Deposition of wear resistant nickel-tungsten plating systems

• US 11,041,252 B2
• Filed: 03/22/2018
• Issued: 06/22/2021
• Est. Priority Date: 03/22/2018
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Piascik, James, Cao, Gangmin, Aizaz, Amer, Lv, Jingkang, Jadidian, Bahram
• Primary Examiner(s): Mendez, Zulmariam
• Application Number:
  US15/928,569
• Publication Number:
  US 20190292678A1
• Time in Patent Office: 1,188 Days
• CPC Class Codes: C10M 103/04 Metals; Alloys
• CPC Class Codes: C10M 103/06 Metal compounds
• CPC Class Codes: C10M 2201/053 used as base material
• CPC Class Codes: C10M 2201/0623 used as base material
• CPC Class Codes: C10N 2030/06 Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
• CPC Class Codes: C10N 2050/08 Solids
• CPC Class Codes: C25D 15/00 Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires
• CPC Class Codes: C25D 3/56 of alloys
• CPC Class Codes: C25D 3/562 containing more than 50% by weight of iron or nickel or cobalt

Abstract

Methods for depositing wear resistant NiW plating systems on metallic components are provided. In various embodiments, the method includes the step or process of preparing a NiW plating bath containing a particle suspension. The NiW plating bath is prepared by introducing wear resistant particles into the NiW plating path and adding at least one charged surfactant. The first type of wear resistant particles and the first charged surfactant may be contacted when introduced into the NiW plating bath or prior to introduction into the NiW plating bath. The at least one charged surfactant binds with the wear resistant particles to form a particle-surfactant complex. The wear resistant NiW plating system is then electrodeposited onto a surface of a component at least partially submerged in the NiW plating bath. The resulting wear resistant NiW plating system comprised of a NiW matrix in which the wear resistant particles are embedded.

Claims

1. A method for forming a wear resistant nickel tungsten (NiW) plating system, the method comprising:

preparing a NiW plating bath containing a particle suspension, preparing comprising;

introducing wear resistant particles into the NiW plating bath, the wear resistant particles comprising alumina particles;

selecting an amount of at least one charged surfactant based on a particle size of the alumina particles, a cumulative surface area of the alumina particles and the quantity of the alumina particles in the NiW plating bath, the at least one charged surfactant comprising sodium dodecyl sulfate and cetyltrimethylammonium bromide;

adding to the NiW plating bath the at least one charged surfactant, the at least one charged surfactant binding with the wear resistant particles to form a particle-surfactant complex; and

electrodepositing the wear resistant NiW plating system onto a surface of a component at least partially submerged in the NiW plating bath, the wear resistant NiW plating system comprised of a NiW matrix in which the wear resistant particles are embedded.

2. The method of claim 1 further comprising formulating the at least one charged surfactant to impart the particle-surfactant complex with a net positive charge exceeding a native positive charge of the wear resistant particles.

3. The method of claim 1 further comprising:

initially contacting the wear resistant particles with the sodium dodecyl sulfate to produce an intermediary particle-surfactant complex with a net negative charge; and

after initially contacting the wear resistant particles with the sodium dodecyl sulfate, subsequently contacting the intermediary particle-surfactant complex with the cetyltrimethylammonium bromide to yield the particle-surfactant complex.

4. The method of claim 3 further comprising pre-coating the wear resistant particles with the sodium dodecyl sulfate and the cetyltrimethylammonium bromide prior to introduction into the NiW plating bath.

5. The method of claim 3 wherein the wear resistant particles, the sodium dodecyl sulfate, and the cetyltrimethylammonium bromide are initially contacted within the NiW plating bath.

6. The method of claim 1 further comprising:

selecting the wear resistant particles to have a hardness greater than that of the NiW matrix.

8. The method of claim 1 wherein further comprising selecting a concentration of the wear resistant particles in the NiW plating bath and electrodepositing the wear resistant NiW plating system such that the NiW plating system has a fill rate between 0.1 and 10% wear resistant particles, by weight.

9. The method of claim 1 further comprising:

introducing about 0.2 grams per liter cetyltrimethylammonium bromide to the NiW plating bath.

7. A method for forming a wear resistant nickel tungsten (NiW) plating system, the method comprising:

preparing a NiW plating bath containing a particle suspension, preparing comprising;

introducing wear resistant particles into the NiW plating bath, the wear resistant particles comprising hexagonal boron nitride particles;

selecting an amount of at least one charged surfactant based on a particle size of the wear resistant particles and a quantity of the wear resistant particles in the NiW plating bath, the at least one charged surfactant comprising sodium dodecyl sulfate and PEG-8 methyl ether dimethicone;

adding to the NiW plating bath the at least one charged surfactant, the at least one charged surfactant binding with the wear resistant particles to form a particle-surfactant complex; and

electrodepositing the wear resistant NiW plating system onto a surface of a component at least partially submerged in the NiW plating bath, the wear resistant NiW plating system comprised of a NiW matrix in which the wear resistant particles are embedded.