conductors.

24. An apparatus as set forth in claim 20 wherein said at least one semi-conductor includes a positive leg and a negative leg spaced apart from each other with a gap therebetween.

25. An apparatus as set forth in claim 20 further comprising a disc shaped insulating member disposed adjacent said at least one semi-conductor that extends between said hot shoe and said cold shoe.

26. An apparatus as set forth in claim 20 wherein said at least one compression member at least partially comprises a metallic foil.

27. An apparatus as set forth in claim 20 further comprising a slot, which is annular, being located between and axially spacing apart peripheral cylindrical surfaces of said cold shoe.

28. A thermoelectric apparatus as set forth in claim 20 further comprising an exhaust pipe of an internal combustion engine located within and contacting said hot shoe.