Ceramic materials and seals for high temperature reactive material devices

• US 11,840,487 B2
• Filed: 02/11/2022
• Issued: 12/12/2023
• Est. Priority Date: 03/05/2015
• Status: Active Grant

• Current Assignee: Ambri
• Original Assignee: Ambri
• Inventors: Bradwell, David J., Neltner, Brian, Pujari, Vimal, McNeley, Michael J., Thompson, Greg A., Lee, Chia-Ying, Deak, David S., Nayar, Hari P.
• Primary Examiner(s): Douyette, Kenneth J
• Application Number:
  US17/670,168
• Publication Number:
  US 20220263168A1
• Time in Patent Office: 669 Days
• CPC Class Codes: C04B 2237/122 based on refractory metals
• CPC Class Codes: C04B 2237/123 based on iron group metals, e.g. steel
• CPC Class Codes: C04B 2237/124 based on copper
• CPC Class Codes: C04B 2237/366 Aluminium nitride
• CPC Class Codes: C04B 2237/403 Refractory metals
• CPC Class Codes: C04B 2237/72 Forming laminates or joined articles comprising at least two interlayers directly next to each other
• CPC Class Codes: C04B 2237/74 Forming laminates or joined articles comprising at least two different interlayers separated by a substrate
• CPC Class Codes: C04B 37/026 consisting of metals or metal salts
• CPC Class Codes: C22C 27/04 Alloys based on tungsten or molybdenum
• CPC Class Codes: H01M 10/39 working at high temperature
• CPC Class Codes: H01M 10/399 Cells with molten salts
• CPC Class Codes: H01M 2220/10 Batteries in stationary systems, e.g. emergency power source in plant
• CPC Class Codes: H01M 2300/0057 Chlorides
• CPC Class Codes: H01M 50/147 Lids or covers
• CPC Class Codes: H01M 50/176 for prismatic or rectangular cells H01M50/181 takes precedence
• CPC Class Codes: H01M 50/186 characterised by the disposition of the sealing members
• CPC Class Codes: H01M 50/191 Inorganic material

Abstract

The disclosure provides seals for devices that operate at elevated temperatures and have reactive metal vapors, such as lithium, sodium or magnesium. In some examples, such devices include energy storage devices that may be used within an electrical power grid or as part of a standalone system. The energy storage devices may be charged from an electricity production source for later discharge, such as when there is a demand for electrical energy consumption.

Claims

1. An electrochemical cell, comprising:

a container comprising a conductor aperture, wherein said container is configured to contain a reactive material at a temperature of at least about 100°

C.;

a conductor that extends from an environment external to said container through said conductor aperture into said container; and

a sealing unit that couples said container to said conductor to seal said conductor aperture, wherein said sealing unit comprises a first ceramic component bonded to a second ceramic component, wherein said first ceramic component comprises a first material and said second ceramic component comprises a second material different from said first material, and wherein said first ceramic component or said second ceramic component is configured to be exposed to said reactive material while said sealing unit seals said conductor aperture.

2. The electrochemical cell of claim 1, wherein said first ceramic component and said second ceramic component comprise a mutual reaction compound.

3. The electrochemical cell of claim 1, wherein said second ceramic component is a layer disposed on one or more surfaces of said first ceramic component.

4. The electrochemical cell of claim 3, wherein said sealing unit further comprises a third ceramic component, and wherein said third ceramic component is another layer disposed on said second ceramic component or on another surface of said one or more surfaces of said first ceramic component than said second ceramic component.

5. The electrochemical cell of claim 1, wherein said first material comprises aluminum nitride, silicon nitride, silicon carbide, or a combination thereof.

6. The electrochemical cell of claim 5, wherein said second material comprises yttrium.

7. The electrochemical cell of claim 1, wherein said second material comprises silicon carbide or tungsten carbide.

8. The electrochemical cell of claim 1, wherein said first ceramic component and said second ceramic component are bonded via sintering.

9. The electrochemical cell of claim 1, wherein said first ceramic component is alloyed to said second ceramic component.

10. The electrochemical cell of claim 1, wherein said first ceramic component is a ring, and wherein said ring is disposed around said conductor.

11. The electrochemical cell of claim 1, wherein said sealing unit further comprises a metal sleeve configured to couple said first ceramic component or said second ceramic component to said container or to said conductor.

12. The electrochemical cell of claim 11, wherein said metal sleeve comprises a material selected from the group consisting of grade 304 stainless steel, grade 430 stainless steel, grade 410 stainless steel, zirconium, an iron-nickel alloy, and 18CrCb ferritic stainless steel.

13. The electrochemical cell of claim 11, wherein said metal sleeve has a thickness of greater than or equal to about 75 micrometers (μ

m).

14. The electrochemical cell of claim 13, wherein said thickness is less than or equal to about 500 μ

m.

15. The electrochemical cell of claim 11, wherein said metal sleeve is coupled to said first ceramic component, said second ceramic component, said container, or said conductor by a braze.

16. The electrochemical cell of claim 15, wherein said braze comprises one or more members selected from the group consisting of silver, aluminum, titanium, nickel, and combinations thereof.

17. The electrochemical cell of claim 1, wherein said second ceramic component is configured to protect said first ceramic component from said reactive material or said environment external to said container.

18. The electrochemical cell of claim 1, wherein said second ceramic component is an active layer configured to permit said first ceramic component to couple to said container or said conductor.

19. The electrochemical cell of claim 1, wherein said reactive material comprises a molten metal and a molten salt.