Optical nitrate sensor compensation algorithm for multiparameter water quality measurement

• US 10,955,341 B2
• Filed: 03/09/2017
• Issued: 03/23/2021
• Est. Priority Date: 03/09/2016
• Status: Active Grant

• Current Assignee: YSI Incorporated (Xylem, Inc.)
• Original Assignee: YSI Incorporated (Xylem, Inc.)
• Inventors: Palassis, Christopher John, Poon, Melanie C. K.
• Primary Examiner(s): Gunberg, Edwin C
• Application Number:
  US15/454,465
• Publication Number:
  US 20170299511A1
• Time in Patent Office: 1,475 Days
• Field of Search: None
• CPC Class Codes: G01J 1/42 using electric radiation detectors optical or mechanical part G01J1/04; by comparison with a reference light or electric value G01J1/10
• CPC Class Codes: G01J 3/10 Arrangements of light sources specially adapted for spectrometry or colorimetry
• CPC Class Codes: G01J 3/28 Investigating the spectrum using colour filters G01J3/51
• CPC Class Codes: G01J 3/42 Absorption spectrometry; Double beam spectrometry; Flicker spectrometry; Reflection spectrometry beam switching arrangements G01J3/08
• CPC Class Codes: G01N 21/33 using ultraviolet light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/53 within a flowing fluid, e.g. smoke
• CPC Class Codes: G01N 21/59 Transmissivity G01N21/25 takes precedence
• CPC Class Codes: G01N 21/8806 Specially adapted optical and illumination features
• CPC Class Codes: G01N 2201/062 LED's
• CPC Class Codes: G01N 33/188 Determining the state of nitrification

Abstract

An optical nitrate sensor features a signal processor or signal processing module configured to:

• • receive signaling containing information about a concentration of nitrate dissolved in the water based upon a first UV optical absorbance of light centered at 229 nm, and also containing information about a dissolved organic matter (DOM) sensed in the water based upon a second UV optical absorbance of associated light centered in a range of 250 nm to 275 nm; and
  • determine corresponding signaling containing information about a corrected concentration of nitrate dissolved in the water by compensating the concentration of nitrate for the DOM sensed in the water, based upon the signaling received.

Claims

1. An optical nitrate sensor for sampling a confined volume of water within a prescribed region of a sampling chamber, comprising:

a UV LED combination configured to generate a first UV LED signal centered at 229 nm and a second UV LED signal centered in a range of 250-275 nm that traverse the confined volume of water within the prescribed region of the sampling chamber in order to sense nitrates in the water with first UV LED signal and dissolved organic matter (DOM) in the water with second UV LED signal;

a reference photodiode configured to respond to part of the first UV LED signal and the second UV LED signal, and provide photodiode reference signaling containing information about the part of the first UV LED signal and the second UV LED signal received;

a measuring photodiode configured to sense the first UV LED signal and the second UV LED signal that pass through the confined volume of water within the prescribed region of the sampling chamber, and provide photodiode measured signaling containing information about a nitrate absorption of the water related to the first UV LED signal and a DOM absorption background related to the second UV LED signal;

a transimpedance amplifier configured to respond to the photodiode reference signaling and the photodiode measured signaling, and provide transimpedance amplifier signaling containing information about a photocurrent to voltage reference signaling conversion of the photodiode reference signaling without interaction with the water, and also a photocurrent to voltage measured signaling conversion of the photodiode measured signaling after interaction with the water; and

a signal processor or signal processing module configured to;

receive the transimpedance amplifier signaling, and

determine corresponding signaling containing information about a DOM background corrected concentration of nitrates dissolved in the water by compensating the concentration of the nitrate absorption sensed in the water at 229 nm for the DOM background absorption sensed in the water in the range of 250-275 nm, based upon the transimpedance amplifier signaling received.

2. An optical nitrate sensor, according to claim 1, where the signal processor or signal processing module is configured to provide the corresponding signaling containing information about the DOM background corrected concentration of nitrate dissolved in the water.

3. An optical nitrate sensor according to claim 1, where the UV LED is configured to respond to signaling and generate the first UV LED signal and the second UV LED signal.

4. An optical nitrate sensor, according to claim 1, wherein the signal processor or signal processing module is configured to determine the DOM background corrected concentration by subtracting the DOM background absorption from the nitrate absorption to compensate for leaves and soil extracts in the water that can optically interfere with a nitrate measurement.

