Button cells and method of producing same

• US 11,024,869 B2
• Filed: 02/21/2020
• Issued: 06/01/2021
• Est. Priority Date: 02/09/2009
• Status: Active Grant

• Current Assignee: VARTA Microbattery GmbH (VARTA AG)
• Original Assignee: VARTA Microbattery GmbH (VARTA AG)
• Inventors: Pytlik, Eduard, Lindner, Jurgen, Barenthin, Ulrich, Gaugler, Winfried
• Primary Examiner(s): Kelly, Cynthia H
• Assistant Examiner(s): Anthony, Julian
• Application Number:
  US16/796,977
• Publication Number:
  US 20200194820A1
• Time in Patent Office: 466 Days
• Field of Search: None
• CPC Class Codes: H01M 10/0427 Button cells
• CPC Class Codes: H01M 10/0431 Cells with wound or folded electrodes H01M10/045 takes precedence
• CPC Class Codes: H01M 10/05 Accumulators with non-aqueous electrolyte H01M10/39 takes precedence
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/24 Alkaline accumulators
• CPC Class Codes: H01M 10/34 Gastight accumulators
• CPC Class Codes: H01M 10/345 Gastight metal hydride accumulators
• CPC Class Codes: H01M 50/109 of button or coin shape
• CPC Class Codes: H01M 50/124 having a layered structure
• CPC Class Codes: H01M 6/10 with wound or folded electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/4911 including sealing

Abstract

A button cell includes a housing, the housing including a cell cup, the cell cup having a flat bottom area, a cell cup casing; an insulator; and an electrode-separator assembly winding disposed within the housing, the electrode-separator assembly winding including a multi-layer assembly that is wound in a spiral shape about an axis, the multi-layer assembly including a positive electrode formed from a first metallic film or mesh coated with a first electrode material, a negative electrode formed from a second metallic film or mesh coated with a second electrode material, and a separator disposed between the positive electrode and the negative electrode. The first metallic film or mesh is bent such that at least a portion extends out of the electrode-separator assembly winding and wherein at least a first part of the portion is not covered with the first electrode material.

Claims

1. A button cell, comprising:

a housing, the housing including;

a cell cup, the cell cup having a flat bottom area, a cell cup casing, and a bottom edge forming a transition between the flat bottom area and the cell cup casing, and

a cell top, the cell top having a flat top area, a cell top casing, and a top edge forming a transition between the flat top area and the cell top casing;

an electrode-separator assembly winding disposed within the housing, the electrode-separator assembly winding including a multi-layer assembly that is wound in a spiral shape about an axis, the multi-layer assembly including;

a positive electrode formed from a first portion of a first metallic film or mesh coated with a first electrode material,

a negative electrode formed from a first portion of a second metallic film or mesh coated with a second electrode material, and

a separator disposed between the positive electrode and the negative electrode; and

a first insulator,

wherein the first metallic film or mesh is bent such that at least a second portion of the first metallic film or mesh extends out of the electrode-separator assembly winding and at least partially lies flat between (i) a first end face of the electrode-separator assembly winding and (ii) a first of the flat bottom area or the flat top area,

wherein the first insulator is disposed between the first end face of the electrode-separator assembly winding and the second portion of the first metallic film or mesh,

wherein at least a first part of the second portion of the first metallic film or mesh is not coated with the first electrode material and serves as an output conductor, and

wherein the first part of the second portion of the first metallic film or mesh is welded to the first of the flat bottom area or the flat top area.

2. The button cell as claimed in claim 1, further comprising a second insulator,

wherein the second metallic film or mesh is bent such that at least a second portion of the second metallic film or mesh extends out of the electrode-separator assembly winding and at least partially lies flat between a second end face of the electrode-separator assembly winding and a second of the flat bottom area or the flat top area,

wherein the second insulator is disposed between the second end face of the electrode-separator assembly winding and the second portion of the second metallic film or mesh,

wherein at least a first part of the second portion of the second metallic film or mesh is not coated with the second electrode material and serves as a second output conductor, and

wherein the first part of the second portion of the second metallic film or mesh is welded to the second of the flat bottom area or the flat top area.

3. The button cell as claimed in claim 2, wherein the second metallic film or mesh includes a first edge extending in the spiral shape and disposed adjacent to the second end face of the electrode-separator assembly winding, wherein the second insulator is disposed between the first edge of the second metallic film or mesh and the second of the flat bottom area or the flat top area to which the first part of the second portion of the second metallic film or mesh is welded.

4. The button cell as claimed in claim 2, wherein the second insulator completely covers the second end face of the electrode-separator assembly winding.

5. The button cell as claimed in claim 2, wherein the second portion of the first metallic film or mesh and the second portion of the second metallic film or mesh are pressed against the cell cup and the cell top.

6. The button cell as claimed in claim 1, wherein the first electrode material is a lithium-intercalating electrode material.

