Devices with guest-host liquid crystal modulators

• US 10,845,665 B1
• Filed: 10/17/2016
• Issued: 11/24/2020
• Est. Priority Date: 02/01/2016
• Status: Active Grant

• Current Assignee: Apple Inc.
• Original Assignee: Apple Inc.
• Inventors: Bayat, Khadijeh, Chen, Cheng, Kamei, Ibuki, Chang, Shih-Wei, Yuen, Avery P., Ge, Zhibing
• Primary Examiner(s): Nguyen, Thanh Nhan P
• Application Number:
  US15/295,142
• Time in Patent Office: 1,499 Days
• Field of Search: 349 16
• CPC Class Codes: E06B 2009/2417 Light path control; means to control reflection
• CPC Class Codes: E06B 2009/2464 featuring transparency control by applying voltage, e.g. LCD, electrochromic panels
• CPC Class Codes: E06B 9/24 Screens or other constructions affording protection against light, especially against sunshine; Similar screens for privacy or appearance; Slat blindsoperating, guiding or securing devices or arrangements for roll-type closures E06B9/56; free-hanging flexible screens A47H23/00
• CPC Class Codes: G02F 1/13725 based on guest-host interaction G02F1/13762, G02F1/13737, take precedence

Abstract

A window may be provided with a light modulator. The light modulator may be dynamically adjusted to control visible light transmission through the window. The window may also have layers that selectively block light with non-visible wavelengths. The light-blocking layers may block ultraviolet light, near infrared light such as light from solar radiation, and far infrared light such as heat produced due to the absorption of visible light by the light modulator. The light modulator may be a guest-host liquid crystal light modulator. The guest-host liquid crystal light modulator may have a layer of liquid crystal material with dye that is interposed between polymer substrate layers. The polymer substrate layers may be thermoplastic layers that are moldable to conform to window shapes with compound curves.

Claims

1. A system, comprising:

structures that form an interior region that is separated from an exterior region; and

a window in the structures that is interposed between the interior region and the exterior region, wherein the window includes;

a guest-host liquid crystal light modulator; and

a layer configured to block infrared light emitted by the guest-host liquid crystal light modulator, wherein the layer that is configured to block the infrared light comprises;

a metal layer,

a metal oxide barrier layer that directly contacts the metal layer, and

a crystalline oxide seed layer that directly contacts the metal oxide barrier layer, wherein the metal oxide barrier layer is interposed between the crystalline oxide seed layer and the metal layer.

2. The system defined in claim 1 wherein the layer that is configured to block the infrared light comprises at least two metal layers.

3. The system defined in claim 1 wherein the metal layer comprises a silver layer.

4. The system defined in claim 3 wherein the crystalline oxide seed layer comprises zinc oxide.

5. The system defined in claim 1 wherein the window further comprises at least one glass layer and a polymer layer on the glass layer that is interposed between the layer that is configured to block the infrared light and the glass layer.

6. The system defined in claim 1 wherein the guest-host liquid crystal light modulator comprises dichroic dye.

7. The system defined in claim 6 wherein the dichroic dye comprises a mixture of azo dye and anthraquinone dye.

8. The system defined in claim 1 wherein the window further comprises first and second glass layers, wherein the guest-host liquid crystal modulator is interposed between the first and second glass layers.

9. The system defined in claim 8 further comprising an ultraviolet light blocking filter layer between the first glass layer and the guest-host liquid crystal modulator.

10. The system defined in claim 1 wherein the light emitted by the guest-host liquid crystal light modulator comprises light with wavelengths from 8 microns to 10 microns, wherein the layer that is configured to block infrared light emitted by the liquid crystal light modulator is configured to block the light with the wavelengths from 8 microns to 10 microns and is configured to block near-infrared light with wavelengths from 700 nm to 2.5 microns.

11. The system defined in claim 1 wherein the guest-host liquid crystal light modulator has pixelated transparent electrodes.

12. The system defined in claim 1 wherein the guest-host liquid crystal light modulator has first and second polymer substrates and wherein the first and second polymer substrates comprise thermoplastic material that is configured to be molded to form a shape with compound curves.

13. The system defined in claim 1 wherein the guest-host liquid crystal light modulator has a layer of liquid crystal molecules and dye molecules interposed between first and second transparent conductive electrodes and wherein the layer of liquid crystal molecules and dye molecules has a thickness that varies across the guest-host liquid crystal light modulator.

14. The system defined in claim 1, wherein the metal oxide barrier layer comprises titanium.

15. The system defined in claim 14, wherein the metal oxide barrier layer comprises titanium oxide, the metal layer comprises silver, and the crystalline oxide seed layer comprises zinc oxide.

16. A system, comprising:

structures that form an interior region that is separated from an exterior region; and

a window in the structures that is interposed between the interior region and the exterior region, wherein the window includes;

a guest-host liquid crystal light modulator; and

a layer configured to block infrared light emitted by the guest-host liquid crystal light modulator, wherein the guest-host liquid crystal light modulator has a layer of liquid crystal molecules and dye molecules interposed between first and second transparent conductive electrodes, wherein the guest-host liquid crystal light modulator has metal terminals that run along at least first and second edges of the transparent conductive electrodes, and wherein the metal terminals are configured to concurrently apply different voltages to the first and second edges that produce a voltage across the guest-host liquid crystal light modulator layer that varies linearly as a function of position along the first and second transparent conductive electrodes, the layer comprising;

a metal layer,

a metal oxide barrier layer that directly contacts the metal layer, and

a crystalline oxide seed layer that directly contacts the metal oxide barrier layer, wherein the metal oxide barrier layer is interposed between the crystalline oxide seed layer and the metal layer.

17. The system defined in claim 16, wherein the metal layer comprises silver, the metal oxide barrier layer comprises titanium oxide, and the crystalline oxide seed layer comprises zinc oxide.

18. A system, comprising:

structures that form an interior region that is separated from an exterior region; and

a window in the structures that is interposed between the interior region and the exterior region, wherein the window includes;

a guest-host liquid crystal light modulator; and

a layer configured to block infrared light emitted by the guest-host liquid crystal light modulator, wherein the guest-host liquid crystal light modulator has a layer of liquid crystal molecules and dye molecules interposed between first and second transparent conductive electrodes, wherein the guest-host liquid crystal light modulator has respective first and second liquid crystal alignment layers on the first and second transparent conductive electrodes, and wherein the first liquid crystal alignment layer has different regions with different respective alignment directions that establish alignment directions for the liquid crystal molecules in the absence of an applied voltage, the layer comprising;

a metal layer,

a metal oxide barrier layer that directly contacts the metal layer, and

a crystalline oxide seed layer that directly contacts the metal oxide barrier layer, wherein the metal oxide barrier layer is interposed between the crystalline oxide seed layer and the metal layer.

19. The system defined in claim 18, wherein the different respective alignment directions are varied in a stepwise fashion across a dimension of the guest-host liquid crystal light modulator.