5. An optical nitrate sensor, according to claim 1, wherein the signal processor or signal processing module is configured to:

receive further signaling containing information about optical scattering from particulate in the water that appears as attenuation at all wavelengths of light; and

determine turbidity corrected signaling containing information about a turbidity corrected concentration of nitrate dissolved in the water, based upon the further signaling received.

6. An optical nitrate sensor, according to claim 1, wherein the signal processor or signal processing module is configured to receive the photodiode reference signaling and the photodiode measured signaling, and implement a compensation algorithm for doing one or more of the following:

determining an absorbance via a logarithm of a ratio of reference (R) and measurement (M) photodiode signaling and a ratio of a non-absorbing or blank standard, including where the non-absorbing or blank standard is determined in relation to deionized water;

or

subtracting a turbidity correction from the absorbance as a polynomial correction of coefficients α

_i or γ

_m, at 229 nm and ˜

275 nm, respectively, including where turbidity data signaling contains information about turbidity data provided from an internal or external optical measurement in nephelometric units;

or

determining or calculating a turbidity compensated nitrate concentration from the absorbance with a conversion factor(s) β

_j;

or

correcting an organic matter background via a subtraction of a turbidity compensated absorbance with a scale factor, δ

, for the 275 nm absorbance;

or

determining or calculating an organic matter and turbidity corrected nitrate concentration via a polynomial of coefficients ε

_k;

or/and

determining or calculating temperature corrections of organic background and turbidity compensated data signaling containing information about the organic background and turbidity compensated data via a polynomial of coefficients, μ

(°

C.).

7. An optical nitrate sensor, according to claim 1, wherein the signal processor or signal processing module is configured to receive the photodiode reference signaling and the photodiode measured signaling, and implement a compensation algorithm for correcting a nitrate measurement by doing one or more of the following:

making a temperature correction using an internal or external temperature sensor;

making a turbidity correction using an external or integrated turbidity measurement.

8. An optical nitrate sensor, according to claim 1, wherein the UV LED comprises:

a first UV LED for providing first UV light centered at 229 nm and that traverses a confined volume of the water within a prescribed region of a sensor body; and

a second UV LED for providing second UV light centered in a range of 250 nm to 275 nm.

9. An optical nitrate sensor, according to claim 1, wherein the optical nitrate sensor comprises:

a sensor body configured to confine a volume of the water within the prescribed region.

10. An optical nitrate sensor, according to claim 1, wherein the signal processor or signal processing module is configured to determine a measurement of the UV optical absorbance based upon the following equation:

Absorbance=−

log(optical transmittance)=−

log(M/a R),

where a is a proportionality constant that can be adjusted for electrical gain normalization.

11. A method for sampling a confined volume of water within a prescribed region of a sampling chamber with an optical nitrate sensor, comprising:

generating with a UV LED combination a first UV LED signal centered at 229 nm and a second UV LED signal centered in a range of 250-275 nm that traverse the confined volume of water within the prescribed region of the sampling chamber in order to sense nitrates in the water with first UV LED signal and dissolved organic matter (DOM) in the water with second UV LED signal;

responding with a reference photodiode to part of the first UV LED signal and the second UV LED signal, and providing photodiode reference signaling containing information about the part of the first UV LED signal and the second UV LED signal received;

sensing with a measuring photodiode the first UV LED signal and the second UV LED signal that pass through the confined volume of water within the prescribed region of the sampling chamber, and providing photodiode measured signaling containing information about a nitrate absorption of the water related to the first UV LED signal and a DOM absorption background related to the second UV LED signal;

responding with a transimpedance amplifier to the photodiode reference signaling and the photodiode measured signaling, and providing transimpedance amplifier signaling containing information about a photocurrent to voltage reference signaling conversion of the photodiode reference signaling without interaction with the water, and also a photocurrent to voltage measured signaling conversion of the photodiode measured signaling after interaction with the water; and

receiving with a signal processor or signal processing module the transimpedance amplifier signaling, and determining corresponding signaling containing information about a DOM background corrected concentration of nitrates dissolved in the water by compensating the concentration of the nitrate absorption sensed in the water at 229 nm for the DOM background absorption sensed in the water in the range of 250-275 nm, based upon the transimpedance amplifier signaling received.

12. A method according to claim 11, wherein the method comprises providing with the signal processor or signal processing module the corresponding signaling containing information about the DOM background corrected concentration of nitrate dissolved in the water.

13. A method according to claim 11, wherein the method comprises responding with the UV LED to control signaling and generating the first UV LED signal and the second UV LED signal.