7. The button cell as claimed in claim 1, wherein the first metallic film or mesh includes a first edge extending in the spiral shape and disposed adjacent to the first end face of the electrode-separator assembly winding, wherein the first insulator is disposed between the first edge of the first metallic film or mesh and the first of the flat bottom area or the flat top area to which the first part of the second portion of the first metallic film or mesh is welded.

8. The button cell as claimed in claim 1, wherein the cell cup casing has a first height,

wherein the cell top casing has a second height, and

wherein the cell cup casing and the cell top casing overlap in a radial direction throughout an overlap area that extends in an axial direction parallel to the axis of the electrode-separator assembly winding, the overlap area having a third height,

wherein the third height is less than the second height.

9. The button cell as claimed in claim 8, wherein the third height is from 20% to 99% of the second height.

10. The button cell as claimed in claim 8, further comprising an insulating seal, a first portion of the insulating seal being disposed between the cell cup casing and the cell top casing in the axially extending overlap area.

11. The button cell as claimed in claim 10, wherein the first portion of the insulating seal has a final thickness in the axially extending overlap area that is compressed to 10% to 90% of an initial thickness of the first portion of the insulating seal, the initial thickness of the insulating seal being a thickness of the insulating seal before being incorporated into the button cell.

12. The button cell as claimed in claim 11, wherein the initial thickness is in the range of 50 μ

m to 250 μ

m.

13. The button cell as claimed in claim 10, wherein the first portion of the insulating seal has a thickness in the range of 5 μ

m to 225 μ

m.

14. The button cell as claimed in claim 13, wherein the first portion of the insulating seal has a thickness in the range of 15 μ

m to 175 μ

m.

15. The button cell as claimed in claim 1, wherein an interference fit is formed between the cell cup casing and the cell top casing.

16. The button cell as claimed in claim 15, wherein a part of the cell cup casing is drawn radially inward.

17. The button cell as claimed in claim 15, wherein the first electrode material is a lithium-intercalating electrode material, and

wherein the housing is configured to absorb radial forces caused by volume changes of the positive electrode and the negative electrode during charging and discharging processes.

18. The button cell as claimed in claim 1, further comprising an insulating seal, at least a portion of the insulating seal being disposed between the cell cup casing and the cell top casing.

19. The button cell as claimed in claim 18, wherein the portion of the insulating seal disposed between the cell cup casing and the cell top casing is disposed on an inner portion of the cell cup casing and an outer portion of the cell top casing.

20. The button cell as claimed in claim 18, wherein the insulating seal is a film seal.

21. The button cell as claimed in claim 1, wherein the electrode-separator assembly winding further includes a winding core.

22. The button cell as claimed in claim 1, wherein the electrode-separator assembly winding does not include a winding core.

23. The button cell as claimed in claim 1, wherein the first metallic film or mesh is a metallic ribbon having a thickness in the range of 10 μ

m to 1000 μ

m,

wherein the second metallic film or mesh is a metallic ribbon having a thickness in the range of 10 μ

m to 1000 μ

m, and

wherein the separator is a porous plastic film having a thickness in the range of 3 μ

m to 100 μ

m.

24. The button cell as claimed in claim 1, wherein the separator includes multiple separator layers, and

wherein the multi-layer assembly has one of the following layer sequences:

negative electrode/separator layer/positive electrode/separator layer, or

positive electrode/separator layer/negative electrode/separator layer.

25. The button cell as claimed in claim 24, wherein the separator layers are porous plastic films having a thickness in the range of 3 μ

m to 100 μ

m.

26. The button cell as claimed in claim 1, wherein the first insulator completely covers the first end face of the electrode-separator assembly winding.

27. The button cell as claimed in claim 1, wherein the cell cup casing is aligned at a right angle to the flat bottom area,

wherein the cell top casing is aligned at a right angle to the flat top area.

28. The button cell as claimed in claim 27, wherein the cell cup casing includes a circular cut edge at an opposite end of the casing from the bottom edge,

wherein at least a portion of the cell top casing has an essentially cylindrical geometry, and

wherein the cell circular cut edge is pressed against the portion of the cell top casing having the essentially cylindrical geometry.

29. The button cell as claimed in claim 1, further comprising an insulating seal, at least a portion of the insulating seal being disposed between the cell cup casing and the cell top casing

wherein at least a portion of the cell cup casing has an internal radius,

wherein at least a portion of the cell top casing has an external radius,

wherein the portion of the insulating seal has a final thickness equal to a difference between the internal radius and the external radius, and

wherein an initial thickness of the portion of the insulating seal is greater than the difference between the internal radius and the external radius, the initial thickness of the insulating seal being a thickness of the insulating seal before being incorporated into the button cell, such that friction is produced between the cell cup and the cell top.

30. The button cell as claimed in claim 1, wherein the cell cup casing includes a cut edge at an opposite end of the casing from the bottom edge, the cut edge being beaded over a portion of the cell top casing.