Composite containing carbon nanostructure, high molecular material using same and preparation method

• US 10,836,640 B2
• Filed: 09/22/2016
• Issued: 11/17/2020
• Est. Priority Date: 10/15/2015
• Status: Active Grant

• Current Assignee: Jinan Shengquan Group Share-Holding Company Limited
• Original Assignee: Jinan Shengquan Group Holding Company Limited
• Inventors: Tang, Yilin, Zhang, Jinzhu, Zheng, Yingfu, Liu, Xiaomin, Liu, Ding
• Primary Examiner(s): Grinsted, Ronald
• Application Number:
  US15/521,534
• Publication Number:
  US 20180273387A1
• Time in Patent Office: 1,517 Days
• Field of Search: 428323
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C01B 32/182 Graphene
• CPC Class Codes: C08K 2003/0812 Aluminium
• CPC Class Codes: C08K 2003/0856 Iron
• CPC Class Codes: C08K 3/04 Carbon
• CPC Class Codes: C08K 3/08 Metals

Abstract

The present invention relates to a composite having a carbon nanostructure, comprising graphene, amorphous carbon and a non-carbon non-oxygen element, wherein the non-carbon non-oxygen element is in an amount of 0.5 wt %-6 wt % of the composite. The present invention discloses controlling the content of the non-carbon non-oxygen element in the composite to obtain excellent far-infrared effect and antibacterial and bacteriostatic effects, wherein the normal emissivity in the far-infrared performance reaches 0.85 or more, and the antibacterial rate reaches 95% or more. The composite having a carbon nanostructure of the present invention is applied to macromolecular materials to modify macromolecular materials under the circumstance that the addition amount is relatively low. The composite having a carbon nanostructure can achieve notable far-infrared performance and antibacterial and bactericidal performances without any pre-modification and activation treatment.

Claims

1. A composite having a carbon nanostructure, the composite comprising:

graphene;

amorphous carbon; and

a non-carbon non-oxygen element comprising elements of Fe, Si, and Al,

wherein the non-carbon non-oxygen element is present in an amount of 0.5 wt %-6 wt % of the composite;

wherein the non-carbon non-oxygen element further comprises P, Ca, and Na;

wherein the non-carbon non-oxygen elements P, Si, Ca, Al and Na in the composite having a carbon nanostructure are introduced through carbon sources.

2. The composite according to claim 1, wherein a G peak and a D peak of carbon element of the composite in a Raman spectrum has a peak height ratio of 1-20.

3. The composite according to claim 1, wherein the composite further has a 2D peak in a Raman spectrum.

4. The composite according to claim 1, wherein the non-carbon non-oxygen elements P, Si, Ca, Al and Na in the composite having a carbon nanostructure are introduced through biomass carbon sources.

5. The composite according to claim 1, wherein the non-carbon non-oxygen element further comprises any one element selected from the group consisting of Ni, Mn, K, Mg, Cr, S, and Co, or a combination of at least two selected therefrom.

6. The composite according to claim 1, wherein the non-carbon non-oxygen element exists in a form of simple substance and/or compound.

7. The composite according to claim 1, wherein the non-carbon non-oxygen element is adsorbed on the surface of or inside the carbon nanostructure in any one or more form selected from the group consisting of simple substance, oxides and carbides.

8. The composite according to claim 1, wherein the composite contains carbon element in an amount of 80 wt % or more.

9. The composite according to claim 1, wherein the composite contains P, Si, Ca, Al, and Na in an amount of 0.5 wt %-4 wt %.

10. The composite according to claim 1, wherein the composite has a far-infrared detection normal emissivity of greater than 0.88.

11. The composite according to claim 1, wherein the graphene has a carbon six-membered ring honeycomb lamellar structure having a thickness of 100 nm or less.

12. The composite according to claim 11, wherein the carbon six-membered ring honeycomb lamellar structure in the composite microscopically shows any one conformation selected from the group consisting of warping, curling and folding, or a combination of at least two selected therefrom.

13. A macromolecular material comprising the composite of claim 1.

14. A process for preparing a composite having a carbon nanostructure of claim 1, the process comprising:

(1) catalyzing a biomass carbon source under the action of a catalyst to obtain a precursor;

(2) maintaining the temperature of the precursor at 140°

C.-180°

C. for 1.5 h-2.5 h under the condition of protective gas to obtain a first intermediate;

(3) heating the first intermediate to 350°

C.-450°

C. under the condition of protective gas and maintaining the temperature for 3 h-4 h to obtain a second intermediate;

(4) heating the second intermediate to 1100°

C.-1300°

C. under the condition of protective gas and maintaining the temperature for 2 h-4 h to obtain a third intermediate; and

(5) alkali washing, acid washing and water washing the third intermediate in sequence to obtain a composite;

wherein the temperatures in steps (3) and (4) are increased at a rate of 14°

C./min-18°

C./min;

wherein the composite having the carbon nanostructure comprises;

graphene;

amorphous carbon; and

a non-carbon non-oxygen element comprising elements of Fe, Si, and Al,

wherein the non-carbon non-oxygen element is present in an amount of 0.5 wt %-6wt % of the composite;

wherein the non-carbon non-oxygen element further comprises P, Ca, and Na;

wherein the non-carbon non-oxygen element P, Si, Ca, Al and Na in the composite having a carbon nanostructure are introduced through carbon sources.

15. A process for preparing a composite having a carbon nanostructure of the claim 1, the process comprising:

(1) mixing a biomass carbon source with a catalyst, stirring, catalyzing and drying to obtain a precursor;

(2) maintaining the temperature of the precursor at 280°

C.-350°

C. for 1.5 h-2.5 h under protective atmosphere, then heating by temperature programming to 950-1200°

C. at an increasing rate of 15-20°

C./min, maintaining the temperature for 3-4 h to obtain a crude product; and

(3) washing the crude product to obtain a composite having a carbon nanostructure

wherein the composite having the carbon nanostructure comprises;

graphene;

amorphous carbon; and

a non-carbon non-oxygen element comprising elements of Fe, Si, and Al,

wherein the non-carbon non-oxygen element is present in an amount of 0.5 wt %-6wt % of the composite;

wherein the non-carbon non-oxygen element further comprises P, Ca, and Na;

wherein the non-carbon non-oxygen elements P, Si, Ca, Al and Na in the composite having a carbon nanostructure are introduced though carbon sources.

16. A process for preparing a macromolecular material, comprising compounding the composite of claim 15 with a macromolecular raw material, without any activation or modification of the composite, wherein the macromolecular raw material is any one or more selected from the group consisting of rubber, plastic, fiber, coating, adhesive agent and polymer-based composite materials.